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Sulfated TiO2 supported molybdenum-based catalysts for transesterification of Jatropha seed oil: Effect of molybdenum species and acidity properties

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  • Gao, Xiu
  • Chen, Chao
  • Zhang, Wenlu
  • Hong, Yanping
  • Wang, Chunrong
  • Wu, Guoqiang

Abstract

A series of sulfated TiO2 supported Mo (xMo/1.5ST) catalysts were synthesized successfully and evaluated for the transesterification of Jatropha seed oil (JO) to biodiesel. Extensive characterization exhibits that the well dispersed Mo oxide species, with Mo6+ and Mo5+ oxidation states, were formed on the surface of the sulfated TiO2. The results indicate the presence of many sulfates species leads to the reduction of Mo6+ species to Mo5+ species. Furthermore, the catalytic activity of the xMo/1.5ST catalysts gradually increases with the increase of Mo-loading, although the sulfates content and the total acid intensity decrease. The transesterification process was fully investigated, and the 10Mo/1.5ST shows the highest yield of biodiesel of up to 97.42%. Additionally, the possible mechanism for the JO transesterification over Mo/1.5ST was described, and the fuel properties of the as-synthesized biodiesel conformed to the current international standards.

Suggested Citation

  • Gao, Xiu & Chen, Chao & Zhang, Wenlu & Hong, Yanping & Wang, Chunrong & Wu, Guoqiang, 2022. "Sulfated TiO2 supported molybdenum-based catalysts for transesterification of Jatropha seed oil: Effect of molybdenum species and acidity properties," Renewable Energy, Elsevier, vol. 191(C), pages 357-369.
    • Handle: RePEc:eee:renene:v:191:y:2022:i:c:p:357-369
    DOI: 10.1016/j.renene.2022.04.021
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    1. Dehghan, Leila & Golmakani, Mohammad-Taghi & Hosseini, Seyed Mohammad Hashem, 2019. "Optimization of microwave-assisted accelerated transesterification of inedible olive oil for biodiesel production," Renewable Energy, Elsevier, vol. 138(C), pages 915-922.
    2. Laskar, Ikbal Bahar & Gupta, Rajat & Chatterjee, Sushovan & Vanlalveni, Chhangte & Rokhum, Lalthazuala, 2020. "Taming waste: Waste Mangifera indica peel as a sustainable catalyst for biodiesel production at room temperature," Renewable Energy, Elsevier, vol. 161(C), pages 207-220.
    3. Mardhiah, H. Haziratul & Ong, Hwai Chyuan & Masjuki, H.H. & Lim, Steven & Lee, H.V., 2017. "A review on latest developments and future prospects of heterogeneous catalyst in biodiesel production from non-edible oils," Renewable and Sustainable Energy Reviews, Elsevier, vol. 67(C), pages 1225-1236.
    4. Kamel Ariffin, Maryam Farhana & Idris, Ani, 2022. "Fe2O3/Chitosan coated superparamagnetic nanoparticles supporting lipase enzyme from Candida Antarctica for microwave assisted biodiesel production," Renewable Energy, Elsevier, vol. 185(C), pages 1362-1375.
    5. Vasaki E, Madhu & Karri, Rama Rao & Ravindran, Gobinath & Paramasivan, Balasubramanian, 2021. "Predictive capability evaluation and optimization of sustainable biodiesel production from oleaginous biomass grown on pulp and paper industrial wastewater," Renewable Energy, Elsevier, vol. 168(C), pages 204-215.
    6. Mahmudul, H.M. & Hagos, F.Y. & Mamat, R. & Adam, A. Abdul & Ishak, W.F.W. & Alenezi, R., 2017. "Production, characterization and performance of biodiesel as an alternative fuel in diesel engines – A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 72(C), pages 497-509.
    7. Liu, Ying & Yan, Hanzhao & Liu, Jia & Dong, Wanglai & Cao, Zhi & Hu, Xingbang & Zhou, Zheng, 2020. "Acidic deep eutectic solvents with long carbon chains as catalysts and reaction media for biodiesel production," Renewable Energy, Elsevier, vol. 162(C), pages 1842-1853.
    8. Ma, Yingqun & Wang, Qunhui & Sun, Xiaohong & Wu, Chuanfu & Gao, Zhen, 2017. "Kinetics studies of biodiesel production from waste cooking oil using FeCl3-modified resin as heterogeneous catalyst," Renewable Energy, Elsevier, vol. 107(C), pages 522-530.
    9. Ma, Yingqun & Wang, Qunhui & Zheng, Lu & Gao, Zhen & Wang, Qiang & Ma, Yuhui, 2016. "Mixed methanol/ethanol on transesterification of waste cooking oil using Mg/Al hydrotalcite catalyst," Energy, Elsevier, vol. 107(C), pages 523-531.
    10. Bora, Akash Pratim & Dhawane, Sumit H. & Anupam, Kumar & Halder, Gopinath, 2018. "Biodiesel synthesis from Mesua ferrea oil using waste shell derived carbon catalyst," Renewable Energy, Elsevier, vol. 121(C), pages 195-204.
    11. Wang, Quan & Wenlei Xie, & Guo, Lihong, 2022. "Molybdenum and zirconium oxides supported on KIT-6 silica: A recyclable composite catalyst for one–pot biodiesel production from simulated low-quality oils," Renewable Energy, Elsevier, vol. 187(C), pages 907-922.
    12. Xie, Wenlei & Gao, Chunli & Li, Jiangbo, 2021. "Sustainable biodiesel production from low-quantity oils utilizing H6PV3MoW8O40 supported on magnetic Fe3O4/ZIF-8 composites," Renewable Energy, Elsevier, vol. 168(C), pages 927-937.
    13. Li, Ying & Niu, Shengli & Wang, Jun & Zhou, Wenbo & Wang, Yongzheng & Han, Kuihua & Lu, Chunmei, 2022. "Mesoporous SrTiO3 perovskite as a heterogeneous catalyst for biodiesel production: Experimental and DFT studies," Renewable Energy, Elsevier, vol. 184(C), pages 164-175.
    14. Das, Velentina & Tripathi, Abhishek Mani & Borah, Manash Jyoti & Dunford, Nurhan Turgut & Deka, Dhanapati, 2020. "Cobalt-doped CaO catalyst synthesized and applied for algal biodiesel production," Renewable Energy, Elsevier, vol. 161(C), pages 1110-1119.
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