IDEAS home Printed from https://ideas.repec.org/a/eee/phsmap/v184y1992i3p393-414.html
   My bibliography  Save this article

Composition fluctuations and the geometry of phase diagrams in multicomponent mixtures

Author

Listed:
  • Teubner, Max

Abstract

The connection between the composition fluctuations and the geometry of the phase diagram, discussed previously for ternary mixtures, is extended to mixtures of arbitrary many components. It is shown that for two coexisting phases the phase diagram determines all but n + 1 of the n(n + 1) independent fluctuations in the two phases. For three coexisting phases all the composition fluctuations in the three phases are determined by the phase diagram up to a scale factor. New geometric constraints on phase diagrams are derived. For four-component mixtures the constraints are determined explicitly.

Suggested Citation

  • Teubner, Max, 1992. "Composition fluctuations and the geometry of phase diagrams in multicomponent mixtures," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 184(3), pages 393-414.
  • Handle: RePEc:eee:phsmap:v:184:y:1992:i:3:p:393-414
    DOI: 10.1016/0378-4371(92)90313-F
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/037843719290313F
    Download Restriction: Full text for ScienceDirect subscribers only. Journal offers the option of making the article available online on Science direct for a fee of $3,000

    File URL: https://libkey.io/10.1016/0378-4371(92)90313-F?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Griffiths, Mary, 1977. "Nutrition : Second European nutrition conference, Munich, 14-17 September 1976," Food Policy, Elsevier, vol. 2(1), pages 76-77, February.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Bakchich, A. & Benyoussef, A. & Touzani, M., 1992. "Phase diagrams of the Blume-Emery-Griffiths model: real-space renormalization group investigation and finite size scaling analysis," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 186(3), pages 524-533.
    2. Meijer, Paul H.E., 1988. "Study of the critical line and its double point in the intermediate model," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 152(3), pages 359-364.
    3. Buzano, C., 1988. "Order-order and order-disorder transitions in the quantum spin-1 Ising-Heisenberg models," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 150(1), pages 54-76.
    4. Grigelionis, Gintautas & Rosengren, Anders, 1994. "Study of the Blume-Emery-Griffiths model on the triangular lattice by the cluster-variation method," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 208(2), pages 287-299.
    5. Quadros, S.G.A. & Salinas, S.R., 1994. "Renormalization-group calculations for a mixed-spin Ising model," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 206(3), pages 479-496.
    6. Meijer, Paul H.E. & Pegg, Ian L., 1991. "Structure of the critical lines for the lattice gas model," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 174(2), pages 391-405.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:phsmap:v:184:y:1992:i:3:p:393-414. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/physica-a-statistical-mechpplications/ .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.