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Improving the stability of synthetic CaO-based CO2 sorbents by structural promoters

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  • Antzara, Andy
  • Heracleous, Eleni
  • Lemonidou, Angeliki A.

Abstract

CaO-based materials are promising sorbents for CO2 capture via carbonate looping for high temperature applications, which however suffer from decreasing sorption capacity over multiple sorption/desorption cycles. In this study, we report the development of mixed CaO-based CO2 sorbents with inert structural promoters prepared via sol–gel auto-combustion that exhibit significant stability increase. Different synthesis parameters such as the organic material used as combustion agent, the inert material used as stabilizer and the CaO concentration in the sorbent were investigated. Citric acid was identified as the most suitable combustion agent, resulting in the formation of calcium oxide with the highest initial sorption capacity. Among the four different promoters used to increase the resistance of CaO toward sintering, Al2O3 and ZrO2 resulted in the most stable sorbents due to formation of the mixed phases Ca3Al2O6 and CaZrO3. The two sorbents exhibited a very stable performance with a sorption capacity higher than 9mol of CO2/kg of sorbent after 100 cycles under mild operating conditions (calcination at 850°C under pure N2 flow). On the other hand Ca–Mg and Ca–La demonstrated a significant decay of sorption capacity with more than 30% deactivation after 100 and 70 cycles respectively. Under severe but more realistic conditions (calcination at 950°C under pure CO2 flow), the mixed CaO–Al2O3 sorbent still retained ∼42% of its initial sorption capacity, corresponding to 4.8mol of CO2/kg of sorbent, while CaO–ZrO2 exhibited a remarkable stability, maintaining sorption capacity of 8.5mol of CO2/kg of sorbent after 100 cycles.

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  • Antzara, Andy & Heracleous, Eleni & Lemonidou, Angeliki A., 2015. "Improving the stability of synthetic CaO-based CO2 sorbents by structural promoters," Applied Energy, Elsevier, vol. 156(C), pages 331-343.
    • Handle: RePEc:eee:appene:v:156:y:2015:i:c:p:331-343
    DOI: 10.1016/j.apenergy.2015.07.026
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    1. Vyacheslav V. Rodaev & Svetlana S. Razlivalova, 2021. "Performance and Durability of the Zr-Doped CaO Sorbent under Cyclic Carbonation–Decarbonation at Different Operating Parameters," Energies, MDPI, vol. 14(16), pages 1-9, August.
    2. Chi, Changyun & Li, Yingjie & Zhang, Wan & Wang, Zeyan, 2019. "Synthesis of a hollow microtubular Ca/Al sorbent with high CO2 uptake by hard templating," Applied Energy, Elsevier, vol. 251(C), pages 1-1.
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    5. Francesca Di Lauro & Claudio Tregambi & Fabio Montagnaro & Laura Molignano & Piero Salatino & Roberto Solimene, 2023. "Influence of Fluidised Bed Inventory on the Performance of Limestone Sorbent in Calcium Looping for Thermochemical Energy Storage," Energies, MDPI, vol. 16(19), pages 1-19, October.
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    7. Han, Rui & Gao, Jihui & Wei, Siyu & Su, Yanlin & Sun, Fei & Zhao, Guangbo & Qin, Yukun, 2018. "Strongly coupled calcium carbonate/antioxidative graphite nanosheets composites with high cycling stability for thermochemical energy storage," Applied Energy, Elsevier, vol. 231(C), pages 412-422.
    8. Jing, Jie-ying & Zhang, Xue-wei & Li, Qing & Li, Ting-yu & Li, Wen-ying, 2018. "Self-activation of CaO/Ca3Al2O6 sorbents by thermally pretreated in CO2 atmosphere," Applied Energy, Elsevier, vol. 220(C), pages 419-425.
    9. Theo, Wai Lip & Lim, Jeng Shiun & Hashim, Haslenda & Mustaffa, Azizul Azri & Ho, Wai Shin, 2016. "Review of pre-combustion capture and ionic liquid in carbon capture and storage," Applied Energy, Elsevier, vol. 183(C), pages 1633-1663.
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    12. Su, Chenglin & Duan, Lunbo & Donat, Felix & Anthony, Edward John, 2018. "From waste to high value utilization of spent bleaching clay in synthesizing high-performance calcium-based sorbent for CO2 capture," Applied Energy, Elsevier, vol. 210(C), pages 117-126.
    13. Mutch, Greg A. & Anderson, James A. & Vega-Maza, David, 2017. "Surface and bulk carbonate formation in calcium oxide during CO2 capture," Applied Energy, Elsevier, vol. 202(C), pages 365-376.
    14. Vyacheslav V. Rodaev & Svetlana S. Razlivalova, 2020. "The Zr-Doped CaO CO 2 Sorbent Fabricated by Wet High-Energy Milling," Energies, MDPI, vol. 13(16), pages 1-7, August.
    15. Benitez-Guerrero, Monica & Valverde, Jose Manuel & Perejon, Antonio & Sanchez-Jimenez, Pedro E. & Perez-Maqueda, Luis A., 2018. "Low-cost Ca-based composites synthesized by biotemplate method for thermochemical energy storage of concentrated solar power," Applied Energy, Elsevier, vol. 210(C), pages 108-116.
    16. Jing, Jie-ying & Li, Ting-yu & Zhang, Xue-wei & Wang, Shi-dong & Feng, Jie & Turmel, William A. & Li, Wen-ying, 2017. "Enhanced CO2 sorption performance of CaO/Ca3Al2O6 sorbents and its sintering-resistance mechanism," Applied Energy, Elsevier, vol. 199(C), pages 225-233.
    17. Gong, Xuzhong & Zhang, Tong & Zhang, Junqiang & Wang, Zhi & Liu, Junhao & Cao, Jianwei & Wang, Chuan, 2022. "Recycling and utilization of calcium carbide slag - current status and new opportunities," Renewable and Sustainable Energy Reviews, Elsevier, vol. 159(C).
    18. Shi, Jiewen & Li, Yingjie & Zhang, Qing & Ma, Xiaotong & Duan, Lunbo & Zhou, Xingang, 2017. "CO2 capture performance of a novel synthetic CaO/sepiolite sorbent at calcium looping conditions," Applied Energy, Elsevier, vol. 203(C), pages 412-421.
    19. Akbari-Emadabadi, S. & Rahimpour, M.R. & Hafizi, A. & Keshavarz, P., 2017. "Production of hydrogen-rich syngas using Zr modified Ca-Co bifunctional catalyst-sorbent in chemical looping steam methane reforming," Applied Energy, Elsevier, vol. 206(C), pages 51-62.
    20. Ma, Xiaotong & Li, Yingjie & Duan, Lunbo & Anthony, Edward & Liu, Hantao, 2018. "CO2 capture performance of calcium-based synthetic sorbent with hollow core-shell structure under calcium looping conditions," Applied Energy, Elsevier, vol. 225(C), pages 402-412.
    21. Zhang, Wan & Li, Yingjie & He, Zirui & Ma, Xiaotong & Song, Haiping, 2017. "CO2 capture by carbide slag calcined under high-concentration steam and energy requirement in calcium looping conditions," Applied Energy, Elsevier, vol. 206(C), pages 869-878.

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