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Ni/ceramic/molten-salt composite catalyst with high-temperature thermal storage for use in solar reforming processes

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  • Kodama, T
  • Isobe, Y
  • Kondoh, Y
  • Yamaguchi, S
  • Shimizu, K.-I

Abstract

Composite materials of catalytically activated porous ceramics with molten salts were proposed for use in solar thermochemical reforming processes of methane as catalyst with high-temperature thermal storage. The high heat capacity and large latent heat (heat of solidification) of the composite molten salt at high temperatures are expected to circumvent the rapid temperature change of the catalyst bed under fluctuation of insolation. The composite catalysts of Ni-activated porous ceramics (mm-sized alumina or zirconia balls) with an alkali-metal chloride or carbonate (NaCl or Na2CO3) were prepared and examined for the activity and stability for CO2 reforming of methane.

Suggested Citation

  • Kodama, T & Isobe, Y & Kondoh, Y & Yamaguchi, S & Shimizu, K.-I, 2004. "Ni/ceramic/molten-salt composite catalyst with high-temperature thermal storage for use in solar reforming processes," Energy, Elsevier, vol. 29(5), pages 895-903.
    • Handle: RePEc:eee:energy:v:29:y:2004:i:5:p:895-903
    DOI: 10.1016/S0360-5442(03)00194-4
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    Cited by:

    1. Agrafiotis, Christos & von Storch, Henrik & Roeb, Martin & Sattler, Christian, 2014. "Solar thermal reforming of methane feedstocks for hydrogen and syngas production—A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 29(C), pages 656-682.
    2. Duan, Wenjun & Yu, Qingbo & Liu, Junxiang & Wu, Tianwei & Yang, Fan & Qin, Qin, 2016. "Experimental and kinetic study of steam gasification of low-rank coal in molten blast furnace slag," Energy, Elsevier, vol. 111(C), pages 859-868.
    3. Huang, Yao-Hui & Su, Chia-Chi & Wang, Shu-Ling & Lu, Ming-Chun, 2012. "Development of Al2O3 carrier-Ru composite catalyst for hydrogen generation from alkaline NaBH4 hydrolysis," Energy, Elsevier, vol. 46(1), pages 242-247.
    4. Yan, T. & Wang, R.Z. & Li, T.X. & Wang, L.W. & Fred, Ishugah T., 2015. "A review of promising candidate reactions for chemical heat storage," Renewable and Sustainable Energy Reviews, Elsevier, vol. 43(C), pages 13-31.
    5. Shih, Yu-Jen & Su, Chia-Chi & Huang, Yao-Hui & Lu, Ming-Chun, 2013. "SiO2-supported ferromagnetic catalysts for hydrogen generation from alkaline NaBH4 (sodium borohydride) solution," Energy, Elsevier, vol. 54(C), pages 263-270.

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