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High temperature thermochemical processing of biomass and methane for high conversion and selectivity to H2-enriched syngas

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  • Palumbo, Aaron W.
  • Sorli, Jeni C.
  • Weimer, Alan W.

Abstract

Hybrid thermochemical processes show promise to increase plant performance with respect to fungible hydrocarbon production as a substitute to petroleum-based transportation fuels. Biomass, methane, and steam were reacted in a high temperature, indirectly heated reactor to determine the effects of biomass type (microalgae, rice hulls, cotton stalk), temperature (1600–1800K), and reactant ratios (α=0–2.0; β=1.0–4.8) on carbon conversion, cold gas efficiency, and syngas composition. This hybrid co-feed system was shown to achieve high H2-content syngas with CO selectivity >0.90 and carbon conversion of both biomass and methane >0.90. Temperature was the dominant factor on the yields of CO, CO2, and CH4, while reactant ratios could be used to fine-tune the syngas composition. H2 yield was only slightly dependent on temperature and excess steam. CO formation was highly kinetically-limited for this temperature range. Biomass type slightly affected gasifier performance, most likely due to total char and soot yield from devolatilization. Allothermal reactor design results in comparable gasifier efficiencies depending on steam input and thermal efficiency; a solarthermal reactor would negate 1.3–1.6kgCO2/kgC processed and represents the recommended configuration for this type of process operation.

Suggested Citation

  • Palumbo, Aaron W. & Sorli, Jeni C. & Weimer, Alan W., 2015. "High temperature thermochemical processing of biomass and methane for high conversion and selectivity to H2-enriched syngas," Applied Energy, Elsevier, vol. 157(C), pages 13-24.
    • Handle: RePEc:eee:appene:v:157:y:2015:i:c:p:13-24
    DOI: 10.1016/j.apenergy.2015.07.072
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    1. Clausen, Lasse R. & Houbak, Niels & Elmegaard, Brian, 2010. "Technoeconomic analysis of a methanol plant based on gasification of biomass and electrolysis of water," Energy, Elsevier, vol. 35(5), pages 2338-2347.
    2. Bridgwater, A. V. & Toft, A. J. & Brammer, J. G., 2002. "A techno-economic comparison of power production by biomass fast pyrolysis with gasification and combustion," Renewable and Sustainable Energy Reviews, Elsevier, vol. 6(3), pages 181-246, September.
    3. Sudiro, Maria & Bertucco, Alberto, 2009. "Production of synthetic gasoline and diesel fuel by alternative processes using natural gas and coal: Process simulation and optimization," Energy, Elsevier, vol. 34(12), pages 2206-2214.
    4. He, Jie & Zhang, Wennan, 2011. "Techno-economic evaluation of thermo-chemical biomass-to-ethanol," Applied Energy, Elsevier, vol. 88(4), pages 1224-1232, April.
    5. Font Palma, Carolina, 2013. "Modelling of tar formation and evolution for biomass gasification: A review," Applied Energy, Elsevier, vol. 111(C), pages 129-141.
    6. Fatih Demirbas, M., 2009. "Biorefineries for biofuel upgrading: A critical review," Applied Energy, Elsevier, vol. 86(Supplemen), pages 151-161, November.
    7. Li, Hongqiang & Hong, Hui & Jin, Hongguang & Cai, Ruixian, 2010. "Analysis of a feasible polygeneration system for power and methanol production taking natural gas and biomass as materials," Applied Energy, Elsevier, vol. 87(9), pages 2846-2853, September.
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