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Thermal treatment of waste photovoltaic module for recovery and recycling: Experimental assessment of the presence of metals in the gas emissions and in the ashes

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  • Tammaro, Marco
  • Rimauro, Juri
  • Fiandra, Valeria
  • Salluzzo, Antonio

Abstract

The rapid expansion of the photovoltaic (PV) module market in the last years will determine in the near future a remarkable growth of corresponding waste. Then, the hazardous materials contained in the modules, such as Cd, Pb and Cr, could be released in the environment if the waste panels will not be handled adequately. Recycling processes of silicon crystalline panels, finalized to separate PV cells from the glass, involve the removal of the EVA (Ethylene Vinyl Acetate) layer through different methods, as the thermal treatment. During this treatment, some hazardous components can be released due to thermal degradation process. In this paper the metals released in the gas emissions and in the ashes due to the thermal treatment of modules were evaluated. For this purpose, three samples of crystalline panels were heated in furnace up to 600 °C and the complete degradation of the EVA was obtained. A mass balance between the sample and its components, before and after treatment, was performed in order to assess the weight loss percentage. Finally, after thermal treatment a qualitative analysis on the separated PV cell surface was performed by SEM-EDS (Scanning Electron Microscope equipped with Energy Dispersive Spectrometer).

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  • Tammaro, Marco & Rimauro, Juri & Fiandra, Valeria & Salluzzo, Antonio, 2015. "Thermal treatment of waste photovoltaic module for recovery and recycling: Experimental assessment of the presence of metals in the gas emissions and in the ashes," Renewable Energy, Elsevier, vol. 81(C), pages 103-112.
    • Handle: RePEc:eee:renene:v:81:y:2015:i:c:p:103-112
    DOI: 10.1016/j.renene.2015.03.014
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    1. Gottesfeld, Perry & Cherry, Christopher R., 2011. "Lead emissions from solar photovoltaic energy systems in China and India," Energy Policy, Elsevier, vol. 39(9), pages 4939-4946, September.
    2. Bruton, TM, 1995. "Current status: Production of high efficiency monocrystalline silicon solar cells," Renewable Energy, Elsevier, vol. 6(3), pages 299-302.
    3. Fthenakis, Vasilis M., 2000. "End-of-life management and recycling of PV modules," Energy Policy, Elsevier, vol. 28(14), pages 1051-1058, November.
    4. Nugent, Daniel & Sovacool, Benjamin K., 2014. "Assessing the lifecycle greenhouse gas emissions from solar PV and wind energy: A critical meta-survey," Energy Policy, Elsevier, vol. 65(C), pages 229-244.
    5. Tsoutsos, Theocharis & Frantzeskaki, Niki & Gekas, Vassilis, 2005. "Environmental impacts from the solar energy technologies," Energy Policy, Elsevier, vol. 33(3), pages 289-296, February.
    6. Turney, Damon & Fthenakis, Vasilis, 2011. "Environmental impacts from the installation and operation of large-scale solar power plants," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(6), pages 3261-3270, August.
    7. Fthenakis, Vasilis M., 2004. "Life cycle impact analysis of cadmium in CdTe PV production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 8(4), pages 303-334, August.
    8. Peng, Jinqing & Lu, Lin & Yang, Hongxing, 2013. "Review on life cycle assessment of energy payback and greenhouse gas emission of solar photovoltaic systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 19(C), pages 255-274.
    9. Kang, Sukmin & Yoo, Sungyeol & Lee, Jina & Boo, Bonghyun & Ryu, Hojin, 2012. "Experimental investigations for recycling of silicon and glass from waste photovoltaic modules," Renewable Energy, Elsevier, vol. 47(C), pages 152-159.
    10. Hernandez, R.R. & Easter, S.B. & Murphy-Mariscal, M.L. & Maestre, F.T. & Tavassoli, M. & Allen, E.B. & Barrows, C.W. & Belnap, J. & Ochoa-Hueso, R. & Ravi, S. & Allen, M.F., 2014. "Environmental impacts of utility-scale solar energy," Renewable and Sustainable Energy Reviews, Elsevier, vol. 29(C), pages 766-779.
    11. Fthenakis, Vasilis & Wang, Wenming & Kim, Hyung Chul, 2009. "Life cycle inventory analysis of the production of metals used in photovoltaics," Renewable and Sustainable Energy Reviews, Elsevier, vol. 13(3), pages 493-517, April.
    12. McDonald, N.C. & Pearce, J.M., 2010. "Producer responsibility and recycling solar photovoltaic modules," Energy Policy, Elsevier, vol. 38(11), pages 7041-7047, November.
    Full references (including those not matched with items on IDEAS)

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    2. Ansanelli, G. & Fiorentino, G. & Tammaro, M. & Zucaro, A., 2021. "A Life Cycle Assessment of a recovery process from End-of-Life Photovoltaic Panels," Applied Energy, Elsevier, vol. 290(C).
    3. Maciej Chrzanowski & Piotr Zawada, 2023. "Fraction Separation Potential in the Recycling Process of Photovoltaic Panels at the Installation Site—A Conceptual Framework from an Economic and Ecological Safety Perspective," Energies, MDPI, vol. 16(5), pages 1-10, February.

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