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Single cell induced starvation in a high temperature proton exchange membrane fuel cell stack

Author

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  • Alegre, Cinthia
  • Lozano, Antonio
  • Manso, Ángel Pérez
  • Álvarez-Manuel, Laura
  • Marzo, Florencio Fernández
  • Barreras, Félix

Abstract

Fuel and oxidant starvation are amongst the most critical phenomena affecting fuel cell durability. Reactant starvation during proton exchange membrane fuel cell operation can cause serious irreversible damages. In the present research, the effect of a selective induced starvation of reactant gases on the performance and degradation of a high-temperature PEM fuel cell is studied. A specifically designed 5-cell stack is used, which enables varying the gas supplied to any of the individual cells. The particularity of selectively starving only one cell in a controlled manner is one of the novelties of this study. Two different tests are performed actuating on the central cell (cell 3). They are denoted as moderate and severe starvation, depending on the intensity of the limitation imposed to the gases flowrate. Some relevant and novel results are obtained. It is verified that the performance degradation caused by a moderate starvation of the reactant gases in a cell is reversible. On the contrary, the damages caused by an aggressive gas starvation, which is also maintained in time (30 min), are irreversible. However, the behavior of the rest of the cells is barely affected by the gas starvation to cell 3. Thus, the other major novelty of the present work is the evidence/proof of the ability of a stack with a starved and highly degraded cell, to continue operating, although with a drastic reduction in the total generated current.

Suggested Citation

  • Alegre, Cinthia & Lozano, Antonio & Manso, Ángel Pérez & Álvarez-Manuel, Laura & Marzo, Florencio Fernández & Barreras, Félix, 2019. "Single cell induced starvation in a high temperature proton exchange membrane fuel cell stack," Applied Energy, Elsevier, vol. 250(C), pages 1176-1189.
  • Handle: RePEc:eee:appene:v:250:y:2019:i:c:p:1176-1189
    DOI: 10.1016/j.apenergy.2019.05.061
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    References listed on IDEAS

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    1. Chen, Yong-Song & Yang, Chih-Wei & Lee, Jiunn-Yih, 2014. "Implementation and evaluation for anode purging of a fuel cell based on nitrogen concentration," Applied Energy, Elsevier, vol. 113(C), pages 1519-1524.
    2. De las Heras, A. & Vivas, F.J. & Segura, F. & Redondo, M.J. & Andújar, J.M., 2018. "Air-cooled fuel cells: Keys to design and build the oxidant/cooling system," Renewable Energy, Elsevier, vol. 125(C), pages 1-20.
    3. Wang, Yun & Chen, Ken S. & Mishler, Jeffrey & Cho, Sung Chan & Adroher, Xavier Cordobes, 2011. "A review of polymer electrolyte membrane fuel cells: Technology, applications, and needs on fundamental research," Applied Energy, Elsevier, vol. 88(4), pages 981-1007, April.
    4. Lee, Chi-Yuan & Chiang, Yu-Chun & Weng, Fang-Bor & Li, Shih-Chun & Wu, Pai-Hsuan & Yueh, Heng-I., 2017. "Flexible micro temperature, voltage and current sensors for local real-time microscopic diagnosis inside high temperature proton exchange membrane fuel cell stack," Renewable Energy, Elsevier, vol. 108(C), pages 126-131.
    5. Wang, Junye, 2017. "System integration, durability and reliability of fuel cells: Challenges and solutions," Applied Energy, Elsevier, vol. 189(C), pages 460-479.
    6. Bae, Suk Joo & Kim, Seong-Joon & Lee, Jin-Hwa & Song, Inseob & Kim, Nam-In & Seo, Yongho & Kim, Ki Buem & Lee, Naesung & Park, Jun-Young, 2014. "Degradation pattern prediction of a polymer electrolyte membrane fuel cell stack with series reliability structure via durability data of single cells," Applied Energy, Elsevier, vol. 131(C), pages 48-55.
    7. Alessandro Stassi & Irene Gatto & Ada Saccà & Vincenzo Baglio & Antonino S. Aricò, 2015. "Enhancement of Oxygen Reduction and Mitigation of Ionomer Dry-Out Using Insoluble Heteropoly Acids in Intermediate Temperature Polymer-Electrolyte Membrane Fuel Cells," Energies, MDPI, vol. 8(8), pages 1-13, July.
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    2. Deng, Shutong & Zhang, Jun & Zhang, Caizhi & Luo, Mengzhu & Ni, Meng & Li, Yu & Zeng, Tao, 2022. "Prediction and optimization of gas distribution quality for high-temperature PEMFC based on data-driven surrogate model," Applied Energy, Elsevier, vol. 327(C).
    3. Jordi Renau & Víctor García & Luis Domenech & Pedro Verdejo & Antonio Real & Alberto Giménez & Fernando Sánchez & Antonio Lozano & Félix Barreras, 2021. "Novel Use of Green Hydrogen Fuel Cell-Based Combined Heat and Power Systems to Reduce Primary Energy Intake and Greenhouse Emissions in the Building Sector," Sustainability, MDPI, vol. 13(4), pages 1-19, February.

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