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Efficient all-small-molecule organic solar cells processed with non-halogen solvent

Author

Listed:
  • Wei Gao

    (Huaqiao University)

  • Ruijie Ma

    (The Hong Kong Polytechnic University)

  • Top Archie Dela Peña

    (The Hong Kong Polytechnic University
    The Hong Kong University of Science and Technology)

  • Cenqi Yan

    (Sichuan University)

  • Hongxiang Li

    (Sichuan University)

  • Mingjie Li

    (The Hong Kong Polytechnic University)

  • Jiaying Wu

    (The Hong Kong University of Science and Technology)

  • Pei Cheng

    (Sichuan University)

  • Cheng Zhong

    (Wuhan University)

  • Zhanhua Wei

    (Huaqiao University)

  • Alex K.-Y. Jen

    (City University of Hong Kong
    City University of Hong Kong)

  • Gang Li

    (The Hong Kong Polytechnic University)

Abstract

All-small-molecule organic solar cells with good batch-to-batch reproducibility combined with non-halogen solvent processing show great potential for commercialization. However, non-halogen solvent processing of all-small-molecule organic solar cells are rarely reported and its power conversion efficiencies are very difficult to improve. Herein, we designed and synthesized a small molecule donor BM-ClEH that can take advantage of strong aggregation property induced by intramolecular chlorine-sulfur non-covalent interaction to improve molecular pre-aggregation in tetrahydrofuran and corresponding micromorphology after film formation. Tetrahydrofuran-fabricated all-small-molecule organic solar cells based on BM-ClEH:BO-4Cl achieved high power conversion efficiencies of 15.0% in binary device and 16.1% in ternary device under thermal annealing treatment. In contrast, weakly aggregated BM-HEH without chlorine-sulfur non-covalent bond is almost inefficient under same processing conditions due to poor pre-aggregation induced disordered π-π stacking, indistinct phase separation and exciton dissociation. This work promotes the development of non-halogen solvent processing of all-small-molecule organic solar cells and provides further guidance.

Suggested Citation

  • Wei Gao & Ruijie Ma & Top Archie Dela Peña & Cenqi Yan & Hongxiang Li & Mingjie Li & Jiaying Wu & Pei Cheng & Cheng Zhong & Zhanhua Wei & Alex K.-Y. Jen & Gang Li, 2024. "Efficient all-small-molecule organic solar cells processed with non-halogen solvent," Nature Communications, Nature, vol. 15(1), pages 1-14, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-46144-8
    DOI: 10.1038/s41467-024-46144-8
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    1. Chao Li & Jiadong Zhou & Jiali Song & Jinqiu Xu & Huotian Zhang & Xuning Zhang & Jing Guo & Lei Zhu & Donghui Wei & Guangchao Han & Jie Min & Yuan Zhang & Zengqi Xie & Yuanping Yi & He Yan & Feng Gao , 2021. "Non-fullerene acceptors with branched side chains and improved molecular packing to exceed 18% efficiency in organic solar cells," Nature Energy, Nature, vol. 6(6), pages 605-613, June.
    2. Yanxun Li & Bo Huang & Xuning Zhang & Jianwei Ding & Yingyu Zhang & Linge Xiao & Boxin Wang & Qian Cheng & Gaosheng Huang & Hong Zhang & Yingguo Yang & Xiaoying Qi & Qiang Zheng & Yuan Zhang & Xiaohui, 2023. "Lifetime over 10000 hours for organic solar cells with Ir/IrOx electron-transporting layer," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    3. Ruimin Zhou & Zhaoyan Jiang & Chen Yang & Jianwei Yu & Jirui Feng & Muhammad Abdullah Adil & Dan Deng & Wenjun Zou & Jianqi Zhang & Kun Lu & Wei Ma & Feng Gao & Zhixiang Wei, 2019. "All-small-molecule organic solar cells with over 14% efficiency by optimizing hierarchical morphologies," Nature Communications, Nature, vol. 10(1), pages 1-9, December.
    4. Zichun Zhou & Shengjie Xu & Jingnan Song & Yingzhi Jin & Qihui Yue & Yuhao Qian & Feng Liu & Fengling Zhang & Xiaozhang Zhu, 2018. "High-efficiency small-molecule ternary solar cells with a hierarchical morphology enabled by synergizing fullerene and non-fullerene acceptors," Nature Energy, Nature, vol. 3(11), pages 952-959, November.
    5. Baobing Fan & Wei Gao & Xuanhao Wu & Xinxin Xia & Yue Wu & Francis R. Lin & Qunping Fan & Xinhui Lu & Wen Jung Li & Wei Ma & Alex K.-Y. Jen, 2022. "Importance of structural hinderance in performance–stability equilibrium of organic photovoltaics," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    6. Rui He & Wanhai Wang & Zongjin Yi & Felix Lang & Cong Chen & Jincheng Luo & Jingwei Zhu & Jarla Thiesbrummel & Sahil Shah & Kun Wei & Yi Luo & Changlei Wang & Huagui Lai & Hao Huang & Jie Zhou & Bings, 2023. "Improving interface quality for 1-cm2 all-perovskite tandem solar cells," Nature, Nature, vol. 618(7963), pages 80-86, June.
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