IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v16y2025i1d10.1038_s41467-025-59896-8.html
   My bibliography  Save this article

Inductive effects in molecular contacts enable wide-bandgap perovskite cells for efficient perovskite/TOPCon tandems

Author

Listed:
  • Yixin Luo

    (Zhejiang University)

  • Yuan Tian

    (Zhejiang University
    Westlake Institute for Advanced Study)

  • Ke Zhao

    (Zhejiang University
    Westlake Institute for Advanced Study)

  • Weiping Mao

    (Jietai New Energy Technology Co., Ltd)

  • Chen Liu

    (Yangzhou University)

  • Jiahui Shen

    (Westlake Institute for Advanced Study
    Yangzhou University)

  • Zhendong Cheng

    (Westlake Institute for Advanced Study)

  • Caner Değer

    (Ziverbey)

  • Xiaohe Miao

    (Westlake University)

  • Zhongwei Zhang

    (Dongfang Electric (Hangzhou) Innovation Institute Co., Ltd.)

  • Xuechun Sun

    (Zhejiang University
    Westlake Institute for Advanced Study)

  • Libing Yao

    (Westlake Institute for Advanced Study)

  • Xu Zhang

    (Zhejiang University
    Westlake Institute for Advanced Study)

  • Pengju Shi

    (Zhejiang University
    Westlake Institute for Advanced Study)

  • Donger Jin

    (Zhejiang University)

  • Jiaxiao Deng

    (Jietai New Energy Technology Co., Ltd)

  • Mengyuan Tian

    (Jietai New Energy Technology Co., Ltd)

  • Ilhan Yavuz

    (Ziverbey)

  • Na Dong

    (Dongfang Electric (Hangzhou) Innovation Institute Co., Ltd.)

  • Ruzhang Liu

    (Yangzhou University)

  • Rui Wang

    (Westlake Institute for Advanced Study)

  • Deren Yang

    (Zhejiang University)

  • Jingjing Xue

    (Zhejiang University
    Shangyu Institute of Semiconductor Materials)

Abstract

Organic molecules that serve as hole-selective contacts, known as self-assembled monolayers (SAMs), play a pivotal role in ensuring high-performance perovskite photovoltaics. Optimal energy alignment between the SAM and the perovskite is essential for desired photovoltaic performance. However, many SAMs are studied in optimal-bandgap perovskites, with limited energy level modification specifically catering to wide-bandgap perovskites. Herein, we demonstrate that the energy level of SAMs can be systematically tuned in a stepwise manner via inductive effects in the conjugated moieties, enabling rational design tailored for specific perovskite bandgaps. The resulting WBG perovskite device based on our tuned SAM achieved a power conversion efficiency (PCE) of 22.8%. Integration with crystalline silicon TOPCon subcells further enabled the construction of a perovskite/TOPCon tandem device with a PCE of 31.1% (certified 30.9%).

Suggested Citation

  • Yixin Luo & Yuan Tian & Ke Zhao & Weiping Mao & Chen Liu & Jiahui Shen & Zhendong Cheng & Caner Değer & Xiaohe Miao & Zhongwei Zhang & Xuechun Sun & Libing Yao & Xu Zhang & Pengju Shi & Donger Jin & J, 2025. "Inductive effects in molecular contacts enable wide-bandgap perovskite cells for efficient perovskite/TOPCon tandems," Nature Communications, Nature, vol. 16(1), pages 1-9, December.
  • Handle: RePEc:nat:natcom:v:16:y:2025:i:1:d:10.1038_s41467-025-59896-8
    DOI: 10.1038/s41467-025-59896-8
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-025-59896-8
    File Function: Abstract
    Download Restriction: no

    File URL: https://libkey.io/10.1038/s41467-025-59896-8?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:16:y:2025:i:1:d:10.1038_s41467-025-59896-8. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    We have no bibliographic references for this item. You can help adding them by using this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.