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Strongly coupled calcium carbonate/antioxidative graphite nanosheets composites with high cycling stability for thermochemical energy storage

Author

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  • Han, Rui
  • Gao, Jihui
  • Wei, Siyu
  • Su, Yanlin
  • Sun, Fei
  • Zhao, Guangbo
  • Qin, Yukun

Abstract

Reversible carbonation/calcination of CaCO3 is a promising technology for thermochemical energy storage in concentrated solar power plants. However, the major drawback of this technology is the rapid deactivation of CaO due to sintering. In this study, newly developed CaCO3/graphite nanosheets composites were synthesized as the heat storage medium through a one-pot route varying the graphite nanosheets load (3–12 wt%). The impregnation of the composites with H3BO3 solutions enhance the initial weightlessness temperature of graphite nanosheets from 900 °C to 1050 °C in pure CO2 atmosphere, thus upgrading the stability of graphite nanosheets during heat storage/release process. The performances of the synthesized composites were evaluated by thermogravimetric analysis, which simulates the heat storage cycle. The composites showed improved heat storage/output capacity and faster heat input/output rate compared to pure CaCO3. Only 3 wt% of graphite nanosheets was needed to effectively stabilize the heat storage capacity of the material. The heat storage capacity of composites with 3 wt% graphite nanosheets is 1313 kJ/kgcomposite after 50 cycles, corresponding to 2.9 times as much as that of pure CaCO3. This high stability is attributed to the unique synthetic strategy in which the CaCO3 nanoparticles uniformly coated on graphite nanosheets surface, and their sintering and aggregation were prevented. This work brings the development of this technology to a level closer to its industrial application.

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  • Han, Rui & Gao, Jihui & Wei, Siyu & Su, Yanlin & Sun, Fei & Zhao, Guangbo & Qin, Yukun, 2018. "Strongly coupled calcium carbonate/antioxidative graphite nanosheets composites with high cycling stability for thermochemical energy storage," Applied Energy, Elsevier, vol. 231(C), pages 412-422.
    • Handle: RePEc:eee:appene:v:231:y:2018:i:c:p:412-422
    DOI: 10.1016/j.apenergy.2018.09.142
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    as
    1. Yu, Ching-tsung & Kuo, Huan-ting & Chen, Yi-ming, 2016. "Carbon dioxide removal using calcium aluminate carbonates on titanic oxide under warm-gas conditions," Applied Energy, Elsevier, vol. 162(C), pages 1122-1130.
    2. Zhang, Zhengguo & Zhang, Ni & Peng, Jing & Fang, Xiaoming & Gao, Xuenong & Fang, Yutang, 2012. "Preparation and thermal energy storage properties of paraffin/expanded graphite composite phase change material," Applied Energy, Elsevier, vol. 91(1), pages 426-431.
    3. Chen, Huichao & Zhang, Pingping & Duan, Yufeng & Zhao, Changsui, 2016. "Reactivity enhancement of calcium based sorbents by doped with metal oxides through the sol–gel process," Applied Energy, Elsevier, vol. 162(C), pages 390-400.
    4. Ma, Xiaotong & Li, Yingjie & Shi, Lei & He, Zirui & Wang, Zeyan, 2016. "Fabrication and CO2 capture performance of magnesia-stabilized carbide slag by by-product of biodiesel during calcium looping process," Applied Energy, Elsevier, vol. 168(C), pages 85-95.
    5. Pardo, P. & Deydier, A. & Anxionnaz-Minvielle, Z. & Rougé, S. & Cabassud, M. & Cognet, P., 2014. "A review on high temperature thermochemical heat energy storage," Renewable and Sustainable Energy Reviews, Elsevier, vol. 32(C), pages 591-610.
    6. Wang, Tingyu & Jiang, Yan & Huang, Jin & Wang, Shuangfeng, 2018. "High thermal conductive paraffin/calcium carbonate phase change microcapsules based composites with different carbon network," Applied Energy, Elsevier, vol. 218(C), pages 184-191.
    7. Hafizi, A. & Rahimpour, M.R. & Hassanajili, S., 2016. "High purity hydrogen production via sorption enhanced chemical looping reforming: Application of 22Fe2O3/MgAl2O4 and 22Fe2O3/Al2O3 as oxygen carriers and cerium promoted CaO as CO2 sorbent," Applied Energy, Elsevier, vol. 169(C), pages 629-641.
    8. Biswas, Kaushik & Lu, Jue & Soroushian, Parviz & Shrestha, Som, 2014. "Combined experimental and numerical evaluation of a prototype nano-PCM enhanced wallboard," Applied Energy, Elsevier, vol. 131(C), pages 517-529.
    9. Antzara, Andy & Heracleous, Eleni & Lemonidou, Angeliki A., 2015. "Improving the stability of synthetic CaO-based CO2 sorbents by structural promoters," Applied Energy, Elsevier, vol. 156(C), pages 331-343.
    10. Wang, Weilong & Yang, Xiaoxi & Fang, Yutang & Ding, Jing & Yan, Jinyue, 2009. "Preparation and thermal properties of polyethylene glycol/expanded graphite blends for energy storage," Applied Energy, Elsevier, vol. 86(9), pages 1479-1483, September.
    11. Sanchez-Jimenez, P.E. & Perez-Maqueda, L.A. & Valverde, J.M., 2014. "Nanosilica supported CaO: A regenerable and mechanically hard CO2 sorbent at Ca-looping conditions," Applied Energy, Elsevier, vol. 118(C), pages 92-99.
    12. Santos, Sérgio F. & Fitiwi, Desta Z. & Cruz, Marco R.M. & Cabrita, Carlos M.P. & Catalão, João P.S., 2017. "Impacts of optimal energy storage deployment and network reconfiguration on renewable integration level in distribution systems," Applied Energy, Elsevier, vol. 185(P1), pages 44-55.
    13. Qin, Changlei & Yin, Junjun & Feng, Bo & Ran, Jingyu & Zhang, Li & Manovic, Vasilije, 2016. "Modelling of the calcination behaviour of a uniformly-distributed CuO/CaCO3 particle in Ca–Cu chemical looping," Applied Energy, Elsevier, vol. 164(C), pages 400-410.
    14. Benitez-Guerrero, Monica & Valverde, Jose Manuel & Perejon, Antonio & Sanchez-Jimenez, Pedro E. & Perez-Maqueda, Luis A., 2018. "Low-cost Ca-based composites synthesized by biotemplate method for thermochemical energy storage of concentrated solar power," Applied Energy, Elsevier, vol. 210(C), pages 108-116.
    15. Tian, Y. & Zhao, C.Y., 2013. "A review of solar collectors and thermal energy storage in solar thermal applications," Applied Energy, Elsevier, vol. 104(C), pages 538-553.
    16. Fan, Li-Wu & Fang, Xin & Wang, Xiao & Zeng, Yi & Xiao, Yu-Qi & Yu, Zi-Tao & Xu, Xu & Hu, Ya-Cai & Cen, Ke-Fa, 2013. "Effects of various carbon nanofillers on the thermal conductivity and energy storage properties of paraffin-based nanocomposite phase change materials," Applied Energy, Elsevier, vol. 110(C), pages 163-172.
    17. Wang, Ke & Hu, Xiumeng & Zhao, Pengfei & Yin, Zeguang, 2016. "Natural dolomite modified with carbon coating for cyclic high-temperature CO2 capture," Applied Energy, Elsevier, vol. 165(C), pages 14-21.
    18. Korhammer, Kathrin & Druske, Mona-Maria & Fopah-Lele, Armand & Rammelberg, Holger Urs & Wegscheider, Nina & Opel, Oliver & Osterland, Thomas & Ruck, Wolfgang, 2016. "Sorption and thermal characterization of composite materials based on chlorides for thermal energy storage," Applied Energy, Elsevier, vol. 162(C), pages 1462-1472.
    19. Mastronardo, E. & Bonaccorsi, L. & Kato, Y. & Piperopoulos, E. & Milone, C., 2016. "Efficiency improvement of heat storage materials for MgO/H2O/Mg(OH)2 chemical heat pumps," Applied Energy, Elsevier, vol. 162(C), pages 31-39.
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    Cited by:

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    2. Ying Yang & Yingjie Li & Xianyao Yan & Jianli Zhao & Chunxiao Zhang, 2021. "Development of Thermochemical Heat Storage Based on CaO/CaCO 3 Cycles: A Review," Energies, MDPI, vol. 14(20), pages 1-26, October.
    3. Chen, Chen & Kong, Mingmin & Zhou, Shuiqing & Sepulveda, Abdon E. & Hong, Hui, 2020. "Energy storage efficiency optimization of methane reforming with CO2 reactors for solar thermochemical energy storage☆," Applied Energy, Elsevier, vol. 266(C).
    4. Sun, Hao & Li, Yingjie & Yan, Xianyao & Zhao, Jianli & Wang, Zeyan, 2020. "Thermochemical energy storage performance of Al2O3/CeO2 co-doped CaO-based material under high carbonation pressure," Applied Energy, Elsevier, vol. 263(C).
    5. Chen, Xiaoyi & Dong, Zhenbiao & Zhu, Liujuan & Ling, Xiang, 2023. "Mass transfer performance inside Ca-based thermochemical energy storage materials under different operating conditions," Renewable Energy, Elsevier, vol. 205(C), pages 340-348.
    6. Han, Rui & Xing, Shuang & Wu, Xueqian & Pang, Caihong & Lu, Shuangchun & Su, Yun & Liu, Qingling & Song, Chunfeng & Gao, Jihui, 2022. "Relevant influence of alkali carbonate doping on the thermochemical energy storage of Ca-based natural minerals during CaO/CaCO3 cycles," Renewable Energy, Elsevier, vol. 181(C), pages 267-277.
    7. Xu, T.X. & Tian, X.K. & Khosa, A.A. & Yan, J. & Ye, Q. & Zhao, C.Y., 2021. "Reaction performance of CaCO3/CaO thermochemical energy storage with TiO2 dopant and experimental study in a fixed-bed reactor," Energy, Elsevier, vol. 236(C).

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