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Photocatalysis and photoelectrochemical glucose oxidation on Bi2WO6: Conditions for the concomitant H2 production

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  • Madriz, Lorean
  • Tatá, José
  • Carvajal, David
  • Núñez, Oswaldo
  • Scharifker, Benjamín R.
  • Mostany, Jorge
  • Borrás, Carlos
  • Cabrerizo, Franco M.
  • Vargas, Ronald

Abstract

Glucose solar light photoinduced oxidation on Bi2WO6 and the chemical kinetics conditions for concurrent photoelectrochemical H2 production are reported. The results show that the conversion of this organic compound is determined by their surface concentration according to the Langmuir-Hinshelwood mechanism. The performance of Bi2WO6 powder for the photocatalytic oxidation of glucose is higher than that observed with TiO2-based materials. Glucose degradation and mineralization rates are similar; therefore, stable intermediates are not formed during glucose oxidation. Photoluminescence studies indicate that glucose promotes electron injection into the valence band of semiconductor. The initial glucose concentration in combination with the electrode potential used, determines the H2 production. In fact, electrode potential of 0.9 V vs. SHE and 60 ppm of glucose defines kobs values equal to kK with maximum H2 evolution rate: 3.05 μmol h−1 cm−2. This value arises from the transformation of the 97% of the Faradaic current measured. The phenomenological conditions for renewable energy applications have been envisaged.

Suggested Citation

  • Madriz, Lorean & Tatá, José & Carvajal, David & Núñez, Oswaldo & Scharifker, Benjamín R. & Mostany, Jorge & Borrás, Carlos & Cabrerizo, Franco M. & Vargas, Ronald, 2020. "Photocatalysis and photoelectrochemical glucose oxidation on Bi2WO6: Conditions for the concomitant H2 production," Renewable Energy, Elsevier, vol. 152(C), pages 974-983.
  • Handle: RePEc:eee:renene:v:152:y:2020:i:c:p:974-983
    DOI: 10.1016/j.renene.2020.01.071
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    References listed on IDEAS

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    1. Tang, Liang & Wang, Jing & Liu, Xudong & Shu, Xiaoqing & Zhang, Zhaohong & Wang, Jun, 2019. "Fabrication of Z-scheme photocatalyst, Er3+:Y3Al5O12@NiGa2O4-MWCNTs-WO3, and visible-light photocatalytic activity for degradation of organic pollutant with simultaneous hydrogen evolution," Renewable Energy, Elsevier, vol. 138(C), pages 474-488.
    2. Zhu, Rongshu & Tian, Fei & Yang, Ruijie & He, Jiansheng & Zhong, Jian & Chen, Baiyang, 2019. "Z scheme system ZnIn2S4/RGO/BiVO4 for hydrogen generation from water splitting and simultaneous degradation of organic pollutants under visible light," Renewable Energy, Elsevier, vol. 139(C), pages 22-27.
    3. Yangen Zhou & Yongfan Zhang & Mousheng Lin & Jinlin Long & Zizhong Zhang & Huaxiang Lin & Jeffrey C.-S. Wu & Xuxu Wang, 2015. "Monolayered Bi2WO6 nanosheets mimicking heterojunction interface with open surfaces for photocatalysis," Nature Communications, Nature, vol. 6(1), pages 1-8, November.
    4. Sharma, Shailja & Pai, Mrinal R. & Kaur, Gurpreet & Divya, & Satsangi, Vibha R. & Dass, Sahab & Shrivastav, Rohit, 2019. "Efficient hydrogen generation on CuO core/AgTiO2 shell nano-hetero-structures by photocatalytic splitting of water," Renewable Energy, Elsevier, vol. 136(C), pages 1202-1216.
    5. Laura Clarizia & Danilo Russo & Ilaria Di Somma & Roberto Andreozzi & Raffaele Marotta, 2017. "Hydrogen Generation through Solar Photocatalytic Processes: A Review of the Configuration and the Properties of Effective Metal-Based Semiconductor Nanomaterials," Energies, MDPI, vol. 10(10), pages 1-21, October.
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    2. Sun, Zhen & Wang, Junxiang & Lu, Sen & Zhang, Guan, 2022. "Enzymatic biomass hydrolysis assisted photocatalytic H2 production from water employing porous carbon doped brookite/anatase heterophase titania photocatalyst," Renewable Energy, Elsevier, vol. 197(C), pages 151-160.
    3. Sudhagar Pitchaimuthu & Kishore Sridharan & Sanjay Nagarajan & Sengeni Ananthraj & Peter Robertson & Moritz F. Kuehnel & Ángel Irabien & Mercedes Maroto-Valer, 2022. "Solar Hydrogen Fuel Generation from Wastewater—Beyond Photoelectrochemical Water Splitting: A Perspective," Energies, MDPI, vol. 15(19), pages 1-23, October.

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