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A review of the composite phase change materials: Fabrication, characterization, mathematical modeling and application to performance enhancement

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  • Zhang, P.
  • Xiao, X.
  • Ma, Z.W.

Abstract

Phase change materials (PCMs) are frequently and widely used in latent thermal energy storage (LTES) system and thermal management (TM) system due to their large latent heats and capabilities of maintaining nearly constant temperature. However, the performances of PCMs in LTES and TM systems are seriously limited by their low thermal conductivities and poor heat transfer performances, which consequently stimulates intensive experimental and theoretical investigations on improving the thermal conductivities and heat transfer performances of PCMs by using different methods. The present paper reviews the recent progresses of the investigations and applications of the composite PCMs with the enhanced performance. The focuses are placed on the composite PCMs fabricated by using the metal foams and carbon materials, which have been proved to be the most promising approaches for thermal conductivity and heat transfer promotion on PCMs. The fabrication processes of the composite PCMs are first introduced in the present paper followed by the thermal characterization. The measurement of the effective thermal conductivities of the composite PCMs is discussed in detail by comparing different measuring methods, and the theoretical models to predict the effective thermal conductivities of the composite PCMs are also presented. The mathematical models describing the phase change heat transfer characteristics of the composite PCMs which are very important for system modeling and design are also addressed and discussed in the present review. Furthermore, the applications of the composite PCMs to LTES and TM systems are introduced and summarized by illustrating the typical examples. It can be understood that the composite PCMs can effectively improve the performances of LTES and TM systems, which therefore calls for the further investigation in this research field. Finally, the future research topics are suggested.

Suggested Citation

  • Zhang, P. & Xiao, X. & Ma, Z.W., 2016. "A review of the composite phase change materials: Fabrication, characterization, mathematical modeling and application to performance enhancement," Applied Energy, Elsevier, vol. 165(C), pages 472-510.
  • Handle: RePEc:eee:appene:v:165:y:2016:i:c:p:472-510
    DOI: 10.1016/j.apenergy.2015.12.043
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    as
    1. Zhang, Nan & Yuan, Yanping & Du, Yanxia & Cao, Xiaoling & Yuan, Yaguang, 2014. "Preparation and properties of palmitic-stearic acid eutectic mixture/expanded graphite composite as phase change material for energy storage," Energy, Elsevier, vol. 78(C), pages 950-956.
    2. Huang, Zhaowen & Gao, Xuenong & Xu, Tao & Fang, Yutang & Zhang, Zhengguo, 2014. "Thermal property measurement and heat storage analysis of LiNO3/KCl – expanded graphite composite phase change material," Applied Energy, Elsevier, vol. 115(C), pages 265-271.
    3. Karaipekli, Ali & Sarı, Ahmet, 2008. "Capric–myristic acid/expanded perlite composite as form-stable phase change material for latent heat thermal energy storage," Renewable Energy, Elsevier, vol. 33(12), pages 2599-2605.
    4. Ling, Ziye & Chen, Jiajie & Fang, Xiaoming & Zhang, Zhengguo & Xu, Tao & Gao, Xuenong & Wang, Shuangfeng, 2014. "Experimental and numerical investigation of the application of phase change materials in a simulative power batteries thermal management system," Applied Energy, Elsevier, vol. 121(C), pages 104-113.
    5. Zhang, P. & Xiao, X. & Meng, Z.N. & Li, M., 2015. "Heat transfer characteristics of a molten-salt thermal energy storage unit with and without heat transfer enhancement," Applied Energy, Elsevier, vol. 137(C), pages 758-772.
    6. Chen, Renjie & Yao, Ruimin & Xia, Wei & Zou, Ruqiang, 2015. "Electro/photo to heat conversion system based on polyurethane embedded graphite foam," Applied Energy, Elsevier, vol. 152(C), pages 183-188.
    7. Yin, Huibin & Gao, Xuenong & Ding, Jing & Zhang, Zhengguo & Fang, Yutang, 2010. "Thermal management of electronic components with thermal adaptation composite material," Applied Energy, Elsevier, vol. 87(12), pages 3784-3791, December.
    8. Zhao, Jianguo & Guo, Yong & Feng, Feng & Tong, Qinghua & Qv, Wenshan & Wang, Haiqing, 2011. "Microstructure and thermal properties of a paraffin/expanded graphite phase-change composite for thermal storage," Renewable Energy, Elsevier, vol. 36(5), pages 1339-1342.
    9. Li, W.Q. & Qu, Z.G. & Zhang, B.L. & Zhao, K. & Tao, W.Q., 2013. "Thermal behavior of porous stainless-steel fiber felt saturated with phase change material," Energy, Elsevier, vol. 55(C), pages 846-852.
    10. Nomura, Takahiro & Tabuchi, Kazuki & Zhu, Chunyu & Sheng, Nan & Wang, Shuangfeng & Akiyama, Tomohiro, 2015. "High thermal conductivity phase change composite with percolating carbon fiber network," Applied Energy, Elsevier, vol. 154(C), pages 678-685.
    11. Ma, F. & Zhang, P. & Xia, Z.Z. & Li, M., 2015. "How to enhance the effective thermal conductivity of composite material based on optimization method?," Energy, Elsevier, vol. 87(C), pages 400-411.
    12. Parameshwaran, R. & Kalaiselvam, S., 2013. "Energy efficient hybrid nanocomposite-based cool thermal storage air conditioning system for sustainable buildings," Energy, Elsevier, vol. 59(C), pages 194-214.
    13. Xiao, X. & Zhang, P., 2015. "Numerical and experimental study of heat transfer characteristics of a shell-tube latent heat storage system: Part II – Discharging process," Energy, Elsevier, vol. 80(C), pages 177-189.
    14. Medrano, M. & Yilmaz, M.O. & Nogués, M. & Martorell, I. & Roca, Joan & Cabeza, Luisa F., 2009. "Experimental evaluation of commercial heat exchangers for use as PCM thermal storage systems," Applied Energy, Elsevier, vol. 86(10), pages 2047-2055, October.
    15. İnce, Şeyma & Seki, Yoldas & Akif Ezan, Mehmet & Turgut, Alpaslan & Erek, Aytunc, 2015. "Thermal properties of myristic acid/graphite nanoplates composite phase change materials," Renewable Energy, Elsevier, vol. 75(C), pages 243-248.
    16. Li, Huiqiang & Chen, Huisu & Li, Xiangyu & Sanjayan, Jay G., 2014. "Development of thermal energy storage composites and prevention of PCM leakage," Applied Energy, Elsevier, vol. 135(C), pages 225-233.
    17. Zhang, Zhengguo & Shi, Guoquan & Wang, Shuping & Fang, Xiaoming & Liu, Xiaohong, 2013. "Thermal energy storage cement mortar containing n-octadecane/expanded graphite composite phase change material," Renewable Energy, Elsevier, vol. 50(C), pages 670-675.
    18. Mehrali, Mohammad & Tahan Latibari, Sara & Mehrali, Mehdi & Mahlia, Teuku Meurah Indra & Sadeghinezhad, Emad & Metselaar, Hendrik Simon Cornelis, 2014. "Preparation of nitrogen-doped graphene/palmitic acid shape stabilized composite phase change material with remarkable thermal properties for thermal energy storage," Applied Energy, Elsevier, vol. 135(C), pages 339-349.
    19. Xu, Biwan & Li, Zongjin, 2013. "Paraffin/diatomite composite phase change material incorporated cement-based composite for thermal energy storage," Applied Energy, Elsevier, vol. 105(C), pages 229-237.
    20. Al-abidi, Abduljalil A. & Bin Mat, Sohif & Sopian, K. & Sulaiman, M.Y. & Mohammed, Abdulrahman Th., 2013. "CFD applications for latent heat thermal energy storage: a review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 20(C), pages 353-363.
    21. Li, Min, 2013. "A nano-graphite/paraffin phase change material with high thermal conductivity," Applied Energy, Elsevier, vol. 106(C), pages 25-30.
    22. Tian, Heqing & Wang, Weilong & Ding, Jing & Wei, Xiaolan & Song, Ming & Yang, Jianping, 2015. "Thermal conductivities and characteristics of ternary eutectic chloride/expanded graphite thermal energy storage composites," Applied Energy, Elsevier, vol. 148(C), pages 87-92.
    23. Khodadadi, J.M. & Fan, Liwu & Babaei, Hasan, 2013. "Thermal conductivity enhancement of nanostructure-based colloidal suspensions utilized as phase change materials for thermal energy storage: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 24(C), pages 418-444.
    24. Warzoha, Ronald J. & Weigand, Rebecca M. & Fleischer, Amy S., 2015. "Temperature-dependent thermal properties of a paraffin phase change material embedded with herringbone style graphite nanofibers," Applied Energy, Elsevier, vol. 137(C), pages 716-725.
    25. Zhao, Y.J. & Wang, R.Z. & Wang, L.W. & Yu, N., 2014. "Development of highly conductive KNO3/NaNO3 composite for TES (thermal energy storage)," Energy, Elsevier, vol. 70(C), pages 272-277.
    26. Biswas, Kaushik & Lu, Jue & Soroushian, Parviz & Shrestha, Som, 2014. "Combined experimental and numerical evaluation of a prototype nano-PCM enhanced wallboard," Applied Energy, Elsevier, vol. 131(C), pages 517-529.
    27. Li, TingXian & Lee, Ju-Hyuk & Wang, RuZhu & Kang, Yong Tae, 2013. "Enhancement of heat transfer for thermal energy storage application using stearic acid nanocomposite with multi-walled carbon nanotubes," Energy, Elsevier, vol. 55(C), pages 752-761.
    28. Wu, Jianghong & Yang, Zhaoguang & Wu, Qinghao & Zhu, Yujuan, 2012. "Transient behavior and dynamic performance of cascade heat pump water heater with thermal storage system," Applied Energy, Elsevier, vol. 91(1), pages 187-196.
    29. Fang, Guiyin & Li, Hui & Chen, Zhi & Liu, Xu, 2010. "Preparation and characterization of stearic acid/expanded graphite composites as thermal energy storage materials," Energy, Elsevier, vol. 35(12), pages 4622-4626.
    30. Verma, Prashant & Varun & Singal, S.K., 2008. "Review of mathematical modeling on latent heat thermal energy storage systems using phase-change material," Renewable and Sustainable Energy Reviews, Elsevier, vol. 12(4), pages 999-1031, May.
    31. Xiao, X. & Zhang, P., 2015. "Numerical and experimental study of heat transfer characteristics of a shell-tube latent heat storage system: Part I – Charging process," Energy, Elsevier, vol. 79(C), pages 337-350.
    32. Dutil, Yvan & Rousse, Daniel R. & Salah, Nizar Ben & Lassue, Stéphane & Zalewski, Laurent, 2011. "A review on phase-change materials: Mathematical modeling and simulations," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(1), pages 112-130, January.
    33. Li, Wei & Zhang, Rong & Jiang, Nan & Tang, Xiao-fen & Shi, Hai-feng & Zhang, Xing-xiang & Zhang, Yuankai & Dong, Lin & Zhang, Ningxin, 2013. "Composite macrocapsule of phase change materials/expanded graphite for thermal energy storage," Energy, Elsevier, vol. 57(C), pages 607-614.
    34. Jegadheeswaran, S. & Pohekar, Sanjay D., 2009. "Performance enhancement in latent heat thermal storage system: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 13(9), pages 2225-2244, December.
    35. Fan, Liwu & Khodadadi, J.M., 2011. "Thermal conductivity enhancement of phase change materials for thermal energy storage: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(1), pages 24-46, January.
    36. Karaipekli, Ali & Sarı, Ahmet & Kaygusuz, Kamil, 2007. "Thermal conductivity improvement of stearic acid using expanded graphite and carbon fiber for energy storage applications," Renewable Energy, Elsevier, vol. 32(13), pages 2201-2210.
    37. Mehrali, Mohammad & Latibari, Sara Tahan & Mehrali, Mehdi & Indra Mahlia, Teuku Meurah & Cornelis Metselaar, Hendrik Simon, 2013. "Preparation and properties of highly conductive palmitic acid/graphene oxide composites as thermal energy storage materials," Energy, Elsevier, vol. 58(C), pages 628-634.
    38. Agyenim, Francis & Hewitt, Neil & Eames, Philip & Smyth, Mervyn, 2010. "A review of materials, heat transfer and phase change problem formulation for latent heat thermal energy storage systems (LHTESS)," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(2), pages 615-628, February.
    39. Xiao, X. & Zhang, P. & Li, M., 2013. "Preparation and thermal characterization of paraffin/metal foam composite phase change material," Applied Energy, Elsevier, vol. 112(C), pages 1357-1366.
    40. Wang, Weilong & Yang, Xiaoxi & Fang, Yutang & Ding, Jing & Yan, Jinyue, 2009. "Preparation and thermal properties of polyethylene glycol/expanded graphite blends for energy storage," Applied Energy, Elsevier, vol. 86(9), pages 1479-1483, September.
    41. Ling, Ziye & Wang, Fangxian & Fang, Xiaoming & Gao, Xuenong & Zhang, Zhengguo, 2015. "A hybrid thermal management system for lithium ion batteries combining phase change materials with forced-air cooling," Applied Energy, Elsevier, vol. 148(C), pages 403-409.
    42. Sharma, Atul & Tyagi, V.V. & Chen, C.R. & Buddhi, D., 2009. "Review on thermal energy storage with phase change materials and applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 13(2), pages 318-345, February.
    43. Zhang, H.L. & Baeyens, J. & Degrève, J. & Cáceres, G. & Segal, R. & Pitié, F., 2014. "Latent heat storage with tubular-encapsulated phase change materials (PCMs)," Energy, Elsevier, vol. 76(C), pages 66-72.
    44. Wang, Yi & Xia, Tian Dong & Feng, Hui Xia & Zhang, Han, 2011. "Stearic acid/polymethylmethacrylate composite as form-stable phase change materials for latent heat thermal energy storage," Renewable Energy, Elsevier, vol. 36(6), pages 1814-1820.
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