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An unexpected Rearrangement of Dimethyl-Allyl-2-Hydroxyethyl Quaternary Ammonium Salts in an Alkaline Medium

Author

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  • G H Torosyan

    (National polytechnic university of Armenia, Armenia)

Abstract

It’s known intramolecular O-benzylation of dimethylbenzyl-2-hydroxyethylammonium chloride at 175-180оС with the formation of dimethylaminoethanol benzyl ether chlorohydrate with a low yield - 5-20% [1]. The same salt undergoes to Sommelet rearrangement in a strong alkaline medium with the formation of corresponding tertiary amine [2].

Suggested Citation

  • G H Torosyan, 2018. "An unexpected Rearrangement of Dimethyl-Allyl-2-Hydroxyethyl Quaternary Ammonium Salts in an Alkaline Medium," Organic & Medicinal Chemistry International Journal, Juniper Publishers Inc., vol. 5(2), pages 53-54, January.
    • Handle: RePEc:adp:jomcij:v:5:y:2018:i:2:p:53-54
    DOI: 10.19080/OMCIJ.2018.05.555658
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