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Modeling of membrane electrode assembly of PEM fuel cell to analyze voltage losses inside

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  • Hong, Po
  • Xu, Liangfei
  • Li, Jianqiu
  • Ouyang, Minggao

Abstract

The membrane electrode assembly plays an important role in determining performance of a PEM fuel cell but the mass transport and electrochemical reactions inside are extremely complex. Recently more research efforts are made on modeling cathode catalyst layer to explain phenomena related to water content. In this paper, a pseudo two-dimensional model of cathode catalyst layer together with a one-dimensional model of membrane is proposed to analyze all kinds of voltage losses inside. The model originates from two probable approaches of oxygen transport, namely via the gas pore and through the electrolyte solution to reach reaction sites. Simulation results show that the inter-diffusion coefficient of oxygen, nitrogen and water vapor affects the mass transport significantly even though the Knudsen diffusion begins to emerge with respect to scale of the gas pore. The cathode catalyst layer can be divided into three different zones and there exists a special zone with only proton conduction. As the electrode electrolyte potential varies, the special zone expands towards the CCL/CGDL interface and it implies accumulation of water content inside. The composition of total proton conduction resistance changes and the proton conduction resistance in the special zone cannot be neglected in comparison with that in membrane.

Suggested Citation

  • Hong, Po & Xu, Liangfei & Li, Jianqiu & Ouyang, Minggao, 2017. "Modeling of membrane electrode assembly of PEM fuel cell to analyze voltage losses inside," Energy, Elsevier, vol. 139(C), pages 277-288.
    • Handle: RePEc:eee:energy:v:139:y:2017:i:c:p:277-288
    DOI: 10.1016/j.energy.2017.07.163
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    References listed on IDEAS

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    Cited by:

    1. Zhao, Jian & Ozden, Adnan & Shahgaldi, Samaneh & Alaefour, Ibrahim E. & Li, Xianguo & Hamdullahpur, Feridun, 2018. "Effect of Pt loading and catalyst type on the pore structure of porous electrodes in polymer electrolyte membrane (PEM) fuel cells," Energy, Elsevier, vol. 150(C), pages 69-76.
    2. Xu, Liangfei & Hu, Zunyan & Fang, Chuan & Li, Jianqiu & Hong, Po & Jiang, Hongliang & Guo, Di & Ouyang, Minggao, 2021. "Anode state observation of polymer electrolyte membrane fuel cell based on unscented Kalman filter and relative humidity sensor before flooding," Renewable Energy, Elsevier, vol. 168(C), pages 1294-1307.
    3. Abdollahzadeh, M. & Ribeirinha, P. & Boaventura, M. & Mendes, A., 2018. "Three-dimensional modeling of PEMFC with contaminated anode fuel," Energy, Elsevier, vol. 152(C), pages 939-959.
    4. Jiangyan Yan & Chang Zhou & Zhihai Rong & Haijiang Wang & Hui Li & Xuejiao Hu, 2020. "Simulation of the Dynamic Characteristics of a PEMFC System in Fluctuating Operating Conditions," Energies, MDPI, vol. 13(14), pages 1-17, July.
    5. Pan, Mingzhang & Li, Chao & Liao, Jinyang & Lei, Han & Pan, Chengjie & Meng, Xianpan & Huang, Haozhong, 2020. "Design and modeling of PEM fuel cell based on different flow fields," Energy, Elsevier, vol. 207(C).
    6. Qiu, Diankai & Peng, Linfa & Liang, Peng & Yi, Peiyun & Lai, Xinmin, 2018. "Mechanical degradation of proton exchange membrane along the MEA frame in proton exchange membrane fuel cells," Energy, Elsevier, vol. 165(PB), pages 210-222.
    7. Chowdhury, Mohammad Ziauddin & Timurkutluk, Bora, 2018. "Transport phenomena of convergent and divergent serpentine flow fields for PEMFC," Energy, Elsevier, vol. 161(C), pages 104-117.

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