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Mixed methanol/ethanol on transesterification of waste cooking oil using Mg/Al hydrotalcite catalyst

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  • Ma, Yingqun
  • Wang, Qunhui
  • Zheng, Lu
  • Gao, Zhen
  • Wang, Qiang
  • Ma, Yuhui

Abstract

Biodiesel production from waste cooking oil using calcined Mg/Al HT (hydrotalcite) as heterogeneous catalyst was investigated. This study describes the calcined Mg/Al HT prepared under optimal conditions to catalyse waste cooking oil for biodiesel preparation and proposes a plausible catalysis mechanism. The catalysts were characterised by Fourier Transform-Infrared, X-ray diffraction, Thermal Gravity Analysis-Differential thermal gravity and Brunner−Emmet−Teller measurements. Hydrotalcite with Mg/Al ratio of 3:1 showed a uniform mesoporous structure, excellent crystallinity, high surface area (270.5 m2/g) and good catalytic activity (at 500 °C calcination). The highest biodiesel yield obtained was 95.2% under optimised conditions of alcohol/oil molar ratio of 6:1, methanol/ethanol molar ratio of 4:2, catalyst content of 1.5%, reaction time of 2.5 h, reaction temperature of 80 °C. Mixed methanol/ethanol showed good synergistic effects as an ester exchange agent, and the catalyst was easily separated and recycled. Therefore, Mg/Al hydrotalcite can effectively catalyse waste cooking oil for biodiesel preparation with mixed methanol/ethanol.

Suggested Citation

  • Ma, Yingqun & Wang, Qunhui & Zheng, Lu & Gao, Zhen & Wang, Qiang & Ma, Yuhui, 2016. "Mixed methanol/ethanol on transesterification of waste cooking oil using Mg/Al hydrotalcite catalyst," Energy, Elsevier, vol. 107(C), pages 523-531.
    • Handle: RePEc:eee:energy:v:107:y:2016:i:c:p:523-531
    DOI: 10.1016/j.energy.2016.04.066
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    5. Laureano Costarrosa & David Eduardo Leiva-Candia & Antonio José Cubero-Atienza & Juan José Ruiz & M. Pilar Dorado, 2018. "Optimization of the Transesterification of Waste Cooking Oil with Mg-Al Hydrotalcite Using Response Surface Methodology," Energies, MDPI, vol. 11(2), pages 1-9, January.
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