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Equation of state for a charged colloidal system

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  • Herrera, J.N.
  • Blum, L.

Abstract

We obtain the equation of state for a charged colloidal solution, which is represented by a collection of sticky charged hard spheres. The mean spherical approximation (MSA) is used for the ionic part, and the Percus-Yevick (PYA) approximation is used for the sticky part. Explicit expressions are obtained for the pressure in terms of a sticky parameter λ and a screening parameter γ. The pressure diagram indicates a first order phase transition characteristics of colloids.

Suggested Citation

  • Herrera, J.N. & Blum, L., 1996. "Equation of state for a charged colloidal system," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 231(1), pages 330-336.
  • Handle: RePEc:eee:phsmap:v:231:y:1996:i:1:p:330-336
    DOI: 10.1016/0378-4371(95)00449-1
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    1. Philippe Cuneo & Françoise Dupont & Sylvie Mabile, 1987. "1980-1985 : des mutations sectorielles plus profondes que prévu," Économie et Statistique, Programme National Persée, vol. 201(1), pages 43-51.
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