IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v11y2018i5p1127-d144269.html
   My bibliography  Save this article

Influence of Hydrogen Sulfide and Redox Reactions on the Surface Properties and Hydrogen Permeability of Pd Membranes

Author

Listed:
  • Wei Feng

    (Advanced Research Institute, Chengdu University, Chengdu 610106, China
    College of Architecture and Environment, Sichuan University, Chengdu 610065, China)

  • Qingyuan Wang

    (Advanced Research Institute, Chengdu University, Chengdu 610106, China
    College of Architecture and Environment, Sichuan University, Chengdu 610065, China)

  • Xiaodong Zhu

    (Advanced Research Institute, Chengdu University, Chengdu 610106, China)

  • Qingquan Kong

    (Advanced Research Institute, Chengdu University, Chengdu 610106, China
    College of Architecture and Environment, Sichuan University, Chengdu 610065, China)

  • Jiejie Wu

    (School of Materials Science and Engineering, Beihang University, Beijing 100083, China)

  • Peipei Tu

    (Advanced Research Institute, Chengdu University, Chengdu 610106, China)

Abstract

Although hydrogen sulfide (H 2 S) was always a negative factor leading to the reduction of hydrogen permeability of palladium (Pd) membranes, its proper application could result in a positive effect. In this study, pure Pd membranes were firstly reacted with H 2 S at 23–450 °C, and then treated by redox reactions. Afterwards, the hydrogen permeability was tested under different reaction conditions using a hydrogen penetrant testing device. Moreover, both products and morphology changes occurred on the Pd membrane surface were analyzed using XRD, XPS and SEM. The results showed that H 2 S was dissociated to produce sulfides at 23 °C. With a rise of temperature, a regular change took place in the reaction products, morphology of the Pd membrane surface and hydrogen permeability. Adsorbed impurities such as sulfides and free carbon on the Pd membrane surface were removed by the redox treatment. The hydrogen permeability was improved by about 80% for the Pd membrane material subjected to the treatment method stated the above against the untreated one.

Suggested Citation

  • Wei Feng & Qingyuan Wang & Xiaodong Zhu & Qingquan Kong & Jiejie Wu & Peipei Tu, 2018. "Influence of Hydrogen Sulfide and Redox Reactions on the Surface Properties and Hydrogen Permeability of Pd Membranes," Energies, MDPI, vol. 11(5), pages 1-10, May.
    • Handle: RePEc:gam:jeners:v:11:y:2018:i:5:p:1127-:d:144269
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/11/5/1127/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/1996-1073/11/5/1127/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Chen, Wei-Hsin & Hsia, Ming-Hsien & Chi, Yen-Hsun & Lin, Yu-Li & Yang, Chang-Chung, 2014. "Polarization phenomena of hydrogen-rich gas in high-permeance Pd and Pd–Cu membrane tubes," Applied Energy, Elsevier, vol. 113(C), pages 41-50.
    2. Vincenzo Franzitta & Domenico Curto & Davide Rao & Alessia Viola, 2016. "Hydrogen Production from Sea Wave for Alternative Energy Vehicles for Public Transport in Trapani (Italy)," Energies, MDPI, vol. 9(10), pages 1-17, October.
    3. Hisham Hafez & George Nakhla & Hesham El Naggar, 2009. "Biological Hydrogen Production from Corn-Syrup Waste Using a Novel System," Energies, MDPI, vol. 2(2), pages 1-11, June.
    4. Jan Christian Koj & Christina Wulf & Andrea Schreiber & Petra Zapp, 2017. "Site-Dependent Environmental Impacts of Industrial Hydrogen Production by Alkaline Water Electrolysis," Energies, MDPI, vol. 10(7), pages 1-15, June.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Hai Li & Xueteng Gao & Chongzhi Jia & Wan Chen & Bei Liu & Lanying Yang & Changyu Sun & Guangjin Chen, 2018. "Enrichment of Hydrogen from a Hydrogen/Propylene Gas Mixture Using ZIF-8/Water-Glycol Slurry," Energies, MDPI, vol. 11(7), pages 1-13, July.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Mehrshad Kolahchian Tabrizi & Jacopo Famiglietti & Davide Bonalumi & Stefano Campanari, 2023. "The Carbon Footprint of Hydrogen Produced with State-of-the-Art Photovoltaic Electricity Using Life-Cycle Assessment Methodology," Energies, MDPI, vol. 16(13), pages 1-25, July.
    2. Fan, Jing-Li & Yu, Pengwei & Li, Kai & Xu, Mao & Zhang, Xian, 2022. "A levelized cost of hydrogen (LCOH) comparison of coal-to-hydrogen with CCS and water electrolysis powered by renewable energy in China," Energy, Elsevier, vol. 242(C).
    3. Sarma, Saurabh Jyoti & Pachapur, Vinayak & Brar, Satinder Kaur & Le Bihan, Yann & Buelna, Gerardo, 2015. "Hydrogen biorefinery: Potential utilization of the liquid waste from fermentative hydrogen production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 50(C), pages 942-951.
    4. Mohamed Benghanem & Adel Mellit & Hamad Almohamadi & Sofiane Haddad & Nedjwa Chettibi & Abdulaziz M. Alanazi & Drigos Dasalla & Ahmed Alzahrani, 2023. "Hydrogen Production Methods Based on Solar and Wind Energy: A Review," Energies, MDPI, vol. 16(2), pages 1-31, January.
    5. Zhang, Cong & Greenblatt, Jeffery B. & Wei, Max & Eichman, Josh & Saxena, Samveg & Muratori, Matteo & Guerra, Omar J., 2020. "Flexible grid-based electrolysis hydrogen production for fuel cell vehicles reduces costs and greenhouse gas emissions," Applied Energy, Elsevier, vol. 278(C).
    6. Hren, Robert & Vujanović, Annamaria & Van Fan, Yee & Klemeš, Jiří Jaromír & Krajnc, Damjan & Čuček, Lidija, 2023. "Hydrogen production, storage and transport for renewable energy and chemicals: An environmental footprint assessment," Renewable and Sustainable Energy Reviews, Elsevier, vol. 173(C).
    7. Squadrito, G. & Nicita, A. & Maggio, G., 2021. "A size-dependent financial evaluation of green hydrogen-oxygen co-production," Renewable Energy, Elsevier, vol. 163(C), pages 2165-2177.
    8. Chen, Wei-Hsin & Tsai, Ching-Wei & Lin, Yu-Li, 2017. "Numerical studies of the influences of bypass on hydrogen separation in a multichannel Pd membrane system," Renewable Energy, Elsevier, vol. 104(C), pages 259-270.
    9. Ribeirinha, P. & Abdollahzadeh, M. & Pereira, A. & Relvas, F. & Boaventura, M. & Mendes, A., 2018. "High temperature PEM fuel cell integrated with a cellular membrane methanol steam reformer: Experimental and modelling," Applied Energy, Elsevier, vol. 215(C), pages 659-669.
    10. Roberta Olindo & Joost G. Vogtländer, 2019. "The Role of Hydrogen in the Ecological Benefits of Ultra Low Sulphur Diesel Production and Use: An LCA Benchmark," Sustainability, MDPI, vol. 11(7), pages 1-17, April.
    11. Birol Kılkış & Şiir Kılkış, 2018. "Hydrogen Economy Model for Nearly Net-Zero Cities with Exergy Rationale and Energy-Water Nexus," Energies, MDPI, vol. 11(5), pages 1-33, May.
    12. Haroun, Basem Mikhaeil & Nakhla, George & Hafez, Hisham & Nasr, Fayza Aly, 2016. "Impact of furfural on biohydrogen production from glucose and xylose in continuous-flow systems," Renewable Energy, Elsevier, vol. 93(C), pages 302-311.
    13. Ribeirinha, P. & Abdollahzadeh, M. & Boaventura, M. & Mendes, A., 2017. "H2 production with low carbon content via MSR in packed bed membrane reactors for high-temperature polymeric electrolyte membrane fuel cell," Applied Energy, Elsevier, vol. 188(C), pages 409-419.
    14. Chen, Wei-Hsin & Kuo, Pei-Chi & Lin, Yu-Li, 2019. "Evolutionary computation for maximizing CO2 and H2 separation in multiple-tube palladium-membrane systems," Applied Energy, Elsevier, vol. 235(C), pages 299-310.
    15. Chen, Yinguang & Liu, Hui & Zheng, Xiong & Wang, Xin & Wu, Jiang, 2017. "New method for enhancement of bioenergy production from municipal organic wastes via regulation of anaerobic fermentation process," Applied Energy, Elsevier, vol. 196(C), pages 190-198.
    16. Koj, Jan Christian & Wulf, Christina & Zapp, Petra, 2019. "Environmental impacts of power-to-X systems - A review of technological and methodological choices in Life Cycle Assessments," Renewable and Sustainable Energy Reviews, Elsevier, vol. 112(C), pages 865-879.
    17. Roberta Olindo & Nathalie Schmitt & Joost Vogtländer, 2021. "Life Cycle Assessments on Battery Electric Vehicles and Electrolytic Hydrogen: The Need for Calculation Rules and Better Databases on Electricity," Sustainability, MDPI, vol. 13(9), pages 1-22, May.
    18. Ushnik Mukherjee & Azadeh Maroufmashat & Apurva Narayan & Ali Elkamel & Michael Fowler, 2017. "A Stochastic Programming Approach for the Planning and Operation of a Power to Gas Energy Hub with Multiple Energy Recovery Pathways," Energies, MDPI, vol. 10(7), pages 1-27, June.
    19. Boguslaw Pierozynski & Tomasz Mikolajczyk & Boguslaw Wojciechowski & Mateusz Luba, 2021. "An Innovative 500 W Alkaline Water Electrolyser System for the Production of Ultra-Pure Hydrogen and Oxygen Gases," Energies, MDPI, vol. 14(3), pages 1-11, January.
    20. Christina Wulf & Petra Zapp & Andrea Schreiber & Wilhelm Kuckshinrichs, 2021. "Setting Thresholds to Define Indifferences and Preferences in PROMETHEE for Life Cycle Sustainability Assessment of European Hydrogen Production," Sustainability, MDPI, vol. 13(13), pages 1-21, June.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:11:y:2018:i:5:p:1127-:d:144269. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.