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Thermal conductivity of three noble gases with carbon monoxide

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  • Imaishi, N.
  • Kestin, J.

Abstract

The paper reports the results of new measurements of the thermal conductivity of binary mixtures of helium, neon and argon with carbon monoxide at 27.5°C and in the pressure range 0.7–12 MPa. The viscosity of these mixtures had been measured previously. The availability of their interaction viscosity allows us to calculate the contribution of the internal degrees of freedom. The Monchick-Pereira-Mason equation provides a reasonable, but far from perfect, basis for a correlation. Even though the low-density viscosity of the present mixtures was essentially the same as the corresponding mixtures with nitrogen, the thermal conductivity is different, pointing to a significant contribution from the rotational degrees of freedom.

Suggested Citation

  • Imaishi, N. & Kestin, J., 1984. "Thermal conductivity of three noble gases with carbon monoxide," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 126(1), pages 98-115.
    • Handle: RePEc:eee:phsmap:v:126:y:1984:i:1:p:98-115
    DOI: 10.1016/0378-4371(84)90145-6
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    References listed on IDEAS

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    1. Imaishi, N. & Kestin, J. & Wakeham, W.A., 1984. "Thermal conductivity of two binary mixtures of gases of equal molecular weight," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 123(1), pages 50-71.
    2. Fleeter, R.D. & Kestin, J. & Paul, R. & Wakeham, W.A., 1981. "The thermal conductivity of mixtures of nitrogen with four noble gases at room temperature," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 108(2), pages 371-401.
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