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Nonbranched-Chain Formation of 1,2-Alkanediols in Systems Alcohol-Formaldehyde

Author

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  • Michael M Silaev

    (Chemistry Faculty, Lomonosov Moscow State University, Vorobievy Gory, Russia)

Abstract

A mechanism of the initiated no branched-chain process of forming 1,2-alkanediols and carbonyl compounds in alcohol-formaldehyde sys-tems is suggested. The quasi-steady-state treatment is used to obtain kinetic equations that can describe the no monotonic (with a maximum) depend-ences of the formation rates of the products on the concentration of freeunsolvatedformaldehyde. The experimental concentration of the free unsolvated form of formaldehyde is given at the different temperatures, solvent permittivity, and total concentrations of formaldehyde in water and alcohols. An empirical equation for calculating the free formaldehyde concentration in alcohol-formaldehyde (including water/ethanediol-formaldehyde) systems at various temperatures and total formaldehyde concentrations and an equation for evaluating solvent concentrations in these systems were derived.

Suggested Citation

  • Michael M Silaev, 2018. "Nonbranched-Chain Formation of 1,2-Alkanediols in Systems Alcohol-Formaldehyde," Organic & Medicinal Chemistry International Journal, Juniper Publishers Inc., vol. 7(2), pages 73-79, June.
    • Handle: RePEc:adp:jomcij:v:7:y:2018:i:2:p:73-79
    DOI: 10.19080/OMCIJ.2018.07.555709
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