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Preparation and Properties of Capric–Myristic Acid/Expanded Graphite Composite Phase Change Materials for Latent Heat Thermal Energy Storage

Author

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  • Dongyi Zhou

    (School of Energy Science and Engineering, Central South University, Changsha 410083, China
    School of Mechanical and Energy Engineering, Shaoyang University, Shaoyang 422000, China
    Key Laboratory of Hunan Province for Efficient Power System and Intelligent Manufacturing, Shaoyang University, Shaoyang 422000, China)

  • Jiawei Yuan

    (School of Mechanical and Energy Engineering, Shaoyang University, Shaoyang 422000, China)

  • Yuhong Zhou

    (School of Mechanical and Energy Engineering, Shaoyang University, Shaoyang 422000, China)

  • Yicai Liu

    (School of Energy Science and Engineering, Central South University, Changsha 410083, China)

Abstract

A novel composite phase change material (CPCM), capric–myristic acid/expanded graphite (CA–MA/EG) CPCM, was prepared by absorbing liquid CA–MA (as the phase change material (PCM)) into EG (as the substrate material) for heat storage in the backfill materials of soil-source heat pump systems. The thermal characteristics and microstructure of the novel CPCM were analyzed using differential scanning calorimetry (DSC) and scanning electronic microscopy (SEM). The thermal conductivities of CA–MA/EG CPCM were surveyed. The thermal stability of the CA–MA/EG was analyzed using thermogravimetric analysis (TGA) and thermal cycle tests. The results showed that the optimal mass content of CA–MA in CPCM was approximately 92.4% and the CA–MA was uniformly distributed in the vesicular structure of EG; the CA–MA/EG CPCM had an appropriate phase change temperature ( T m : 19.78 °C, T f : 18.85 °C), high latent heat ( H m : 137.3 J/g, H f : 139.9 J/g), and excellent thermostability and thermal reliability. The thermal conductivity of the CPCM was remarkably enhanced after adding EG. Therefore, the CPCMs demonstrated outstanding thermal performance and can be utilized in low-temperature latent heat thermal energy storage (LHTES) systems, such as soil-source heat pump systems.

Suggested Citation

  • Dongyi Zhou & Jiawei Yuan & Yuhong Zhou & Yicai Liu, 2020. "Preparation and Properties of Capric–Myristic Acid/Expanded Graphite Composite Phase Change Materials for Latent Heat Thermal Energy Storage," Energies, MDPI, vol. 13(10), pages 1-12, May.
    • Handle: RePEc:gam:jeners:v:13:y:2020:i:10:p:2462-:d:357771
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