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Strain engineering of two-dimensional multilayered heterostructures for beyond-lithium-based rechargeable batteries

Author

Listed:
  • Pan Xiong

    (University of Technology)

  • Fan Zhang

    (University of Technology)

  • Xiuyun Zhang

    (Yangzhou University)

  • Shijian Wang

    (University of Technology)

  • Hao Liu

    (University of Technology)

  • Bing Sun

    (University of Technology)

  • Jinqiang Zhang

    (University of Technology)

  • Yi Sun

    (Yangzhou University)

  • Renzhi Ma

    (International Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science (NIMS))

  • Yoshio Bando

    (International Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science (NIMS))

  • Cuifeng Zhou

    (The University of Sydney)

  • Zongwen Liu

    (The University of Sydney)

  • Takayoshi Sasaki

    (International Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science (NIMS))

  • Guoxiu Wang

    (University of Technology)

Abstract

Beyond-lithium-ion batteries are promising candidates for high-energy-density, low-cost and large-scale energy storage applications. However, the main challenge lies in the development of suitable electrode materials. Here, we demonstrate a new type of zero-strain cathode for reversible intercalation of beyond-Li+ ions (Na+, K+, Zn2+, Al3+) through interface strain engineering of a 2D multilayered VOPO4-graphene heterostructure. In-situ characterization and theoretical calculations reveal a reversible intercalation mechanism of cations in the 2D multilayered heterostructure with a negligible volume change. When applied as cathodes in K+-ion batteries, we achieve a high specific capacity of 160 mA h g−1 and a large energy density of ~570 W h kg−1, presenting the best reported performance to date. Moreover, the as-prepared 2D multilayered heterostructure can also be extended as cathodes for high-performance Na+, Zn2+, and Al3+-ion batteries. This work heralds a promising strategy to utilize strain engineering of 2D materials for advanced energy storage applications.

Suggested Citation

  • Pan Xiong & Fan Zhang & Xiuyun Zhang & Shijian Wang & Hao Liu & Bing Sun & Jinqiang Zhang & Yi Sun & Renzhi Ma & Yoshio Bando & Cuifeng Zhou & Zongwen Liu & Takayoshi Sasaki & Guoxiu Wang, 2020. "Strain engineering of two-dimensional multilayered heterostructures for beyond-lithium-based rechargeable batteries," Nature Communications, Nature, vol. 11(1), pages 1-12, December.
    • Handle: RePEc:nat:natcom:v:11:y:2020:i:1:d:10.1038_s41467-020-17014-w
    DOI: 10.1038/s41467-020-17014-w
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    Cited by:

    1. Shijian Wang & Xin Guo & Kun Huang & Amritroop Achari & Javad Safaei & Yaojie Lei & Dongfang Li & Qinfen Gu & Chenghua Sun & Lucy Gloag & Steven Langford & Andre Geim & Rahul Raveendran Nair & Guoxiu , 2025. "Cooperative Jahn-Teller effect and engineered long-range strain in manganese oxide/graphene superlattice for aqueous zinc-ion batteries," Nature Communications, Nature, vol. 16(1), pages 1-12, December.
    2. Mali, Vima & Saxena, Rajat & Kumar, Kundan & Kalam, Abul & Tripathi, Brijesh, 2021. "Review on battery thermal management systems for energy-efficient electric vehicles," Renewable and Sustainable Energy Reviews, Elsevier, vol. 151(C).

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