IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v40y2012i1p47-58.html
   My bibliography  Save this article

Recovery of methane from hydrate reservoir with gaseous carbon dioxide using a three-dimensional middle-size reactor

Author

Listed:
  • Yuan, Qing
  • Sun, Chang-Yu
  • Yang, Xin
  • Ma, Ping-Chuan
  • Ma, Zheng-Wei
  • Liu, Bei
  • Ma, Qing-Lan
  • Yang, Lan-Ying
  • Chen, Guang-Jin

Abstract

Three groups of hydrate-bearing sediment samples with/without underlying gas were prepared using a three-dimensional middle-size reactor to investigate the favorable conditions for methane recovery from hydrate reservoir with gaseous CO2. The experimental results indicated that hydrate reservoir with underlying free gas, high saturation of free gas and low saturation of water is appropriate for recovering CH4 with CO2. For the replacement mechanism, it is assumed that the CO2–CH4 replacement chiefly includes two parts: CH4 hydrate dissociation and mixed hydrate re-formation from the dissociated water and free water. In the re-formed hydrate, CO2 molecules mainly occupy the large cage and CH4 molecules mainly occupy the small cage. A kinetics model was constructed to describe the replacement process, which considers not only the kinetic reaction of CH4–CO2 replacement but also the reaction between CO2 and free water. The calculated results agree well with the experimental data. The influencing factors on the replacement rate were also discussed according to the developed model. It is found that the replacement rate and the mole fraction of CH4 in gas phase increase with the increase of initial CO2 mole fraction, the decrease of system pressure, and the increase of diffusion coefficient of CH4 in hydrate layer.

Suggested Citation

  • Yuan, Qing & Sun, Chang-Yu & Yang, Xin & Ma, Ping-Chuan & Ma, Zheng-Wei & Liu, Bei & Ma, Qing-Lan & Yang, Lan-Ying & Chen, Guang-Jin, 2012. "Recovery of methane from hydrate reservoir with gaseous carbon dioxide using a three-dimensional middle-size reactor," Energy, Elsevier, vol. 40(1), pages 47-58.
    • Handle: RePEc:eee:energy:v:40:y:2012:i:1:p:47-58
    DOI: 10.1016/j.energy.2012.02.043
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544212001387
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2012.02.043?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Lee, Hyun Ju & Lee, Ju Dong & Linga, Praveen & Englezos, Peter & Kim, Young Seok & Lee, Man Sig & Kim, Yang Do, 2010. "Gas hydrate formation process for pre-combustion capture of carbon dioxide," Energy, Elsevier, vol. 35(6), pages 2729-2733.
    2. Li, Xiao-Sen & Xu, Chun-Gang & Chen, Zhao-Yang & Wu, Hui-Jie, 2010. "Tetra-n-butyl ammonium bromide semi-clathrate hydrate process for post-combustion capture of carbon dioxide in the presence of dodecyl trimethyl ammonium chloride," Energy, Elsevier, vol. 35(9), pages 3902-3908.
    3. Yamasaki, A & Wakatsuki, M & Teng, H & Yanagisawa, Y & Yamada, K, 2000. "A new ocean disposal scenario for anthropogenic CO2: CO2 hydrate formation in a submerged crystallizer and its disposal," Energy, Elsevier, vol. 25(1), pages 85-96.
    4. Li, Xiao-Sen & Xu, Chun-Gang & Chen, Zhao-Yang & Wu, Hui-Jie, 2011. "Hydrate-based pre-combustion carbon dioxide capture process in the system with tetra-n-butyl ammonium bromide solution in the presence of cyclopentane," Energy, Elsevier, vol. 36(3), pages 1394-1403.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Wang, Xiaolin & Zhang, Fengyuan & Lipiński, Wojciech, 2020. "Research progress and challenges in hydrate-based carbon dioxide capture applications," Applied Energy, Elsevier, vol. 269(C).
    2. Ding, Ya-Long & Xu, Chun-Gang & Yu, Yi-Song & Li, Xiao-Sen, 2017. "Methane recovery from natural gas hydrate with simulated IGCC syngas," Energy, Elsevier, vol. 120(C), pages 192-198.
    3. Babu, Ponnivalavan & Ong, Hong Wen Nelson & Linga, Praveen, 2016. "A systematic kinetic study to evaluate the effect of tetrahydrofuran on the clathrate process for pre-combustion capture of carbon dioxide," Energy, Elsevier, vol. 94(C), pages 431-442.
    4. Babu, Ponnivalavan & Ho, Chie Yin & Kumar, Rajnish & Linga, Praveen, 2014. "Enhanced kinetics for the clathrate process in a fixed bed reactor in the presence of liquid promoters for pre-combustion carbon dioxide capture," Energy, Elsevier, vol. 70(C), pages 664-673.
    5. Xu, Chun-Gang & Zhang, Shao-Hong & Cai, Jing & Chen, Zhao-Yang & Li, Xiao-Sen, 2013. "CO2 (carbon dioxide) separation from CO2–H2 (hydrogen) gas mixtures by gas hydrates in TBAB (tetra-n-butyl ammonium bromide) solution and Raman spectroscopic analysis," Energy, Elsevier, vol. 59(C), pages 719-725.
    6. Yu, Yi-Song & Xu, Chun-Gang & Li, Xiao-Sen, 2018. "Crystal morphology-based kinetic study of carbon dioxide-hydrogen-tetra-n-butyl ammonium bromide hydrates formation in a static system," Energy, Elsevier, vol. 143(C), pages 546-553.
    7. Lee, Yohan & Lee, Dongyoung & Lee, Jong-Won & Seo, Yongwon, 2016. "Enclathration of CO2 as a co-guest of structure H hydrates and its implications for CO2 capture and sequestration," Applied Energy, Elsevier, vol. 163(C), pages 51-59.
    8. Yang, Mingjun & Jing, Wen & Zhao, Jiafei & Ling, Zheng & Song, Yongchen, 2016. "Promotion of hydrate-based CO2 capture from flue gas by additive mixtures (THF (tetrahydrofuran) + TBAB (tetra-n-butyl ammonium bromide))," Energy, Elsevier, vol. 106(C), pages 546-553.
    9. Babu, Ponnivalavan & Linga, Praveen & Kumar, Rajnish & Englezos, Peter, 2015. "A review of the hydrate based gas separation (HBGS) process for carbon dioxide pre-combustion capture," Energy, Elsevier, vol. 85(C), pages 261-279.
    10. Xu, Chun-Gang & Li, Xiao-Sen & Lv, Qiu-Nan & Chen, Zhao-Yang & Cai, Jing, 2012. "Hydrate-based CO2 (carbon dioxide) capture from IGCC (integrated gasification combined cycle) synthesis gas using bubble method with a set of visual equipment," Energy, Elsevier, vol. 44(1), pages 358-366.
    11. Wang, Lanyun & Zhang, Yajuan & Xie, Huilong & Lu, Xiaoran & Wen, Xinglin & Liu, Zhen & Zhou, Huajian & Liu, Zejian & Xu, Yongliang, 2022. "Effect of voltage and initial temperature on thermodynamics and kinetics of CO2 hydrate formation in an electrostatic spraying reactor," Energy, Elsevier, vol. 239(PD).
    12. Ma, Z.W. & Zhang, P. & Bao, H.S. & Deng, S., 2016. "Review of fundamental properties of CO2 hydrates and CO2 capture and separation using hydration method," Renewable and Sustainable Energy Reviews, Elsevier, vol. 53(C), pages 1273-1302.
    13. Yang, Mingjun & Zhou, Hang & Wang, Pengfei & Song, Yongchen, 2018. "Effects of additives on continuous hydrate-based flue gas separation," Applied Energy, Elsevier, vol. 221(C), pages 374-385.
    14. Chen, Zhaoyang & Fang, Jie & Xu, Chungang & Xia, Zhiming & Yan, Kefeng & Li, Xiaosen, 2020. "Carbon dioxide hydrate separation from Integrated Gasification Combined Cycle (IGCC) syngas by a novel hydrate heat-mass coupling method," Energy, Elsevier, vol. 199(C).
    15. Ho, Leong Chuan & Babu, Ponnivalavan & Kumar, Rajnish & Linga, Praveen, 2013. "HBGS (hydrate based gas separation) process for carbon dioxide capture employing an unstirred reactor with cyclopentane," Energy, Elsevier, vol. 63(C), pages 252-259.
    16. Veluswamy, Hari Prakash & Kumar, Asheesh & Premasinghe, Kulesha & Linga, Praveen, 2017. "Effect of guest gas on the mixed tetrahydrofuran hydrate kinetics in a quiescent system," Applied Energy, Elsevier, vol. 207(C), pages 573-583.
    17. Yan, Jin & Lu, Yi-Yu & Zhong, Dong-Liang & Zou, Zhen-Lin & Li, Jian-Bo, 2019. "Enhanced methane recovery from low-concentration coalbed methane by gas hydrate formation in graphite nanofluids," Energy, Elsevier, vol. 180(C), pages 728-736.
    18. Yi, Jie & Zhong, Dong-Liang & Yan, Jin & Lu, Yi-Yu, 2019. "Impacts of the surfactant sulfonated lignin on hydrate based CO2 capture from a CO2/CH4 gas mixture," Energy, Elsevier, vol. 171(C), pages 61-68.
    19. Veluswamy, Hari Prakash & Kumar, Rajnish & Linga, Praveen, 2014. "Hydrogen storage in clathrate hydrates: Current state of the art and future directions," Applied Energy, Elsevier, vol. 122(C), pages 112-132.
    20. Li, Ze-Yu & Xia, Zhi-Ming & Chen, Zhao-Yang & Li, Xiao-Sen & Xu, Chun-Gang & Yan, Ran, 2019. "The plateau effects and crystal transition study in Tetrahydrofuran (THF)/CO2/H2 hydrate formation processes," Applied Energy, Elsevier, vol. 238(C), pages 195-201.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:40:y:2012:i:1:p:47-58. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.