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Biological Hydrogen Production from Corn-Syrup Waste Using a Novel System

Author

Listed:
  • Hisham Hafez

    (Civil and Environmental Engineering Department, University of Western Ontario, London, Ontario, Canada)

  • George Nakhla

    (Civil and Environmental Engineering Department, University of Western Ontario, London, Ontario, Canada)

  • Hesham El Naggar

    (Civil and Environmental Engineering Department, University of Western Ontario, London, Ontario, Canada)

Abstract

The reported patent-pending system comprises a novel biohydrogen reactor with a gravity settler for decoupling of SRT from HRT. The biohydrogenator was operated for 100 days at 37 °C, hydraulic retention time 8 h and solids retention time ranging from 2.2–2.5 days. The feed was a corn-syrup waste generated as a byproduct from an industrial facility for bioethanol production located in southwestern Ontario, Canada. The system was initially started up with a synthetic feed containing glucose at concentration of 8 g/L and other essential inorganics. Anaerobicaly-digested sludge from the St. Mary’s wastewater treatment plant (St. Mary, Ontario, Canada) was used as the seed, and was heat treated at 70 °C for 30 min to inhibit methanogens. After 10 days, when the hydrogen production was steady, the corn-syrup waste was introduced to the system. Glucose was the main constituent in the corn-syrup; its concentration was varied over a period of 90 days from 8 to 25 g/L. The change in glucose concentration was used to study the impact of variable organic loading on the stability of hydrogen production in the biohydrogenator. Hydrogen production rate increased from 10 L H 2 /L·d to 34 L H 2 /L·d with the increase of organic loading rate (OLR) from 26 to 81 gCOD/L·d, while a maximum hydrogen yield of 430 mL H 2 /gCOD was achieved in the system with an overall average of 385 mL H 2 /gCOD.

Suggested Citation

  • Hisham Hafez & George Nakhla & Hesham El Naggar, 2009. "Biological Hydrogen Production from Corn-Syrup Waste Using a Novel System," Energies, MDPI, vol. 2(2), pages 1-11, June.
  • Handle: RePEc:gam:jeners:v:2:y:2009:i:2:p:445-455:d:5245
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    Citations

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    Cited by:

    1. Vinayak Laxman Pachapur & Prianka Kutty & Preetika Pachapur & Satinder Kaur Brar & Yann Le Bihan & Rosa Galvez-Cloutier & Gerardo Buelna, 2019. "Seed Pretreatment for Increased Hydrogen Production Using Mixed-Culture Systems with Advantages over Pure-Culture Systems," Energies, MDPI, vol. 12(3), pages 1-26, February.
    2. Sivagurunathan, Periyasamy & Sen, Biswarup & Lin, Chiu-Yue, 2015. "High-rate fermentative hydrogen production from beverage wastewater," Applied Energy, Elsevier, vol. 147(C), pages 1-9.
    3. Sarma, Saurabh Jyoti & Pachapur, Vinayak & Brar, Satinder Kaur & Le Bihan, Yann & Buelna, Gerardo, 2015. "Hydrogen biorefinery: Potential utilization of the liquid waste from fermentative hydrogen production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 50(C), pages 942-951.
    4. Chen, Yinguang & Liu, Hui & Zheng, Xiong & Wang, Xin & Wu, Jiang, 2017. "New method for enhancement of bioenergy production from municipal organic wastes via regulation of anaerobic fermentation process," Applied Energy, Elsevier, vol. 196(C), pages 190-198.
    5. Haroun, Basem Mikhaeil & Nakhla, George & Hafez, Hisham & Nasr, Fayza Aly, 2016. "Impact of furfural on biohydrogen production from glucose and xylose in continuous-flow systems," Renewable Energy, Elsevier, vol. 93(C), pages 302-311.
    6. Wei Feng & Qingyuan Wang & Xiaodong Zhu & Qingquan Kong & Jiejie Wu & Peipei Tu, 2018. "Influence of Hydrogen Sulfide and Redox Reactions on the Surface Properties and Hydrogen Permeability of Pd Membranes," Energies, MDPI, vol. 11(5), pages 1-10, May.

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