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Theoretical description of the methyl group relaxation in liquids

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  • Blicharska, Barbara

Abstract

Spin-lattice and spin-spin relaxation times of protons and deuterons of methyl groups in liquids are calculated using a semiclassical form of the density operator formalism and symmetry adapted spherical tensors. The model of molecular motion assumes diffusion of the whole molecule containing the methyl group with some internal rotation. Special consideration is given to uniaxial internal rotation and anisotropic diffusion as well as to biaxial internal rotation and isotropic diffusion in interpreting the experimental results.

Suggested Citation

  • Blicharska, Barbara, 1988. "Theoretical description of the methyl group relaxation in liquids," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 147(3), pages 601-626.
    • Handle: RePEc:eee:phsmap:v:147:y:1988:i:3:p:601-626
    DOI: 10.1016/0378-4371(88)90172-0
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    1. Schertz, Lyle P., 1984. "U.S. Components Of Selected World Food Studies," Staff Reports 277650, United States Department of Agriculture, Economic Research Service.
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