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Improvement in the Electrochemical Properties of Lithium Metal by Heat Treatment: Changes in the Chemical Composition of Native and Solid Electrolyte Interphase Films

Author

Listed:
  • Paul Maldonado Nogales

    (Department of Energy Systems Engineering, Soonchunhyang University, Soonchunhyang-ro 22-gil, Sinchang-myeon, Asan-si 31538, Korea)

  • Hee-Youb Song

    (Department of Energy Systems Engineering, Soonchunhyang University, Soonchunhyang-ro 22-gil, Sinchang-myeon, Asan-si 31538, Korea)

  • Mun-Hui Jo

    (Department of Energy Systems Engineering, Soonchunhyang University, Soonchunhyang-ro 22-gil, Sinchang-myeon, Asan-si 31538, Korea)

  • Soon-Ki Jeong

    (Department of Energy Systems Engineering, Soonchunhyang University, Soonchunhyang-ro 22-gil, Sinchang-myeon, Asan-si 31538, Korea)

Abstract

This study aims to improve the electrochemical properties of lithium metal for application as a negative electrode in high-energy-density batteries. Lithium metal was heat-treated at varying temperatures to modify the native and solid electrolyte interphase (SEI) films, which decreased the interfacial resistance between the lithium electrode and electrolyte, thereby improving the cycling performance. Moreover, the influence of the native and SEI films on lithium metals depended on the heat-treatment temperature. Accordingly, X-ray photoelectron spectroscopy (XPS) was performed to investigate the chemical composition of the native and SEI films on the heat-treated lithium metals before and after immersion in an organic electrolyte solution. The XPS results revealed the high dependence of the chemical composition of the outer layer of the native and SEI films on the heat-treatment temperature, implying that the native and SEI films can be effectively modified by heat treatment.

Suggested Citation

  • Paul Maldonado Nogales & Hee-Youb Song & Mun-Hui Jo & Soon-Ki Jeong, 2022. "Improvement in the Electrochemical Properties of Lithium Metal by Heat Treatment: Changes in the Chemical Composition of Native and Solid Electrolyte Interphase Films," Energies, MDPI, vol. 15(4), pages 1-9, February.
    • Handle: RePEc:gam:jeners:v:15:y:2022:i:4:p:1419-:d:750144
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    References listed on IDEAS

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    1. Jiangfeng Qian & Wesley A. Henderson & Wu Xu & Priyanka Bhattacharya & Mark Engelhard & Oleg Borodin & Ji-Guang Zhang, 2015. "High rate and stable cycling of lithium metal anode," Nature Communications, Nature, vol. 6(1), pages 1-9, May.
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