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Performance assessment of partially sulfonated PVdF-co-HFP as polymer electrolyte membranes in single chambered microbial fuel cells

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  • Kumar, Vikash
  • Nandy, Arpita
  • Das, Suparna
  • Salahuddin, M.
  • Kundu, Patit P.

Abstract

In the present study, PVdF-co-HFP copolymer and its sulfonated derivatives have been analyzed as polymer electrolyte membrane in single chamber MFCs. The sulfonation of PVdF-co-HFP copolymer was performed by treating with chlorosulfonic acid for 5, 7 and 9h, resulting in 23%, 30%, and 18% of degree of sulfonation (DS) in the respective SP-5, SP-7, and SP-9 membranes. On observing the membranes under field emission scanning electron microscope fitted with EDAX, porosity was found to be increasing with increase in the duration of sulfonation except for 9h duration. The elemental analysis of the membranes indicated the presence of higher sulfur and oxygen content with the increasing sulfonation duration except for 9h duration, for which crosslinks were formed via sulfone linkages. The membranes were characterized for their ion exchange capacity (IEC) and proton conductivity; IEC value of 0.21meqg−1, 0.42meqg−1, and 0.12meqg−1 and proton conductivity of 0.0012Scm−1, 0.00363Scm−1, and 0.0006Scm−1 were observed for SP-5, SP-7, and SP-9 membranes. Open air cathode MFCs with membrane electrode assemblies (MEA) containing sulfonated and non-sulfonated PVdF-co-HFP membranes have been analyzed for their overall MFC performance. It was observed that amongst these membranes, MFC with SP-7 membrane showed the maximum power and current density of 290.176±15mWm−2 and 1390.866±70mAm−2 with an overall ∼89% COD removal in 28days operation, using electrogenic mixed firmicute consortium. In overall, the study illustrates the impression of sulfonated PVdF-co-HFP membranes as PEM and its application in MFC for harvesting bio-energy.

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  • Kumar, Vikash & Nandy, Arpita & Das, Suparna & Salahuddin, M. & Kundu, Patit P., 2015. "Performance assessment of partially sulfonated PVdF-co-HFP as polymer electrolyte membranes in single chambered microbial fuel cells," Applied Energy, Elsevier, vol. 137(C), pages 310-321.
    • Handle: RePEc:eee:appene:v:137:y:2015:i:c:p:310-321
    DOI: 10.1016/j.apenergy.2014.09.073
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    1. Li, Xiaojing & Wang, Xin & Zhang, Yueyong & Ding, Ning & Zhou, Qixing, 2014. "Opening size optimization of metal matrix in rolling-pressed activated carbon air–cathode for microbial fuel cells," Applied Energy, Elsevier, vol. 123(C), pages 13-18.
    2. Raman, Kumaran & Lan, John Chi-Wei, 2012. "Performance and kinetic study of photo microbial fuel cells (PMFCs) with different electrode distances," Applied Energy, Elsevier, vol. 100(C), pages 100-105.
    3. Sevda, Surajbhan & Dominguez-Benetton, Xochitl & Vanbroekhoven, Karolien & De Wever, Heleen & Sreekrishnan, T.R. & Pant, Deepak, 2013. "High strength wastewater treatment accompanied by power generation using air cathode microbial fuel cell," Applied Energy, Elsevier, vol. 105(C), pages 194-206.
    4. Lobato, Justo & González del Campo, Araceli & Fernández, Francisco J. & Cañizares, Pablo & Rodrigo, Manuel A., 2013. "Lagooning microbial fuel cells: A first approach by coupling electricity-producing microorganisms and algae," Applied Energy, Elsevier, vol. 110(C), pages 220-226.
    5. Li, Weiqing & Zhang, Shaohui & Chen, Gang & Hua, Yumei, 2014. "Simultaneous electricity generation and pollutant removal in microbial fuel cell with denitrifying biocathode over nitrite," Applied Energy, Elsevier, vol. 126(C), pages 136-141.
    6. Chen, Man & Zhang, Fang & Zhang, Yan & Zeng, Raymond J., 2013. "Alkali production from bipolar membrane electrodialysis powered by microbial fuel cell and application for biogas upgrading," Applied Energy, Elsevier, vol. 103(C), pages 428-434.
    7. Wang, Yong-Peng & Liu, Xian-Wei & Li, Wen-Wei & Li, Feng & Wang, Yun-Kun & Sheng, Guo-Ping & Zeng, Raymond J. & Yu, Han-Qing, 2012. "A microbial fuel cell–membrane bioreactor integrated system for cost-effective wastewater treatment," Applied Energy, Elsevier, vol. 98(C), pages 230-235.
    8. Rahimnejad, Mostafa & Ghoreyshi, Ali Asghar & Najafpour, Ghasem & Jafary, Tahereh, 2011. "Power generation from organic substrate in batch and continuous flow microbial fuel cell operations," Applied Energy, Elsevier, vol. 88(11), pages 3999-4004.
    9. Chen, Yinguang & Luo, Jingyang & Yan, Yuanyuan & Feng, Leiyu, 2013. "Enhanced production of short-chain fatty acid by co-fermentation of waste activated sludge and kitchen waste under alkaline conditions and its application to microbial fuel cells," Applied Energy, Elsevier, vol. 102(C), pages 1197-1204.
    10. Das, Suparna & Kumar, Piyush & Dutta, Kingshuk & Kundu, Patit Paban, 2014. "Partial sulfonation of PVdF-co-HFP: A preliminary study and characterization for application in direct methanol fuel cell," Applied Energy, Elsevier, vol. 113(C), pages 169-177.
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    2. Song, Bing-Ye & He, Yan & He, Ya-Ling & Huang, Dong & Zhang, Yu-Wen, 2019. "Experimental study on anode components optimization for direct glucose fuel cells," Energy, Elsevier, vol. 176(C), pages 15-22.

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