IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v36y2011i2p726-731.html
   My bibliography  Save this article

Screening, optimization and kinetics of Jatropha curcas oil transesterification with heterogeneous catalysts

Author

Listed:
  • Zanette, Andréia F.
  • Barella, Rodrigo A.
  • Pergher, Sibele B.C.
  • Treichel, Helen
  • Oliveira, Débora
  • Mazutti, Marcio A.
  • Silva, Edson A.
  • Oliveira, J. Vladimir

Abstract

This work investigates the production of fatty acid methyl esters (FAME) from Jatropha curcas oil using a variety of heterogeneous catalysts: resins, zeolites, clays, hydrotalcites, aluminas and niobium oxide. For this purpose, a catalyst screening was first conducted in a batch reactor at the following operating conditions: oil to methanol molar ratio of 1:9, 6h of reaction, 5 wt% catalyst, at 333 and 393K. From the screening step, KSF clay and Amberlyst 15 catalysts were selected to carry out a 23 full factorial central composite rotatable design so as to elucidate the effects of process variables on FAME yield. The optimum reaction conditions for both catalysts were found to be oil to methanol molar ratio of 1:12, 5 wt% of catalyst, 433K and 6h of reaction with a FAME yield of about 70 wt%. A kinetic study was then experimentally performed and a semi-empirical model was built to represent the experimental data. Finally, catalyst re-utilization in five successive batch experiments was evaluated at the optimized conditions.

Suggested Citation

  • Zanette, Andréia F. & Barella, Rodrigo A. & Pergher, Sibele B.C. & Treichel, Helen & Oliveira, Débora & Mazutti, Marcio A. & Silva, Edson A. & Oliveira, J. Vladimir, 2011. "Screening, optimization and kinetics of Jatropha curcas oil transesterification with heterogeneous catalysts," Renewable Energy, Elsevier, vol. 36(2), pages 726-731.
    • Handle: RePEc:eee:renene:v:36:y:2011:i:2:p:726-731
    DOI: 10.1016/j.renene.2010.08.028
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S096014811000399X
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2010.08.028?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Pramanik, K, 2003. "Properties and use of jatropha curcas oil and diesel fuel blends in compression ignition engine," Renewable Energy, Elsevier, vol. 28(2), pages 239-248.
    2. Trakarnpruk, Wimonrat & Porntangjitlikit, Suriya, 2008. "Palm oil biodiesel synthesized with potassium loaded calcined hydrotalcite and effect of biodiesel blend on elastomer properties," Renewable Energy, Elsevier, vol. 33(7), pages 1558-1563.
    3. Yuan, Xingzhong & Liu, Jia & Zeng, Guangming & Shi, Jingang & Tong, Jingyi & Huang, Guohe, 2008. "Optimization of conversion of waste rapeseed oil with high FFA to biodiesel using response surface methodology," Renewable Energy, Elsevier, vol. 33(7), pages 1678-1684.
    4. Szczęsna Antczak, Mirosława & Kubiak, Aneta & Antczak, Tadeusz & Bielecki, Stanisław, 2009. "Enzymatic biodiesel synthesis – Key factors affecting efficiency of the process," Renewable Energy, Elsevier, vol. 34(5), pages 1185-1194.
    5. Basha, Syed Ameer & Gopal, K. Raja & Jebaraj, S., 2009. "A review on biodiesel production, combustion, emissions and performance," Renewable and Sustainable Energy Reviews, Elsevier, vol. 13(6-7), pages 1628-1634, August.
    6. Park, Ji-Yeon & Wang, Zhong-Ming & Kim, Deog-Keun & Lee, Jin-Suk, 2010. "Effects of water on the esterification of free fatty acids by acid catalysts," Renewable Energy, Elsevier, vol. 35(3), pages 614-618.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Kumar, Praveen & Matoh, Lev & Srivastava, Vimal Chandra & Štangar, Urška Lavrenčič, 2020. "Synthesis of zinc/ferrocyanide nano-composite catalysts having a high activity for transesterification reaction," Renewable Energy, Elsevier, vol. 148(C), pages 946-952.
    2. Abdullah, Mudafer & Bulent Koc, A., 2013. "Oil removal from waste coffee grounds using two-phase solvent extraction enhanced with ultrasonication," Renewable Energy, Elsevier, vol. 50(C), pages 965-970.
    3. Badday, Ali Sabri & Abdullah, Ahmad Zuhairi & Lee, Keat Teong & Khayoon, Muataz Sh., 2012. "Intensification of biodiesel production via ultrasonic-assisted process: A critical review on fundamentals and recent development," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(7), pages 4574-4587.
    4. Amani, H. & Ahmad, Z. & Hameed, B.H., 2014. "Synthesis of fatty acid methyl esters via the methanolysis of palm oil over Ca3.5xZr0.5yAlxO3 mixed oxide catalyst," Renewable Energy, Elsevier, vol. 66(C), pages 680-685.
    5. Mukhtar, Ahmad & Saqib, Sidra & Mubashir, Muhammad & Ullah, Sami & Inayat, Abrar & Mahmood, Abid & Ibrahim, Muhammad & Show, Pau Loke, 2021. "Mitigation of CO2 emissions by transforming to biofuels: Optimization of biofuels production processes," Renewable and Sustainable Energy Reviews, Elsevier, vol. 150(C).
    6. Laskar, Ikbal Bahar & Changmai, Bishwajit & Gupta, Rajat & Shi, Da & Jenkinson, Kellie J. & Wheatley, Andrew E.H. & Rokhum, Lalthazuala, 2021. "A mesoporous polysulfonic acid-formaldehyde polymeric catalyst for biodiesel production from Jatropha curcas oil," Renewable Energy, Elsevier, vol. 173(C), pages 415-421.
    7. Endalew, Abebe K. & Kiros, Yohannes & Zanzi, Rolando, 2011. "Heterogeneous catalysis for biodiesel production from Jatropha curcas oil (JCO)," Energy, Elsevier, vol. 36(5), pages 2693-2700.
    8. Banković-Ilić, Ivana B. & Stamenković, Olivera S. & Veljković, Vlada B., 2012. "Biodiesel production from non-edible plant oils," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(6), pages 3621-3647.
    9. Kalam, M.A. & Ahamed, J.U. & Masjuki, H.H., 2012. "Land availability of Jatropha production in Malaysia," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(6), pages 3999-4007.
    10. Mardhiah, H. Haziratul & Ong, Hwai Chyuan & Masjuki, H.H. & Lim, Steven & Lee, H.V., 2017. "A review on latest developments and future prospects of heterogeneous catalyst in biodiesel production from non-edible oils," Renewable and Sustainable Energy Reviews, Elsevier, vol. 67(C), pages 1225-1236.
    11. Navarro-Pineda, Freddy S. & Baz-Rodríguez, Sergio A. & Handler, Robert & Sacramento-Rivero, Julio C., 2016. "Advances on the processing of Jatropha curcas towards a whole-crop biorefinery," Renewable and Sustainable Energy Reviews, Elsevier, vol. 54(C), pages 247-269.
    12. de Aguiar, Viviane Marques & de Souza, Andrea Luzia F. & Galdino, Fernanda S. & da Silva, Michelle Martha C. & Teixeira, Viviane Gomes & Lachter, Elizabeth R., 2017. "Sulfonated poly(divinylbenzene) and poly(styrene-divinylbenzene) as catalysts for esterification of fatty acids," Renewable Energy, Elsevier, vol. 114(PB), pages 725-732.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Charlotte Stead & Zia Wadud & Chris Nash & Hu Li, 2019. "Introduction of Biodiesel to Rail Transport: Lessons from the Road Sector," Sustainability, MDPI, vol. 11(3), pages 1-20, February.
    2. Hasan, M.M. & Rahman, M.M., 2017. "Performance and emission characteristics of biodiesel–diesel blend and environmental and economic impacts of biodiesel production: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 74(C), pages 938-948.
    3. Fazal, M.A. & Haseeb, A.S.M.A. & Masjuki, H.H., 2011. "Biodiesel feasibility study: An evaluation of material compatibility; performance; emission and engine durability," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(2), pages 1314-1324, February.
    4. Tariq, Muhammad & Ali, Saqib & Khalid, Nasir, 2012. "Activity of homogeneous and heterogeneous catalysts, spectroscopic and chromatographic characterization of biodiesel: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(8), pages 6303-6316.
    5. Palash, S.M. & Kalam, M.A. & Masjuki, H.H. & Masum, B.M. & Rizwanul Fattah, I.M. & Mofijur, M., 2013. "Impacts of biodiesel combustion on NOx emissions and their reduction approaches," Renewable and Sustainable Energy Reviews, Elsevier, vol. 23(C), pages 473-490.
    6. Atabani, A.E. & Silitonga, A.S. & Ong, H.C. & Mahlia, T.M.I. & Masjuki, H.H. & Badruddin, Irfan Anjum & Fayaz, H., 2013. "Non-edible vegetable oils: A critical evaluation of oil extraction, fatty acid compositions, biodiesel production, characteristics, engine performance and emissions production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 18(C), pages 211-245.
    7. Ong, H.C. & Mahlia, T.M.I. & Masjuki, H.H. & Norhasyima, R.S., 2011. "Comparison of palm oil, Jatropha curcas and Calophyllum inophyllum for biodiesel: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(8), pages 3501-3515.
    8. Altarazi, Yazan S.M. & Abu Talib, Abd Rahim & Yu, Jianglong & Gires, Ezanee & Abdul Ghafir, Mohd Fahmi & Lucas, John & Yusaf, Talal, 2022. "Effects of biofuel on engines performance and emission characteristics: A review," Energy, Elsevier, vol. 238(PC).
    9. Monteiro, Rodolpho R.C. & Arana-Peña, Sara & da Rocha, Thays N. & Miranda, Letícia P. & Berenguer-Murcia, Ángel & Tardioli, Paulo W. & dos Santos, José C.S. & Fernandez-Lafuente, Roberto, 2021. "Liquid lipase preparations designed for industrial production of biodiesel. Is it really an optimal solution?," Renewable Energy, Elsevier, vol. 164(C), pages 1566-1587.
    10. Banerjee, A. & Chakraborty, R., 2009. "Parametric sensitivity in transesterification of waste cooking oil for biodiesel production—A review," Resources, Conservation & Recycling, Elsevier, vol. 53(9), pages 490-497.
    11. Daroch, Maurycy & Geng, Shu & Wang, Guangyi, 2013. "Recent advances in liquid biofuel production from algal feedstocks," Applied Energy, Elsevier, vol. 102(C), pages 1371-1381.
    12. Atabani, A.E. & Silitonga, A.S. & Badruddin, Irfan Anjum & Mahlia, T.M.I. & Masjuki, H.H. & Mekhilef, S., 2012. "A comprehensive review on biodiesel as an alternative energy resource and its characteristics," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(4), pages 2070-2093.
    13. Singh, Paramvir & Varun, & Chauhan, S.R., 2016. "Carbonyl and aromatic hydrocarbon emissions from diesel engine exhaust using different feedstock: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 63(C), pages 269-291.
    14. Jocelyn Alejandra Cortez-Núñez & María Eugenia Gutiérrez-Castillo & Violeta Y. Mena-Cervantes & Ángel Refugio Terán-Cuevas & Luis Raúl Tovar-Gálvez & Juan Velasco, 2020. "A GIS Approach Land Suitability and Availability Analysis of Jatropha Curcas L. Growth in Mexico as a Potential Source for Biodiesel Production," Energies, MDPI, vol. 13(22), pages 1-23, November.
    15. Dwivedi, Gaurav & Sharma, M.P., 2014. "Impact of cold flow properties of biodiesel on engine performance," Renewable and Sustainable Energy Reviews, Elsevier, vol. 31(C), pages 650-656.
    16. Yaakob, Zahira & Mohammad, Masita & Alherbawi, Mohammad & Alam, Zahangir & Sopian, Kamaruzaman, 2013. "Overview of the production of biodiesel from Waste cooking oil," Renewable and Sustainable Energy Reviews, Elsevier, vol. 18(C), pages 184-193.
    17. Vallinayagam, R. & Vedharaj, S. & Yang, W.M. & Roberts, W.L. & Dibble, R.W., 2015. "Feasibility of using less viscous and lower cetane (LVLC) fuels in a diesel engine: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 51(C), pages 1166-1190.
    18. Mahlia, T.M.I. & Syazmi, Z.A.H.S. & Mofijur, M. & Abas, A.E. Pg & Bilad, M.R. & Ong, Hwai Chyuan & Silitonga, A.S., 2020. "Patent landscape review on biodiesel production: Technology updates," Renewable and Sustainable Energy Reviews, Elsevier, vol. 118(C).
    19. Arumugam, A. & Ponnusami, V., 2014. "Biodiesel production from Calophyllum inophyllum oil using lipase producing Rhizopus oryzae cells immobilized within reticulated foams," Renewable Energy, Elsevier, vol. 64(C), pages 276-282.
    20. Rajasekar, E. & Murugesan, A. & Subramanian, R. & Nedunchezhian, N., 2010. "Review of NOx reduction technologies in CI engines fuelled with oxygenated biomass fuels," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(7), pages 2113-2121, September.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:36:y:2011:i:2:p:726-731. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.