IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v93y2016icp323-331.html
   My bibliography  Save this article

Biodiesel production from soybean and Jatropha oils using cesium impregnated sodium zirconate as a heterogeneous base catalyst

Author

Listed:
  • Torres-Rodríguez, Daniela A.
  • Romero-Ibarra, Issis C.
  • Ibarra, Ilich A.
  • Pfeiffer, Heriberto

Abstract

Cesium modified sodium zirconate (Cs-Na2ZrO3) was prepared by ionic exchange from sodium zirconate (Na2ZrO3), which was synthesized via a solid state reaction. Both ceramics, i.e., pristine Na2ZrO3 and the Cs-Na2ZrO3, were used as basic heterogeneous catalysts in biodiesel production. Soybean and Jatropha oils were used as triglyceride sources for transesterification reactions. Parameters, such as catalyst concentration (between 0.5 and 3 wt%), reaction time, different methanol/vegetable oil molar ratios, and temperature of the reaction, were evaluated. The cesium cation influence was evaluated from the basic transesterification reactivity. The results showed that the introduction of cesium significantly modified the catalytic activity in biodiesel production. Cs enhanced the reaction kinetics in obtaining biodiesel and reduced the reaction time in comparison with pristine Na2ZrO3. The results showed that Cs-Na2ZrO3 as a basic heterogeneous catalyst exhibited the best fatty acid methyl esters (FAME) conversion for soybean oil (98.8%) at 1 wt%, 30:1 methanol/oil ratio, 65 °C, and 15 min. The best conditions for Jatropha oil (90.8%) were 3 wt%, 15:1 methanol/oil ratio, 65 °C, and 1 h. The impregnation of Na2ZrO3 with cesium represents a very exciting alternative heterogeneous base catalyst for biodiesel production.

Suggested Citation

  • Torres-Rodríguez, Daniela A. & Romero-Ibarra, Issis C. & Ibarra, Ilich A. & Pfeiffer, Heriberto, 2016. "Biodiesel production from soybean and Jatropha oils using cesium impregnated sodium zirconate as a heterogeneous base catalyst," Renewable Energy, Elsevier, vol. 93(C), pages 323-331.
    • Handle: RePEc:eee:renene:v:93:y:2016:i:c:p:323-331
    DOI: 10.1016/j.renene.2016.02.061
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148116301628
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2016.02.061?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Lee, H.V. & Juan, J.C. & Taufiq-Yap, Y.H., 2015. "Preparation and application of binary acid–base CaO–La2O3 catalyst for biodiesel production," Renewable Energy, Elsevier, vol. 74(C), pages 124-132.
    2. Atadashi, I.M. & Aroua, M.K. & Aziz, A. Abdul, 2011. "Biodiesel separation and purification: A review," Renewable Energy, Elsevier, vol. 36(2), pages 437-443.
    3. De Meyer, Annelies & Cattrysse, Dirk & Rasinmäki, Jussi & Van Orshoven, Jos, 2014. "Methods to optimise the design and management of biomass-for-bioenergy supply chains: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 31(C), pages 657-670.
    4. Guo, Pingmei & Zheng, Chang & Zheng, Mingming & Huang, Fenghong & Li, Wenlin & Huang, Qingde, 2013. "Solid base catalysts for production of fatty acid methyl esters," Renewable Energy, Elsevier, vol. 53(C), pages 377-383.
    5. Chouhan, A.P. Singh & Sarma, A.K., 2011. "Modern heterogeneous catalysts for biodiesel production: A comprehensive review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(9), pages 4378-4399.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Kumar, Praveen & Matoh, Lev & Srivastava, Vimal Chandra & Štangar, Urška Lavrenčič, 2020. "Synthesis of zinc/ferrocyanide nano-composite catalysts having a high activity for transesterification reaction," Renewable Energy, Elsevier, vol. 148(C), pages 946-952.
    2. Essamlali, Younes & Amadine, Othmane & Fihri, Aziz & Zahouily, Mohamed, 2019. "Sodium modified fluorapatite as a sustainable solid bi-functional catalyst for biodiesel production from rapeseed oil," Renewable Energy, Elsevier, vol. 133(C), pages 1295-1307.
    3. Masera, Kemal & Hossain, Abul Kalam, 2023. "Advancement of biodiesel fuel quality and NOx emission control techniques," Renewable and Sustainable Energy Reviews, Elsevier, vol. 178(C).
    4. Wang, Yongqiang & Zhao, Dan & Chen, Guanyi & Liu, Shejiang & Ji, Na & Ding, Hui & Fu, Jianfeng, 2019. "Preparation of phosphotungstic acid based poly(ionic liquid) and its application to esterification of palmitic acid," Renewable Energy, Elsevier, vol. 133(C), pages 317-324.
    5. Gupta, Jharna & Agarwal, Madhu & Dalai, A.K., 2019. "Intensified transesterification of mixture of edible and nonedible oils in reverse flow helical coil reactor for biodiesel production," Renewable Energy, Elsevier, vol. 134(C), pages 509-525.
    6. P Mohamed Shameer & P Mohamed Nishath, 2018. "Investigation and enhancement on fuel stability characteristics of biodiesel dosed with various synthetic antioxidants," Energy & Environment, , vol. 29(7), pages 1189-1207, November.
    7. Sakthivel, R. & Ramesh, K. & Purnachandran, R. & Mohamed Shameer, P., 2018. "A review on the properties, performance and emission aspects of the third generation biodiesels," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 2970-2992.
    8. Savaliya, Mehulkumar L. & Patel, Pooja J. & Dholakiya, Bharatkumar Z., 2017. "A simple and sustainable process for the preparation of fuel grade esters using PE-Si composite: A reusable catalytic system," Renewable Energy, Elsevier, vol. 109(C), pages 1-12.
    9. Kumar, Dipesh & Singh, Bhaskar, 2019. "BaZrO3 and Cs-BaZrO3 catalysed transesterification of Millettia Pinnata oil and optimisation of reaction variables by response surface Box-Behnken design," Renewable Energy, Elsevier, vol. 133(C), pages 411-421.
    10. Shelare, Sagar D. & Belkhode, Pramod N. & Nikam, Keval Chandrakant & Jathar, Laxmikant D. & Shahapurkar, Kiran & Soudagar, Manzoore Elahi M. & Veza, Ibham & Khan, T.M. Yunus & Kalam, M.A. & Nizami, Ab, 2023. "Biofuels for a sustainable future: Examining the role of nano-additives, economics, policy, internet of things, artificial intelligence and machine learning technology in biodiesel production," Energy, Elsevier, vol. 282(C).
    11. Teuku Meurah Indra Riayatsyah & Hwai Chyuan Ong & Wen Tong Chong & Lisa Aditya & Heri Hermansyah & Teuku Meurah Indra Mahlia, 2017. "Life Cycle Cost and Sensitivity Analysis of Reutealis trisperma as Non-Edible Feedstock for Future Biodiesel Production," Energies, MDPI, vol. 10(7), pages 1-21, June.
    12. Mijangos, Gabriela E. & Cuautli, Cristina & Romero-Ibarra, Issis C. & Vazquez-Arenas, Jorge & Santolalla-Vargas, Carlos E. & Santes, Víctor & Castañeda-Galván, Adrián A. & Pfeiffer, Heriberto, 2022. "Experimental and theoretical analysis revealing the underlying chemistry accounting for the heterogeneous transesterification reaction in Na2SiO3 and Li2SiO3 catalysts," Renewable Energy, Elsevier, vol. 184(C), pages 845-856.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Mansir, Nasar & Teo, Siow Hwa & Rashid, Umer & Saiman, Mohd Izham & Tan, Yen Ping & Alsultan, G. Abdulkareem & Taufiq-Yap, Yun Hin, 2018. "Modified waste egg shell derived bifunctional catalyst for biodiesel production from high FFA waste cooking oil. A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 3645-3655.
    2. Zhang, Heng & Li, Hu & Hu, Yulin & Venkateswara Rao, Kasanneni Tirumala & Xu, Chunbao (Charles) & Yang, Song, 2019. "Advances in production of bio-based ester fuels with heterogeneous bifunctional catalysts," Renewable and Sustainable Energy Reviews, Elsevier, vol. 114(C), pages 1-1.
    3. Shahinuzzaman, M. & Yaakob, Zahira & Ahmed, Yunus, 2017. "Non-sulphide zeolite catalyst for bio-jet-fuel conversion," Renewable and Sustainable Energy Reviews, Elsevier, vol. 77(C), pages 1375-1384.
    4. Vadery, Vinu & Cherikkallinmel, Sudha Kochiyil & Ramakrishnan, Resmi M. & Sugunan, Sankaran & Narayanan, Binitha N., 2019. "Green production of biodiesel over waste borosilicate glass derived catalyst and the process up-gradation in pilot scale," Renewable Energy, Elsevier, vol. 141(C), pages 1042-1053.
    5. Atabani, A.E. & Silitonga, A.S. & Badruddin, Irfan Anjum & Mahlia, T.M.I. & Masjuki, H.H. & Mekhilef, S., 2012. "A comprehensive review on biodiesel as an alternative energy resource and its characteristics," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(4), pages 2070-2093.
    6. Babu, D. & Karvembu, R. & Anand, R., 2018. "Impact of split injection strategy on combustion, performance and emissions characteristics of biodiesel fuelled common rail direct injection assisted diesel engine," Energy, Elsevier, vol. 165(PB), pages 577-592.
    7. Atadashi, I.M. & Aroua, M.K. & Abdul Aziz, A.R. & Sulaiman, N.M.N., 2011. "Membrane biodiesel production and refining technology: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(9), pages 5051-5062.
    8. Ba, Birome Holo & Prins, Christian & Prodhon, Caroline, 2016. "Models for optimization and performance evaluation of biomass supply chains: An Operations Research perspective," Renewable Energy, Elsevier, vol. 87(P2), pages 977-989.
    9. Li, Zhuoxue & Yang, Depo & Huang, Miaoling & Hu, Xinjun & Shen, Jiangang & Zhao, Zhimin & Chen, Jianping, 2012. "Chrysomya megacephala (Fabricius) larvae: A new biodiesel resource," Applied Energy, Elsevier, vol. 94(C), pages 349-354.
    10. Ambat, Indu & Srivastava, Varsha & Sillanpää, Mika, 2018. "Recent advancement in biodiesel production methodologies using various feedstock: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 90(C), pages 356-369.
    11. Goh, Brandon Han Hoe & Ong, Hwai Chyuan & Cheah, Mei Yee & Chen, Wei-Hsin & Yu, Kai Ling & Mahlia, Teuku Meurah Indra, 2019. "Sustainability of direct biodiesel synthesis from microalgae biomass: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 107(C), pages 59-74.
    12. Carland, Corinne & Goentzel, Jarrod & Montibeller, Gilberto, 2018. "Modeling the values of private sector agents in multi-echelon humanitarian supply chains," European Journal of Operational Research, Elsevier, vol. 269(2), pages 532-543.
    13. Cambero, Claudia & Sowlati, Taraneh, 2014. "Assessment and optimization of forest biomass supply chains from economic, social and environmental perspectives – A review of literature," Renewable and Sustainable Energy Reviews, Elsevier, vol. 36(C), pages 62-73.
    14. Emmanuel Garbolino & Warren Daniel & Guillermo Hinojos Mendoza, 2018. "Expected Global Warming Impacts on the Spatial Distribution and Productivity for 2050 of Five Species of Trees Used in the Wood Energy Supply Chain in France," Energies, MDPI, vol. 11(12), pages 1-17, December.
    15. Mirkouei, Amin & Haapala, Karl R. & Sessions, John & Murthy, Ganti S., 2017. "A review and future directions in techno-economic modeling and optimization of upstream forest biomass to bio-oil supply chains," Renewable and Sustainable Energy Reviews, Elsevier, vol. 67(C), pages 15-35.
    16. Gao, Evelyn & Sowlati, Taraneh & Akhtari, Shaghaygh, 2019. "Profit allocation in collaborative bioenergy and biofuel supply chains," Energy, Elsevier, vol. 188(C).
    17. Singlitico, Alessandro & Goggins, Jamie & Monaghan, Rory F.D., 2019. "The role of life cycle assessment in the sustainable transition to a decarbonised gas network through green gas production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 99(C), pages 16-28.
    18. Mensah, Theophilus Nii Odai & Oyewo, Ayobami Solomon & Breyer, Christian, 2021. "The role of biomass in sub-Saharan Africa’s fully renewable power sector – The case of Ghana," Renewable Energy, Elsevier, vol. 173(C), pages 297-317.
    19. Alberto Benato & Alarico Macor, 2019. "Italian Biogas Plants: Trend, Subsidies, Cost, Biogas Composition and Engine Emissions," Energies, MDPI, vol. 12(6), pages 1-31, March.
    20. Yazan, Devrim Murat & Mandras, Giovanni & Garau, Giorgio, 2017. "Environmental and economic sustainability of integrated production in bio-refineries: The thistle case in Sardinia," Renewable Energy, Elsevier, vol. 102(PB), pages 349-360.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:93:y:2016:i:c:p:323-331. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.