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Lipases immobilized on the modified polyporous magnetic cellulose support as an efficient and recyclable catalyst for biodiesel production from Yellow horn seed oil

Author

Listed:
  • Zhang, Huaxia
  • Liu, Tianshu
  • Zhu, Yawei
  • Hong, Li
  • Li, Tianfeng
  • Wang, Xiqing
  • Fu, Yujie

Abstract

In the present study, modified polyporous magnetic cellulose beads (PMCBs) were synthesized by several organic amines (EDA, DETA, TETA and AST) grafting PMCBs and then utilized as a new kind of support to immobilize Candida antarctica lipase B (CALB) for biodiesel production. The immobilized lipase catalysts based on PMCBs were characterized by Fourier transform infrared and scanning electron microscopy. The results showed that PMCBs-DETA was a more suitable immobilization support and the catalytic activity of immobilized lipases could reach 1.0 U/mg. Then the synthesized catalyst of CALB-PMCBs-DETA was used to produce biodiesel from Yellow horn seed oil via transesterification reaction. A high biodiesel yield (92.3%) was obtained under the optimal reaction conditions and the main compositions of the prepared biodiesel were tested by GC-MS. Moreover, the catalyst of CALB-PMCBs-DETA could be removed easily by a magnet and recycled at least 5 times. As a new kind of support, the modified PMCBs could be a promising alternative for the carriers of immobilizing enzymes used for the green and efficient production of biodiesel.

Suggested Citation

  • Zhang, Huaxia & Liu, Tianshu & Zhu, Yawei & Hong, Li & Li, Tianfeng & Wang, Xiqing & Fu, Yujie, 2020. "Lipases immobilized on the modified polyporous magnetic cellulose support as an efficient and recyclable catalyst for biodiesel production from Yellow horn seed oil," Renewable Energy, Elsevier, vol. 145(C), pages 1246-1254.
    • Handle: RePEc:eee:renene:v:145:y:2020:i:c:p:1246-1254
    DOI: 10.1016/j.renene.2019.06.031
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    Cited by:

    1. Khozeymeh Nezhad, Marziyeh & Aghaei, Hamidreza, 2021. "Tosylated cloisite as a new heterofunctional carrier for covalent immobilization of lipase and its utilization for production of biodiesel from waste frying oil," Renewable Energy, Elsevier, vol. 164(C), pages 876-888.
    2. Quayson, Emmanuel & Amoah, Jerome & Hama, Shinji & Kondo, Akihiko & Ogino, Chiaki, 2020. "Immobilized lipases for biodiesel production: Current and future greening opportunities," Renewable and Sustainable Energy Reviews, Elsevier, vol. 134(C).
    3. Hao, Xiaohong & Suo, Hang & Zhang, Guanhua & Xu, Peixing & Gao, Xin & Du, Su, 2021. "Ultrasound-assisted enzymatic preparation of fatty acid ethyl ester in deep eutectic solvent," Renewable Energy, Elsevier, vol. 164(C), pages 937-947.

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