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Metal Supported Electrolysis Cells

Author

Listed:
  • Anke Hagen

    (DTU Energy, Technical University of Denmark, Fysikvej B. 310, 2800 Kongens Lyngby, Denmark)

  • Riccardo Caldogno

    (DTU Energy, Technical University of Denmark, Fysikvej B. 310, 2800 Kongens Lyngby, Denmark
    Politecnico di Milano, Piazza Leonardo da Vinci 32, 20133 Milano, Italy)

  • Federico Capotondo

    (DTU Energy, Technical University of Denmark, Fysikvej B. 310, 2800 Kongens Lyngby, Denmark
    Politecnico di Milano, Piazza Leonardo da Vinci 32, 20133 Milano, Italy)

  • Xiufu Sun

    (DTU Energy, Technical University of Denmark, Fysikvej B. 310, 2800 Kongens Lyngby, Denmark)

Abstract

Solid oxide electrolyser (SOE) technology can become a key player in energy systems, with increasing shares of electricity from fluctuating sources such as wind and solar, contributing to power grid balance and energy storage as well as providing green fuels for transportation. Most mature SOE configurations are electrolyte supported or fuel electrode supported. Metal supported SOE cell configurations are an interesting concept for decreasing costs and increasing robustness. The present study compares fuel electrode supported and metal supported cells in terms of performance and durability under SOE conditions. Special emphasis was on medium temperature operating conditions of 650 °C. Metal supported cells, fabricated using ceramic processing methods, showed a better performance compared to state-of-the-art (SoA) cells with Ni/YSZ fuel electrode supported configuration, fabricated by tape casting and screen printing, under steam electrolysis conditions at 700 and 650 °C. The area specific cell resistance (ASR) was lower by ca. 20% for the metal supported cell in 50% H 2 O in H 2 vs. air at 650 °C. Furthermore, the metal supported cells showed a stable performance—even a slight activation—during long-term steam electrolysis tests over 500 h at 650 °C and −0.25 and −0.5 A/cm 2 , while the SoA reference cell degraded with 13%/1000 h under the same conditions.

Suggested Citation

  • Anke Hagen & Riccardo Caldogno & Federico Capotondo & Xiufu Sun, 2022. "Metal Supported Electrolysis Cells," Energies, MDPI, vol. 15(6), pages 1-12, March.
  • Handle: RePEc:gam:jeners:v:15:y:2022:i:6:p:2045-:d:768634
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    References listed on IDEAS

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    1. Venkatesan Venkata Krishnan, 2017. "Recent developments in metal‐supported solid oxide fuel cells," Wiley Interdisciplinary Reviews: Energy and Environment, Wiley Blackwell, vol. 6(5), September.
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    Cited by:

    1. Abdul Ghani Olabi & Tabbi Wilberforce & Abdulrahman Alanazi & Parag Vichare & Enas Taha Sayed & Hussein M. Maghrabie & Khaled Elsaid & Mohammad Ali Abdelkareem, 2022. "Novel Trends in Proton Exchange Membrane Fuel Cells," Energies, MDPI, vol. 15(14), pages 1-35, July.
    2. Igor Tatarewicz & Sławomir Skwierz & Michał Lewarski & Robert Jeszke & Maciej Pyrka & Monika Sekuła, 2023. "Mapping the Future of Green Hydrogen: Integrated Analysis of Poland and the EU’s Development Pathways to 2050," Energies, MDPI, vol. 16(17), pages 1-27, August.
    3. Mohsen Fallah Vostakola & Hasan Ozcan & Rami S. El-Emam & Bahman Amini Horri, 2023. "Recent Advances in High-Temperature Steam Electrolysis with Solid Oxide Electrolysers for Green Hydrogen Production," Energies, MDPI, vol. 16(8), pages 1-50, April.

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