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Three-dimensional modeling of PEMFC with contaminated anode fuel

Author

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  • Abdollahzadeh, M.
  • Ribeirinha, P.
  • Boaventura, M.
  • Mendes, A.

Abstract

A novel transient multi-dimensional non-isothermal multiphase model for simulating PEMFC was developed. A multiphase agglomerate catalyst model was considered for the cathode catalyst layer, while in the anode catalyst layer the effect of CO and CO2 presence was taken into consideration assuming two families of catalysts, Pt/C and Pt-Ru. The model predictions were compared to experimental data found in the literature and from an in-house PEMFC. The model was able to capture accurately the steady polarization curves of PEMFCs fed with hydrogen containing different amounts of CO and CO2. Moreover, the corresponding transient voltage was accurately simulated. The results indicated that even low CO concentration in the anode fuel, leads to a considerable degradation of the fuel cell output current density. Among the tested gas diffusion layers, the ones with the highest thickness showed worst performance of the PEMFC. Results showed, that high tortuosity and low contact angle (hydrophobicity) of the gas diffusion layer, decreases the performance of the PEMFC.

Suggested Citation

  • Abdollahzadeh, M. & Ribeirinha, P. & Boaventura, M. & Mendes, A., 2018. "Three-dimensional modeling of PEMFC with contaminated anode fuel," Energy, Elsevier, vol. 152(C), pages 939-959.
    • Handle: RePEc:eee:energy:v:152:y:2018:i:c:p:939-959
    DOI: 10.1016/j.energy.2018.03.162
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    4. Lei, Gang & Zheng, Hualin & Zhang, Jun & Siong Chin, Cheng & Xu, Xinhai & Zhou, Weijiang & Zhang, Caizhi, 2023. "Analyzing characteristic and modeling of high-temperature proton exchange membrane fuel cells with CO poisoning effect," Energy, Elsevier, vol. 282(C).
    5. Zhu, Jingyu & Tan, Jinzhu & Pan, Qing & Liu, Zenghui & Hou, Qiong, 2019. "Effects of Mg2+ contamination on the performance of proton exchange membrane fuel cell," Energy, Elsevier, vol. 189(C).
    6. Lu Zhang & Yongfeng Liu & Pucheng Pei & Xintong Liu & Long Wang & Yuan Wan, 2022. "Variation Characteristic Analysis of Water Content at the Flow Channel of Proton Exchange Membrane Fuel Cell," Energies, MDPI, vol. 15(9), pages 1-20, April.
    7. Cai, Yonghua & Wu, Di & Sun, Jingming & Chen, Ben, 2021. "The effect of cathode channel blockages on the enhanced mass transfer and performance of PEMFC," Energy, Elsevier, vol. 222(C).
    8. Zhang, Jun & Zhang, Caizhi & Li, Jin & Deng, Bo & Fan, Min & Ni, Meng & Mao, Zhanxin & Yuan, Honggeng, 2021. "Multi-perspective analysis of CO poisoning in high-temperature proton exchange membrane fuel cell stack via numerical investigation," Renewable Energy, Elsevier, vol. 180(C), pages 313-328.
    9. Rezk, Hegazy & Olabi, A.G. & Ferahtia, Seydali & Sayed, Enas Taha, 2022. "Accurate parameter estimation methodology applied to model proton exchange membrane fuel cell," Energy, Elsevier, vol. 255(C).
    10. Asensio, F.J. & San Martín, J.I. & Zamora, I. & Saldaña, G. & Oñederra, O., 2019. "Analysis of electrochemical and thermal models and modeling techniques for polymer electrolyte membrane fuel cells," Renewable and Sustainable Energy Reviews, Elsevier, vol. 113(C), pages 1-1.
    11. Zhang, Weixin & Yi, Peiyun & Peng, Linfa & Lai, Xinmin, 2018. "Strategy of alternating bias voltage on corrosion resistance and interfacial conductivity enhancement of TiCx/a-C coatings on metallic bipolar plates in PEMFCs," Energy, Elsevier, vol. 162(C), pages 933-943.

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