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Critical Progress of Polymer Solar Cells with a Power Conversion Efficiency over 18%

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  • Hongyue Tian

    (School of Physical Science and Engineering, Beijing Jiaotong University, Beijing 100044, China
    These authors contributed equally to this work.)

  • Mingxin Zhao

    (School of Physical Science and Engineering, Beijing Jiaotong University, Beijing 100044, China
    These authors contributed equally to this work.)

  • Xiaoling Ma

    (School of Physical Science and Engineering, Beijing Jiaotong University, Beijing 100044, China)

  • Chunyu Xu

    (School of Physical Science and Engineering, Beijing Jiaotong University, Beijing 100044, China)

  • Wenjing Xu

    (School of Physical Science and Engineering, Beijing Jiaotong University, Beijing 100044, China)

  • Zhongyuan Liu

    (School of Physical Science and Engineering, Beijing Jiaotong University, Beijing 100044, China)

  • Miao Zhang

    (Department of Applied Biology and Chemical Technology and Research Institute for Smart Energy, The Hong Kong Polytechnic University, Hung Hom, Hong Kong, China)

  • Fujun Zhang

    (School of Physical Science and Engineering, Beijing Jiaotong University, Beijing 100044, China)

Abstract

The power conversion efficiencies (PCEs) of organic photovoltaics (OPVs) have reached more than 19%, along with the prosperous development of materials and device engineering. It is meaningful to make a comprehensive review of the research of OPVs for further performance improvement. In this review, some typical materials of high-performance OPVs are summarized, including representative polymer donor materials, non-fullerene acceptor materials, and interfacial modification materials, as well as their design rules for molecular engineering. From the point of view of device engineering, active layer treatment and deposition technology are introduced, which can play a critical role in adjusting the degree of molecular aggregation and vertical distribution. Meanwhile, a ternary strategy has been confirmed as an efficient method for improving the performance of OPVs, and the multiple roles of the appropriate third component in the photo-electronic conversion process are emphasized and analyzed. The challenges and perspectives concerning this region are also put forward for further developing high-performance OPVs.

Suggested Citation

  • Hongyue Tian & Mingxin Zhao & Xiaoling Ma & Chunyu Xu & Wenjing Xu & Zhongyuan Liu & Miao Zhang & Fujun Zhang, 2023. "Critical Progress of Polymer Solar Cells with a Power Conversion Efficiency over 18%," Energies, MDPI, vol. 16(11), pages 1-34, June.
    • Handle: RePEc:gam:jeners:v:16:y:2023:i:11:p:4494-:d:1162655
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    References listed on IDEAS

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    1. Chao Li & Jiadong Zhou & Jiali Song & Jinqiu Xu & Huotian Zhang & Xuning Zhang & Jing Guo & Lei Zhu & Donghui Wei & Guangchao Han & Jie Min & Yuan Zhang & Zengqi Xie & Yuanping Yi & He Yan & Feng Gao , 2021. "Non-fullerene acceptors with branched side chains and improved molecular packing to exceed 18% efficiency in organic solar cells," Nature Energy, Nature, vol. 6(6), pages 605-613, June.
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