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Rational copolymerization strategy engineered C self-doped g-C3N4 for efficient and robust solar photocatalytic H2 evolution

Author

Listed:
  • Liu, Enli
  • Lin, Xue
  • Hong, Yuanzhi
  • Yang, Lan
  • Luo, Bifu
  • Shi, Weilong
  • Shi, Junyou

Abstract

Graphitic carbon nitride (g-C3N4) with unique physicochemical features has garnered much attention in artificial photosynthesis, yet the photoactivity of pristine g-C3N4 (PCN) is severely restricted because of its rapid charge recombination rate and narrow visible-light absorption. To this end, for the first time, here we reported a rational one-step copolymerization strategy for the fabrication of carbon self-doped g-C3N4 (CCN) by using melamine and chitosan as the starting materials. Experimental results indicated that the bridged N atoms were substituted by C atoms in the g-C3N4 matrix, resulting in the formation of delocalized big π bonds, thereby the obviously increased the electrical conductivity, remarkably extended the visible-light absorption region, and significantly improved the mobility of photoinduced electron-hole pairs. Consequently, the as-engineered CCN with abundant mesopores structure showed a dramatically boosting photocatalytic H2-evolved activity (1224 μmol g−1 h−1), 4.5-folds than PCN powders. Eventually, the resulting CCN exhibited an extremely long-term durable stability after storing in reaction solution for 90 days. Our work will bring about potential application in designing of high-performance g-C3N4 photocatalyst for renewable solar-to-H2 conversion.

Suggested Citation

  • Liu, Enli & Lin, Xue & Hong, Yuanzhi & Yang, Lan & Luo, Bifu & Shi, Weilong & Shi, Junyou, 2021. "Rational copolymerization strategy engineered C self-doped g-C3N4 for efficient and robust solar photocatalytic H2 evolution," Renewable Energy, Elsevier, vol. 178(C), pages 757-765.
    • Handle: RePEc:eee:renene:v:178:y:2021:i:c:p:757-765
    DOI: 10.1016/j.renene.2021.06.066
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    1. Mahvelati-Shamsabadi, Tahereh & Lee, Byeong-Kyu, 2020. "Photocatalytic H2 evolution and CO2 reduction over phosphorus-doped g-C3N4 nanostructures: Electronic, Optical, and Surface properties," Renewable and Sustainable Energy Reviews, Elsevier, vol. 130(C).
    2. Yiou Wang & Anastasia Vogel & Michael Sachs & Reiner Sebastian Sprick & Liam Wilbraham & Savio J. A. Moniz & Robert Godin & Martijn A. Zwijnenburg & James R. Durrant & Andrew I. Cooper & Junwang Tang, 2019. "Current understanding and challenges of solar-driven hydrogen generation using polymeric photocatalysts," Nature Energy, Nature, vol. 4(9), pages 746-760, September.
    3. Stančin, H. & Mikulčić, H. & Wang, X. & Duić, N., 2020. "A review on alternative fuels in future energy system," Renewable and Sustainable Energy Reviews, Elsevier, vol. 128(C).
    4. Vincent Wing-hei Lau & Igor Moudrakovski & Tiago Botari & Simon Weinberger & Maria B. Mesch & Viola Duppel & Jürgen Senker & Volker Blum & Bettina V. Lotsch, 2016. "Rational design of carbon nitride photocatalysts by identification of cyanamide defects as catalytically relevant sites," Nature Communications, Nature, vol. 7(1), pages 1-10, November.
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    1. Chen, Ruijie & Zhang, Zhiqiang & Wu, Jun & Chen, Xueru & Wang, Lei & Yin, Haotian & Li, Hongping & Ding, Jing & Wan, Hui & Guan, Guofeng, 2022. "“Carbon diffusion” engineered carbon nitride nanosheets for high-efficiency photocatalytic solar-to-fuels conversion," Renewable Energy, Elsevier, vol. 197(C), pages 943-952.
    2. Sun, Zhen & Wang, Junxiang & Lu, Sen & Zhang, Guan, 2022. "Enzymatic biomass hydrolysis assisted photocatalytic H2 production from water employing porous carbon doped brookite/anatase heterophase titania photocatalyst," Renewable Energy, Elsevier, vol. 197(C), pages 151-160.
    3. Shi, Weilong & Sun, Wei & Liu, Yanan & Li, Xiangyu & Lin, Xue & Guo, Feng & Hong, Yuanzhi, 2022. "Onion-ring-like g-C3N4 modified with Bi3TaO7 quantum dots: A novel 0D/3D S-scheme heterojunction for enhanced photocatalytic hydrogen production under visible light irradiation," Renewable Energy, Elsevier, vol. 182(C), pages 958-968.
    4. Guo, Feng & Chen, Zhihao & Shi, Yuxing & Cao, Longwen & Cheng, Xiaofang & Shi, Weilong & Chen, Lizhuang & Lin, Xue, 2022. "A ragged porous hollow tubular carbon nitride towards boosting visible-light photocatalytic hydrogen production in water and seawater," Renewable Energy, Elsevier, vol. 188(C), pages 1-10.

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    More about this item

    Keywords

    g-C3N4; Chitosan; Carbon self-doped; Delocalized big π bonds; Photocatalytic H2 production; Solar-to-H2 conversion;
    All these keywords.

    JEL classification:

    • H2 - Public Economics - - Taxation, Subsidies, and Revenue

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