IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v34y2009i9p1351-1354.html
   My bibliography  Save this article

Electrochemical properties of novel organodisulfide poly 1,2-bis(thiophen-3-ylmethyl)disulfane as cathode material for secondary lithium batteries

Author

Listed:
  • Weng, Guoming
  • Su, Yuzhi
  • Liu, Zhaoqing
  • Zhang, Jianhua
  • Dong, Wen
  • Xu, Changwei

Abstract

We successfully synthesized a new organodisulfide poly 1,2-bis(thiophen-3-ylmethyl)disulfane by a facile preparation method. The types of the chemical groups of poly-3-thienylthiophene were characterized by Fourier transform infrared spectroscopy (FTIR). The electrochemical properties of S–S bonds redox behavior in the organodisulfides were investigated in CH3CN/0.1M [Bu4N] [PF6] solution. The separation of the anodic and cathodic peak potentials for poly 1,2-bis(thiophen-3-ylmethyl)disulfane is 180mV. The results indicated that poly 1,2-bis(thiophen-3-ylmethyl)disulfane has an excellent electrochemical reversibility. The average specific capacity of 230mAhg−1 for poly-3-thienylthiophene is about 2 times higher than that of LiCoO2.

Suggested Citation

  • Weng, Guoming & Su, Yuzhi & Liu, Zhaoqing & Zhang, Jianhua & Dong, Wen & Xu, Changwei, 2009. "Electrochemical properties of novel organodisulfide poly 1,2-bis(thiophen-3-ylmethyl)disulfane as cathode material for secondary lithium batteries," Energy, Elsevier, vol. 34(9), pages 1351-1354.
    • Handle: RePEc:eee:energy:v:34:y:2009:i:9:p:1351-1354
    DOI: 10.1016/j.energy.2009.05.032
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544209002138
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2009.05.032?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Han, Jinduo & Jia, Yongzhong & Jin, Shan & Jing, Yan & Tillard, Monique & Belin, Claude, 2006. "Morphology and electrochemistry of spinel Li–Mn–O optimized by composite technology," Energy, Elsevier, vol. 31(12), pages 2088-2093.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Seng, Kuok Hau & Li, Li & Chen, Da-Peng & Chen, Zhi Xin & Wang, Xiao-Lin & Liu, Hua Kun & Guo, Zai Ping, 2013. "The effects of FEC (fluoroethylene carbonate) electrolyte additive on the lithium storage properties of NiO (nickel oxide) nanocuboids," Energy, Elsevier, vol. 58(C), pages 707-713.
    2. Bai, Hongwei & Liu, Zhaoyang & Sun, Darren Delai & Chan, Siew Hwa, 2014. "Hierarchical 3D micro-/nano-V2O5 (vanadium pentoxide) spheres as cathode materials for high-energy and high-power lithium ion-batteries," Energy, Elsevier, vol. 76(C), pages 607-613.
    3. Singh, Shishir Kumar & Shalu, & Balo, Liton & Gupta, Himani & Singh, Varun Kumar & Tripathi, Alok Kumar & Verma, Yogendra Lal & Singh, Rajendra Kumar, 2018. "Improved electrochemical performance of EMIMFSI ionic liquid based gel polymer electrolyte with temperature for rechargeable lithium battery," Energy, Elsevier, vol. 150(C), pages 890-900.
    4. Yang, Zunxian & Meng, Qing & Guo, Zaiping & Yu, Xuebin & Guo, Tailiang & Zeng, Rong, 2013. "Highly reversible lithium storage in uniform Li4Ti5O12/carbon hybrid nanowebs as anode material for lithium-ion batteries," Energy, Elsevier, vol. 55(C), pages 925-932.
    5. Yang, Zunxian & Meng, Qing & Yan, Wenhuan & Lv, Jun & Guo, Zaiping & Yu, Xuebin & Chen, Zhixin & Guo, Tailiang & Zeng, Rong, 2015. "Novel three-dimensional tin/carbon hybrid core/shell architecture with large amount of solid cross-linked micro/nanochannels for lithium ion battery application," Energy, Elsevier, vol. 82(C), pages 960-967.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Yang, Zunxian & Meng, Qing & Guo, Zaiping & Yu, Xuebin & Guo, Tailiang & Zeng, Rong, 2013. "Highly reversible lithium storage in uniform Li4Ti5O12/carbon hybrid nanowebs as anode material for lithium-ion batteries," Energy, Elsevier, vol. 55(C), pages 925-932.
    2. Chen, Jiasheng & Wang, Xuan Liang & Jin, En Mei & Moon, Seung-Guen & Jeong, Sang Mun, 2021. "Optimization of B2O3 coating process for NCA cathodes to achieve long-term stability for application in lithium ion batteries," Energy, Elsevier, vol. 222(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:34:y:2009:i:9:p:1351-1354. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.