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Clathrate hydrate technology for cold storage in air conditioning systems

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  • Wang, Xiaolin
  • Dennis, Mike
  • Hou, Liangzhuo

Abstract

Clathrate hydrate is an attractive technology for cold storage applications. It offers a high cold storage density and elevates the phase change temperature compared to water. It offers better heat transfer properties and improved cyclic stability compared to eutectic salts. This paper reviews previous work on clathrate hydrates as phase change materials (PCMs) for cold storage air conditioning applications. Three aspects have been focused on: the characteristics of clathrate hydrates, modification of clathrate hydrate properties, and practical utilization of clathrate hydrates as cold storage media. Specifically, refrigerant clathrate hydrates, CO2 hydrates, hydrocarbon clathrate hydrates and multi-component clathrate hydrates are introduced. Technologies to decrease equilibrium pressure, increase dissociation enthalpy, accelerate formation process, decrease supercooling extent and enhance gas solubility are summarized. Clathrate hydrates based cold storage air conditioning systems that transport cooling in a manner of fixed container as well as in hydrate slurry are reviewed, and optimizing methods of system performance are studied. Finally, four features of clathrate hydrates, namely the self-preservation effect, memory effect, gas conversion and hydrate structure transformation are discussed.

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  • Wang, Xiaolin & Dennis, Mike & Hou, Liangzhuo, 2014. "Clathrate hydrate technology for cold storage in air conditioning systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 36(C), pages 34-51.
    • Handle: RePEc:eee:rensus:v:36:y:2014:i:c:p:34-51
    DOI: 10.1016/j.rser.2014.04.032
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    Cited by:

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    9. Fatima Doria Benmesbah & Livio Ruffine & Pascal Clain & Véronique Osswald & Olivia Fandino & Laurence Fournaison & Anthony Delahaye, 2020. "Methane Hydrate Formation and Dissociation in Sand Media: Effect of Water Saturation, Gas Flowrate and Particle Size," Energies, MDPI, vol. 13(19), pages 1-21, October.
    10. Yang, Mingjun & Chong, Zheng Rong & Zheng, Jianan & Song, Yongchen & Linga, Praveen, 2017. "Advances in nuclear magnetic resonance (NMR) techniques for the investigation of clathrate hydrates," Renewable and Sustainable Energy Reviews, Elsevier, vol. 74(C), pages 1346-1360.
    11. Veluswamy, Hari Prakash & Kumar, Asheesh & Seo, Yutaek & Lee, Ju Dong & Linga, Praveen, 2018. "A review of solidified natural gas (SNG) technology for gas storage via clathrate hydrates," Applied Energy, Elsevier, vol. 216(C), pages 262-285.
    12. Dong, Hongsheng & Wang, Jiaqi & Xie, Zhuoxue & Wang, Bin & Zhang, Lunxiang & Shi, Quan, 2021. "Potential applications based on the formation and dissociation of gas hydrates," Renewable and Sustainable Energy Reviews, Elsevier, vol. 143(C).
    13. Bi, Yuehong & Chen, Jie & Miao, Zhen, 2016. "Thermodynamic optimization for dissociation process of gas hydrates," Energy, Elsevier, vol. 106(C), pages 270-276.
    14. Chi-Chun Lo & Shang-Ho Tsai & Bor-Shyh Lin, 2016. "Ice Storage Air-Conditioning System Simulation with Dynamic Electricity Pricing: A Demand Response Study," Energies, MDPI, vol. 9(2), pages 1-16, February.
    15. Kim, Shol & Lee, Seong Hyuk & Kang, Yong Tae, 2017. "Characteristics of CO2 hydrate formation/dissociation in H2O + THF aqueous solution and estimation of CO2 emission reduction by district cooling application," Energy, Elsevier, vol. 120(C), pages 362-373.
    16. Veluswamy, Hari Prakash & Kumar, Asheesh & Premasinghe, Kulesha & Linga, Praveen, 2017. "Effect of guest gas on the mixed tetrahydrofuran hydrate kinetics in a quiescent system," Applied Energy, Elsevier, vol. 207(C), pages 573-583.
    17. Cheng, Chuanxiao & Wang, Fan & Tian, Yongjia & Wu, Xuehong & Zheng, Jili & Zhang, Jun & Li, Longwei & Yang, Penglin & Zhao, Jiafei, 2020. "Review and prospects of hydrate cold storage technology," Renewable and Sustainable Energy Reviews, Elsevier, vol. 117(C).
    18. Zhao, Jiafei & Song, Yongchen & Lim, Xin-Le & Lam, Wei-Haur, 2017. "Opportunities and challenges of gas hydrate policies with consideration of environmental impacts," Renewable and Sustainable Energy Reviews, Elsevier, vol. 70(C), pages 875-885.

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