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Alternative approach to estimate the hydrolysis rate constant of particulate material from batch data

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  • Koch, Konrad
  • Drewes, Jörg E.

Abstract

As anaerobic batch tests are easy to conduct, they are commonly used to assess the effects of different operational factors on the anaerobic digestion process. Hydrolysis of particulate material is often assumed to be the rate limiting step in anaerobic digestion. Its velocity is often estimated by data fitting from batch tests. In this study, a Monod-type alternative to the commonly used first-order approach is presented. The approach was adapted from balancing a continuously stirred-tank reactor and better accommodates the fact that even after a long incubation time, some of the methane potential of the substrate remains untapped in the digestate. In addition, an equation is proposed to directly calculate the hydrolysis constant from the time when the daily gas production is less than 1% of the total gas production. The hydrolysis constant can then easily be read-off from a table when the batch test duration is known.

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  • Koch, Konrad & Drewes, Jörg E., 2014. "Alternative approach to estimate the hydrolysis rate constant of particulate material from batch data," Applied Energy, Elsevier, vol. 120(C), pages 11-15.
    • Handle: RePEc:eee:appene:v:120:y:2014:i:c:p:11-15
    DOI: 10.1016/j.apenergy.2014.01.050
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    4. Chowdhury, M.M.I. & Nakhla, G. & Zhu, J., 2017. "Ultrasonically enhanced anaerobic digestion of thickened waste activated sludge using fluidized bed reactors," Applied Energy, Elsevier, vol. 204(C), pages 807-818.
    5. Ebenezer, A. Vimala & Arulazhagan, P. & Adish Kumar, S. & Yeom, Ick-Tae & Rajesh Banu, J., 2015. "Effect of deflocculation on the efficiency of low-energy microwave pretreatment and anaerobic biodegradation of waste activated sludge," Applied Energy, Elsevier, vol. 145(C), pages 104-110.
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    7. Sohoo, Ihsanullah & Ritzkowski, Marco & Heerenklage, Jörn & Kuchta, Kerstin, 2021. "Biochemical methane potential assessment of municipal solid waste generated in Asian cities: A case study of Karachi, Pakistan," Renewable and Sustainable Energy Reviews, Elsevier, vol. 135(C).
    8. Koch, Konrad & Helmreich, Brigitte & Drewes, Jörg E., 2015. "Co-digestion of food waste in municipal wastewater treatment plants: Effect of different mixtures on methane yield and hydrolysis rate constant," Applied Energy, Elsevier, vol. 137(C), pages 250-255.
    9. Li, Yangyang & Jin, Yiying & Li, Jinhui & Li, Hailong & Yu, Zhixin & Nie, Yongfeng, 2017. "Effects of thermal pretreatment on degradation kinetics of organics during kitchen waste anaerobic digestion," Energy, Elsevier, vol. 118(C), pages 377-386.
    10. Li, Yangyang & Jin, Yiying & Li, Jinhui & Li, Hailong & Yu, Zhixin, 2016. "Effects of pungency degree on mesophilic anaerobic digestion of kitchen waste," Applied Energy, Elsevier, vol. 181(C), pages 171-178.
    11. Li, Yangyang & Jin, Yiying & Li, Jinhui & Li, Hailong & Yu, Zhixin, 2016. "Effects of thermal pretreatment on the biomethane yield and hydrolysis rate of kitchen waste," Applied Energy, Elsevier, vol. 172(C), pages 47-58.
    12. Dandikas, Vasilis & Heuwinkel, Hauke & Lichti, Fabian & Eckl, Thomas & Drewes, Jörg E. & Koch, Konrad, 2018. "Correlation between hydrolysis rate constant and chemical composition of energy crops," Renewable Energy, Elsevier, vol. 118(C), pages 34-42.
    13. Lei Zhu & Jiahou Hao & Houwei Lai & Guibai Li, 2022. "Effects of pH Adjustment on the Release of Carbon Source of Particulate Organic Matter (POM) in Domestic Sewage," Sustainability, MDPI, vol. 14(13), pages 1-15, June.

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