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Challenges and strategies for optimization of glycerol steam reforming process

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  • Silva, Joel M.
  • Soria, M.A.
  • Madeira, Luis M.

Abstract

The steam reforming of the main biodiesel by-product, glycerol, has been catching up the interest of the scientific community in the last years. The use of glycerol for hydrogen production is an advantageous option not only because glycerol is renewable but also because its use would lead to the decrease of the price of biodiesel, thus making it more competitive. Consequently, the use of biodiesel at large scale would significantly reduce CO2 emissions comparatively to fossil fuels. Moreover, hydrogen itself is seen as a very attractive clean fuel for transportation purposes. Therefore, the industrialization of the glycerol steam reforming (GSR) process would have a tremendous global environmental impact. In the last years, intensive research regarding GSR thermodynamics, catalysts, reaction mechanisms and kinetics, and innovative reactor configurations (sorption enhanced reactors (SERs) and membrane reactors (MRs)) has been done, aiming for improving the process effectiveness. In this review, the main challenges and strategies adopted for optimization of GSR process are addressed, namely the GSR thermodynamic aspects, the last developments on catalysis and kinetics, as well as the last advances on GSR performed in SERs and MRs.

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  • Silva, Joel M. & Soria, M.A. & Madeira, Luis M., 2015. "Challenges and strategies for optimization of glycerol steam reforming process," Renewable and Sustainable Energy Reviews, Elsevier, vol. 42(C), pages 1187-1213.
    • Handle: RePEc:eee:rensus:v:42:y:2015:i:c:p:1187-1213
    DOI: 10.1016/j.rser.2014.10.084
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    1. Adhikari, Sushil & Fernando, Sandun D. & Haryanto, Agus, 2008. "Hydrogen production from glycerin by steam reforming over nickel catalysts," Renewable Energy, Elsevier, vol. 33(5), pages 1097-1100.
    2. Dou, Binlin & Song, Yongchen & Wang, Chao & Chen, Haisheng & Xu, Yujie, 2014. "Hydrogen production from catalytic steam reforming of biodiesel byproduct glycerol: Issues and challenges," Renewable and Sustainable Energy Reviews, Elsevier, vol. 30(C), pages 950-960.
    3. Chen, Haisheng & Ding, Yulong & Cong, Ngoc T. & Dou, Binlin & Dupont, Valerie & Ghadiri, Mojtaba & Williams, Paul T., 2011. "A comparative study on hydrogen production from steam-glycerol reforming: thermodynamics and experimental," Renewable Energy, Elsevier, vol. 36(2), pages 779-788.
    4. Gutiérrez Ortiz, F.J. & Serrera, A. & Galera, S. & Ollero, P., 2013. "Experimental study of the supercritical water reforming of glycerol without the addition of a catalyst," Energy, Elsevier, vol. 56(C), pages 193-206.
    5. Dave, Chirag D. & Pant, K.K., 2011. "Renewable hydrogen generation by steam reforming of glycerol over zirconia promoted ceria supported catalyst," Renewable Energy, Elsevier, vol. 36(11), pages 3195-3202.
    6. Tuza, Pablo V. & Manfro, Robinson L. & Ribeiro, Nielson F.P. & Souza, Mariana M.V.M., 2013. "Production of renewable hydrogen by aqueous-phase reforming of glycerol over Ni–Cu catalysts derived from hydrotalcite precursors," Renewable Energy, Elsevier, vol. 50(C), pages 408-414.
    7. Hajjaji, Noureddine & Chahbani, Amna & Khila, Zouhour & Pons, Marie-Noëlle, 2014. "A comprehensive energy–exergy-based assessment and parametric study of a hydrogen production process using steam glycerol reforming," Energy, Elsevier, vol. 64(C), pages 473-483.
    8. Sanchez-Jimenez, P.E. & Perez-Maqueda, L.A. & Valverde, J.M., 2014. "Nanosilica supported CaO: A regenerable and mechanically hard CO2 sorbent at Ca-looping conditions," Applied Energy, Elsevier, vol. 118(C), pages 92-99.
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    1. Schwengber, Carine Aline & Alves, Helton José & Schaffner, Rodolfo Andrade & da Silva, Fernando Alves & Sequinel, Rodrigo & Bach, Vanessa Rossato & Ferracin, Ricardo José, 2016. "Overview of glycerol reforming for hydrogen production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 58(C), pages 259-266.
    2. Macedo, M. Salomé & Soria, M.A. & Madeira, Luis M., 2021. "Process intensification for hydrogen production through glycerol steam reforming," Renewable and Sustainable Energy Reviews, Elsevier, vol. 146(C).
    3. Okoye, P.U. & Hameed, B.H., 2016. "Review on recent progress in catalytic carboxylation and acetylation of glycerol as a byproduct of biodiesel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 53(C), pages 558-574.
    4. Charisiou, N.D. & Italiano, C. & Pino, L. & Sebastian, V. & Vita, A. & Goula, M.A., 2020. "Hydrogen production via steam reforming of glycerol over Rh/γ-Al2O3 catalysts modified with CeO2, MgO or La2O3," Renewable Energy, Elsevier, vol. 162(C), pages 908-925.
    5. Okoye, P.U. & Abdullah, A.Z. & Hameed, B.H., 2017. "A review on recent developments and progress in the kinetics and deactivation of catalytic acetylation of glycerol—A byproduct of biodiesel," Renewable and Sustainable Energy Reviews, Elsevier, vol. 74(C), pages 387-401.
    6. Menezes, João Paulo da S.Q. & Duarte, Karine R. & Manfro, Robinson L. & Souza, Mariana M.V.M., 2020. "Effect of niobia addition on cobalt catalysts supported on alumina for glycerol steam reforming," Renewable Energy, Elsevier, vol. 148(C), pages 864-875.
    7. Rocha, Cláudio & Soria, M.A. & Madeira, Luís M., 2022. "Use of Ni-containing catalysts for synthetic olive mill wastewater steam reforming," Renewable Energy, Elsevier, vol. 185(C), pages 1329-1342.
    8. Chen, Guanyi & Tao, Junyu & Liu, Caixia & Yan, Beibei & Li, Wanqing & Li, Xiangping, 2017. "Hydrogen production via acetic acid steam reforming: A critical review on catalysts," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 1091-1098.
    9. Abel Rodrigues & João Carlos Bordado & Rui Galhano dos Santos, 2017. "Upgrading the Glycerol from Biodiesel Production as a Source of Energy Carriers and Chemicals—A Technological Review for Three Chemical Pathways," Energies, MDPI, vol. 10(11), pages 1-36, November.

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