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In situ catalytic conversion of tar using rice husk char/ash supported nickel–iron catalysts for biomass pyrolytic gasification combined with the mixing-simulation in fluidized-bed gasifier

Author

Listed:
  • Shen, Yafei
  • Zhao, Peitao
  • Shao, Qinfu
  • Takahashi, Fumitake
  • Yoshikawa, Kunio

Abstract

A catalytic gasification technology has been proposed for tar in situ conversion using the rice husk char (RHC) or rice husk ash (RHA) supported nickel–iron catalysts. Biomass tar could be converted effectively by co-pyrolysis with the RHC/RHA supported nickel–iron catalysts at 800°C, simplifying the follow-up tar removal process. Under the optimized conditions, the tar conversion efficiency could reach about 92.3% by the RHC Ni–Fe, which exhibited more advantages of easy preparation and energy-saving. In addition, the tar conversion efficiency could reach about 93% by the RHA Ni. Significantly, partial metal oxides (e.g., NiO, Fe2O3) in the carbon matrix of RHC could be in-situ carbothermally reduced into the metallic state (e.g., Ni0) by reducing gases (e.g., CO) or carbon atom, thereby enhancing the catalytic performance of tar conversion. Furthermore, mixing with other solid particles such as sand and RHA Ni, can also improve biomass (e.g., RH) fluidization behavior by optimizing the operation parameters (e.g., particle size, mass fraction) in the mode of fluidized bed gasifier (FBG). After the solid–solid mixing simulation, the RH mass fraction of 0.5 and the particle diameter of 0.5mm can be employed in the binary mixture of RH and RHA.

Suggested Citation

  • Shen, Yafei & Zhao, Peitao & Shao, Qinfu & Takahashi, Fumitake & Yoshikawa, Kunio, 2015. "In situ catalytic conversion of tar using rice husk char/ash supported nickel–iron catalysts for biomass pyrolytic gasification combined with the mixing-simulation in fluidized-bed gasifier," Applied Energy, Elsevier, vol. 160(C), pages 808-819.
    • Handle: RePEc:eee:appene:v:160:y:2015:i:c:p:808-819
    DOI: 10.1016/j.apenergy.2014.10.074
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    References listed on IDEAS

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    1. Fagbemi, L & Khezami, L & Capart, R, 2001. "Pyrolysis products from different biomasses: application to the thermal cracking of tar," Applied Energy, Elsevier, vol. 69(4), pages 293-306, August.
    2. Slopiecka, Katarzyna & Bartocci, Pietro & Fantozzi, Francesco, 2012. "Thermogravimetric analysis and kinetic study of poplar wood pyrolysis," Applied Energy, Elsevier, vol. 97(C), pages 491-497.
    3. Ahmed, I.I. & Nipattummakul, N. & Gupta, A.K., 2011. "Characteristics of syngas from co-gasification of polyethylene and woodchips," Applied Energy, Elsevier, vol. 88(1), pages 165-174, January.
    4. Wang, Duo & Yuan, Wenqiao & Ji, Wei, 2011. "Char and char-supported nickel catalysts for secondary syngas cleanup and conditioning," Applied Energy, Elsevier, vol. 88(5), pages 1656-1663, May.
    5. Shen, Yafei & Yoshikawa, Kunio, 2013. "Recent progresses in catalytic tar elimination during biomass gasification or pyrolysis—A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 21(C), pages 371-392.
    6. R. Rao, T & Ram. Bheemarasetti, J.V, 2001. "Minimum fluidization velocities of mixtures of biomass and sands," Energy, Elsevier, vol. 26(6), pages 633-644.
    7. Font Palma, Carolina, 2013. "Modelling of tar formation and evolution for biomass gasification: A review," Applied Energy, Elsevier, vol. 111(C), pages 129-141.
    8. Choudhary, V. R. & Mamman, A. S., 2000. "Energy efficient conversion of methane to syngas over NiO-MgO solid solution," Applied Energy, Elsevier, vol. 66(2), pages 161-175, June.
    9. Phuphuakrat, Thana & Namioka, Tomoaki & Yoshikawa, Kunio, 2010. "Tar removal from biomass pyrolysis gas in two-step function of decomposition and adsorption," Applied Energy, Elsevier, vol. 87(7), pages 2203-2211, July.
    10. Rutberg, Philip G. & Kuznetsov, Vadim A. & Serba, Evgeny O. & Popov, Sergey D. & Surov, Alexander V. & Nakonechny, Ghennady V. & Nikonov, Alexey V., 2013. "Novel three-phase steam–air plasma torch for gasification of high-caloric waste," Applied Energy, Elsevier, vol. 108(C), pages 505-514.
    11. Ahmed, I. & Gupta, A.K., 2009. "Evolution of syngas from cardboard gasification," Applied Energy, Elsevier, vol. 86(9), pages 1732-1740, September.
    12. Fernández, J.R. & Abanades, J.C., 2014. "Conceptual design of a Ni-based chemical looping combustion process using fixed-beds," Applied Energy, Elsevier, vol. 135(C), pages 309-319.
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