IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v189y2022icp421-434.html
   My bibliography  Save this article

Magnetic reusable acid-base bifunctional Co doped Fe2O3–CaO nanocatalysts for biodiesel production from soybean oil and waste frying oil

Author

Listed:
  • Xia, Shaige
  • Li, Jian
  • Chen, Guanyi
  • Tao, Junyu
  • Li, Wanqing
  • Zhu, Guangbin

Abstract

Biodiesel is a promising renewable liquid fuel, but the poor reusability and low FFA resistance of the transesterification catalyst is hindering its development. In this work, acid-base bi-functional Co doped Fe2O3–CaO nanocatalysts were prepared by one-pot hydrothermal followed by calcination method for biodiesel production from soybean oil and waste frying oil (WFO). The catalyst was characterized by XRD, XPS, TPD technologies and so on. The results showed that the doping of Co into the Fe2O3 lattice makes α-Fe2O3 crystal transform into γ-Fe2O3 thus the catalyst has stronger magnetic strength for magnetic separation. And the catalyst preparation conditions and reaction parameters were optimized, the results showed that under the 16:1 methanol to oil molar ratio, 3 wt% catalyst dosage, and 70 °C for 150 min, the enhanced catalytic activity and improved FFA resistance with the 98.2% and 91.5% biodiesel yield from soybean oil and WFO can be obtained, respectively. In addition, stability and reusability of the catalysts were improved and no distinct activity drop after 5 consecutive transesterification recycles. Furthermore, the functional group and composition of biodiesel were analyzed using GC-MS, ATR-FTIR and NMR techniques. And combustion dynamic characteristics were analyzed by TG, and the results demonstrate that the produced biodiesel has good combustion ability and potential application in industrial production.

Suggested Citation

  • Xia, Shaige & Li, Jian & Chen, Guanyi & Tao, Junyu & Li, Wanqing & Zhu, Guangbin, 2022. "Magnetic reusable acid-base bifunctional Co doped Fe2O3–CaO nanocatalysts for biodiesel production from soybean oil and waste frying oil," Renewable Energy, Elsevier, vol. 189(C), pages 421-434.
    • Handle: RePEc:eee:renene:v:189:y:2022:i:c:p:421-434
    DOI: 10.1016/j.renene.2022.02.122
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148122002713
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2022.02.122?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Đặng, Tấn-Hiệp & Nguyễn, Xuân-Hoàn & Chou, Chi-Lin & Chen, Bing-Hung, 2021. "Preparation of cancrinite-type zeolite from diatomaceous earth as transesterification catalysts for biodiesel production," Renewable Energy, Elsevier, vol. 174(C), pages 347-358.
    2. Foroutan, Rauf & Mohammadi, Reza & Razeghi, Jafar & Ramavandi, Bahman, 2021. "Biodiesel production from edible oils using algal biochar/CaO/K2CO3 as a heterogeneous and recyclable catalyst," Renewable Energy, Elsevier, vol. 168(C), pages 1207-1216.
    3. Li, Yuesong & Lian, Shuang & Tong, Dongmei & Song, Ruili & Yang, Wenyan & Fan, Yong & Qing, Renwei & Hu, Changwei, 2011. "One-step production of biodiesel from Nannochloropsis sp. on solid base Mg–Zr catalyst," Applied Energy, Elsevier, vol. 88(10), pages 3313-3317.
    4. Abdelmigeed, Mai O. & Al-Sakkari, Eslam G. & Hefney, Mahmoud S. & Ismail, Fatma M. & Abdelghany, Amr & Ahmed, Tamer S. & Ismail, Ibrahim M., 2021. "Magnetized ZIF-8 impregnated with sodium hydroxide as a heterogeneous catalyst for high-quality biodiesel production," Renewable Energy, Elsevier, vol. 165(P1), pages 405-419.
    5. Hu, Ningmeng & Ning, Ping & He, Liang & Guan, Qingqing & Shi, Yuzhen & Miao, Rongrong, 2021. "Near-room temperature transesterification over bifunctional CunO-Bs/SBA-15 catalyst for biodiesel production," Renewable Energy, Elsevier, vol. 170(C), pages 1-11.
    6. Mardhiah, H. Haziratul & Ong, Hwai Chyuan & Masjuki, H.H. & Lim, Steven & Lee, H.V., 2017. "A review on latest developments and future prospects of heterogeneous catalyst in biodiesel production from non-edible oils," Renewable and Sustainable Energy Reviews, Elsevier, vol. 67(C), pages 1225-1236.
    7. Khatibi, Maryam & Khorasheh, Farhad & Larimi, Afsanehsadat, 2021. "Biodiesel production via transesterification of canola oil in the presence of Na–K doped CaO derived from calcined eggshell," Renewable Energy, Elsevier, vol. 163(C), pages 1626-1636.
    8. Marinković, Dalibor M. & Stanković, Miroslav V. & Veličković, Ana V. & Avramović, Jelena M. & Miladinović, Marija R. & Stamenković, Olivera O. & Veljković, Vlada B. & Jovanović, Dušan M., 2016. "Calcium oxide as a promising heterogeneous catalyst for biodiesel production: Current state and perspectives," Renewable and Sustainable Energy Reviews, Elsevier, vol. 56(C), pages 1387-1408.
    9. Yusuff, Adeyinka S. & Bhonsle, Aman K. & Bangwal, Dinesh P. & Atray, Neeraj, 2021. "Development of a barium-modified zeolite catalyst for biodiesel production from waste frying oil: Process optimization by design of experiment," Renewable Energy, Elsevier, vol. 177(C), pages 1253-1264.
    10. Borges, M.E. & Díaz, L., 2012. "Recent developments on heterogeneous catalysts for biodiesel production by oil esterification and transesterification reactions: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(5), pages 2839-2849.
    11. Liang Zhou & Jingang Yao & Zhaoxia Ren & Zhenqiang Yu & Hongzhen Cai, 2020. "Development of Magnetic Multi-Shelled Hollow Catalyst for Biodiesel Production," Energies, MDPI, vol. 13(11), pages 1-14, June.
    12. Issariyakul, Titipong & Dalai, Ajay K., 2014. "Biodiesel from vegetable oils," Renewable and Sustainable Energy Reviews, Elsevier, vol. 31(C), pages 446-471.
    13. Ibrahim, Shaimaa M., 2021. "Preparation, characterization and application of novel surface-modified ZrSnO4 as Sn-based TMOs catalysts for the stearic acid esterification with methanol to biodiesel," Renewable Energy, Elsevier, vol. 173(C), pages 151-163.
    14. Bozbas, Kahraman, 2008. "Biodiesel as an alternative motor fuel: Production and policies in the European Union," Renewable and Sustainable Energy Reviews, Elsevier, vol. 12(2), pages 542-552, February.
    15. Li, Ying & Niu, Shengli & Wang, Jun & Zhou, Wenbo & Wang, Yongzheng & Han, Kuihua & Lu, Chunmei, 2022. "Mesoporous SrTiO3 perovskite as a heterogeneous catalyst for biodiesel production: Experimental and DFT studies," Renewable Energy, Elsevier, vol. 184(C), pages 164-175.
    16. Das, Velentina & Tripathi, Abhishek Mani & Borah, Manash Jyoti & Dunford, Nurhan Turgut & Deka, Dhanapati, 2020. "Cobalt-doped CaO catalyst synthesized and applied for algal biodiesel production," Renewable Energy, Elsevier, vol. 161(C), pages 1110-1119.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Li, Hui & Wang, Yongbo & Han, Zhihao & Wang, Tianyu & Wang, Yunpu & Liu, Chenhui & Guo, Min & Li, Guoning & Lu, Wanpeng & Yu, Mingzhi & Ma, Xiaoling, 2022. "Nanosheet like CaO/C derived from Ca-BTC for biodiesel production assisted with microwave," Applied Energy, Elsevier, vol. 326(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Mansir, Nasar & Teo, Siow Hwa & Rashid, Umer & Saiman, Mohd Izham & Tan, Yen Ping & Alsultan, G. Abdulkareem & Taufiq-Yap, Yun Hin, 2018. "Modified waste egg shell derived bifunctional catalyst for biodiesel production from high FFA waste cooking oil. A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 3645-3655.
    2. Gao, Xiu & Chen, Chao & Zhang, Wenlu & Hong, Yanping & Wang, Chunrong & Wu, Guoqiang, 2022. "Sulfated TiO2 supported molybdenum-based catalysts for transesterification of Jatropha seed oil: Effect of molybdenum species and acidity properties," Renewable Energy, Elsevier, vol. 191(C), pages 357-369.
    3. Goh, Brandon Han Hoe & Ong, Hwai Chyuan & Cheah, Mei Yee & Chen, Wei-Hsin & Yu, Kai Ling & Mahlia, Teuku Meurah Indra, 2019. "Sustainability of direct biodiesel synthesis from microalgae biomass: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 107(C), pages 59-74.
    4. Zhang, Heng & Li, Hu & Hu, Yulin & Venkateswara Rao, Kasanneni Tirumala & Xu, Chunbao (Charles) & Yang, Song, 2019. "Advances in production of bio-based ester fuels with heterogeneous bifunctional catalysts," Renewable and Sustainable Energy Reviews, Elsevier, vol. 114(C), pages 1-1.
    5. Xie, Wenlei & Li, Jiangbo, 2023. "Magnetic solid catalysts for sustainable and cleaner biodiesel production: A comprehensive review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 171(C).
    6. Goli, Jibril & Sahu, Omprakash, 2018. "Development of heterogeneous alkali catalyst from waste chicken eggshell for biodiesel production," Renewable Energy, Elsevier, vol. 128(PA), pages 142-154.
    7. Dahdah, Eliane & Estephane, Jane & Haydar, Reem & Youssef, Yara & El Khoury, Bilal & Gennequin, Cedric & Aboukaïs, Antoine & Abi-Aad, Edmond & Aouad, Samer, 2020. "Biodiesel production from refined sunflower oil over Ca–Mg–Al catalysts: Effect of the composition and the thermal treatment," Renewable Energy, Elsevier, vol. 146(C), pages 1242-1248.
    8. Bambase, Manolito E. & Almazan, Rober Angelo R. & Demafelis, Rex B. & Sobremisana, Marisa J. & Dizon, Lisa Stephanie H., 2021. "Biodiesel production from refined coconut oil using hydroxide-impregnated calcium oxide by cosolvent method," Renewable Energy, Elsevier, vol. 163(C), pages 571-578.
    9. Emine E Çakırca & Gizem N Tekin & Oğuzhan İlgen & Ayşe N Akın, 2019. "Catalytic activity of CaO-based catalyst in transesterification of microalgae oil with methanol," Energy & Environment, , vol. 30(1), pages 176-187, February.
    10. Shemelis N. Gebremariam & Trine Hvoslef-Eide & Meseret T. Terfa & Jorge M. Marchetti, 2019. "Techno-Economic Performance of Different Technological Based Bio-Refineries for Biofuel Production," Energies, MDPI, vol. 12(20), pages 1-21, October.
    11. Li, Ying & Niu, Shengli & Hao, Yanan & Zhou, Wenbo & Wang, Jun & Liu, Jiangwei, 2022. "Role of oxygen vacancy on activity of Fe-doped SrTiO3 perovskite bifunctional catalysts for biodiesel production," Renewable Energy, Elsevier, vol. 199(C), pages 1258-1271.
    12. Feng, Weiliang & Tie, Xinlong & Duan, Xiaoling & Yan, Su & Fang, Si & Sun, Peiyong & Gan, Lin & Wang, Tielin, 2023. "Covalent immobilization of phosphotungstic acid and amino acid on metal-organic frameworks with different structures: Acid-base bifunctional heterogeneous catalyst for the production of biodiesel from," Renewable Energy, Elsevier, vol. 210(C), pages 26-39.
    13. Mofijur, M. & Masjuki, H.H. & Kalam, M.A. & Hazrat, M.A. & Liaquat, A.M. & Shahabuddin, M. & Varman, M., 2012. "Prospects of biodiesel from Jatropha in Malaysia," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(7), pages 5007-5020.
    14. Yan, Yunjun & Li, Xiang & Wang, Guilong & Gui, Xiaohua & Li, Guanlin & Su, Feng & Wang, Xiaofeng & Liu, Tao, 2014. "Biotechnological preparation of biodiesel and its high-valued derivatives: A review," Applied Energy, Elsevier, vol. 113(C), pages 1614-1631.
    15. Al-Saadi, Ali & Mathan, Bobby & He, Yinghe, 2020. "Esterification and transesterification over SrO–ZnO/Al2O3 as a novel bifunctional catalyst for biodiesel production," Renewable Energy, Elsevier, vol. 158(C), pages 388-399.
    16. Supamathanon, Natkanin & Boonserm, Kornkanok & Osakoo, Nattawut & Wittayakun, Jatuporn & Prayoonpokarach, Sanchai & Chanlek, Narong & Dungkaew, Winya, 2023. "Potassium supported on zeolite-geopolymer hybrid materials as a new solid base catalyst for transesterification of soybean oil," Renewable Energy, Elsevier, vol. 202(C), pages 1460-1469.
    17. Jume, Binta Hadi & Gabris, Mohammad Ali & Rashidi Nodeh, Hamid & Rezania, Shahabaldin & Cho, Jinwoo, 2020. "Biodiesel production from waste cooking oil using a novel heterogeneous catalyst based on graphene oxide doped metal oxide nanoparticles," Renewable Energy, Elsevier, vol. 162(C), pages 2182-2189.
    18. Liu, Kang & Wang, Rui & Yu, Meiqing, 2018. "An efficient, recoverable solid base catalyst of magnetic bamboo charcoal: Preparation, characterization, and performance in biodiesel production," Renewable Energy, Elsevier, vol. 127(C), pages 531-538.
    19. kumar, Mukesh & Sharma, Mahendra Pal, 2016. "Selection of potential oils for biodiesel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 56(C), pages 1129-1138.
    20. Nongbe, Medy C. & Ekou, Tchirioua & Ekou, Lynda & Yao, Kouassi Benjamin & Le Grognec, Erwan & Felpin, François-Xavier, 2017. "Biodiesel production from palm oil using sulfonated graphene catalyst," Renewable Energy, Elsevier, vol. 106(C), pages 135-141.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:189:y:2022:i:c:p:421-434. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.