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On mechanism of lignin decomposition – Investigation using microscale techniques: Py-GC-MS, Py-FT-IR and TGA

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  • Wądrzyk, Mariusz
  • Janus, Rafał
  • Lewandowski, Marek
  • Magdziarz, Aneta

Abstract

Lignin stands the most abundantly available source of renewable aromatic compounds which is generated as a useless waste by-product in numerous industrial processes, e.g., in pulp and paper manufacturing as well as during second-generation ethanol production. The present work aims to investigate the effect of reaction conditions (particularly the reaction atmosphere type) on the composition of the volatiles that evolved during the pyrolysis of lignin. The pyrolytic studies were carried out using coupled microscale techniques, i.e., Py-GC-MS, and Py-FT-IR. The pyrolysis is usually carried out under an inert atmosphere. Herein, there was additionally studied comprehensively the effect of oxidizing (CO2 and air) and reducing atmosphere (H2). There was found a profound impact of the processing temperature on the composition changes of volatiles. A minor effect was noted for the pyrolysis atmosphere on the qualitative composition of the volatiles, but certain quantitative differences between their concentration were observed. Their composition confirmed the complex molecular structure of lignin. Among the identified compounds, there were found phenol derivatives as primary products of cleavage of lignin structures as well as aliphatic oxygen compounds and aromatic hydrocarbons as the products of the secondary decomposition and deoxygenation thereof.

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  • Wądrzyk, Mariusz & Janus, Rafał & Lewandowski, Marek & Magdziarz, Aneta, 2021. "On mechanism of lignin decomposition – Investigation using microscale techniques: Py-GC-MS, Py-FT-IR and TGA," Renewable Energy, Elsevier, vol. 177(C), pages 942-952.
    • Handle: RePEc:eee:renene:v:177:y:2021:i:c:p:942-952
    DOI: 10.1016/j.renene.2021.06.006
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    References listed on IDEAS

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    1. Azadi, Pooya & Inderwildi, Oliver R. & Farnood, Ramin & King, David A., 2013. "Liquid fuels, hydrogen and chemicals from lignin: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 21(C), pages 506-523.
    2. Stančin, H. & Mikulčić, H. & Wang, X. & Duić, N., 2020. "A review on alternative fuels in future energy system," Renewable and Sustainable Energy Reviews, Elsevier, vol. 128(C).
    3. Sobek, Szymon & Werle, Sebastian, 2020. "Isoconversional determination of the apparent reaction models governing pyrolysis of wood, straw and sewage sludge, with an approach to rate modelling," Renewable Energy, Elsevier, vol. 161(C), pages 972-987.
    4. Roberts, Justo José & Cassula, Agnelo Marotta & Osvaldo Prado, Pedro & Dias, Rubens Alves & Balestieri, José Antonio Perrella, 2015. "Assessment of dry residual biomass potential for use as alternative energy source in the party of General Pueyrredón, Argentina," Renewable and Sustainable Energy Reviews, Elsevier, vol. 41(C), pages 568-583.
    5. Zhang, Xin & Deng, Honghu & Hou, Xueyi & Qiu, Rongliang & Chen, Zhihua, 2019. "Pyrolytic behavior and kinetic of wood sawdust at isothermal and non-isothermal conditions," Renewable Energy, Elsevier, vol. 142(C), pages 284-294.
    6. Dhyani, Vaibhav & Bhaskar, Thallada, 2018. "A comprehensive review on the pyrolysis of lignocellulosic biomass," Renewable Energy, Elsevier, vol. 129(PB), pages 695-716.
    7. Guo, Mingxin & Song, Weiping & Buhain, Jeremy, 2015. "Bioenergy and biofuels: History, status, and perspective," Renewable and Sustainable Energy Reviews, Elsevier, vol. 42(C), pages 712-725.
    8. Nanda, Sonil & Azargohar, Ramin & Dalai, Ajay K. & Kozinski, Janusz A., 2015. "An assessment on the sustainability of lignocellulosic biomass for biorefining," Renewable and Sustainable Energy Reviews, Elsevier, vol. 50(C), pages 925-941.
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    1. Wądrzyk, Mariusz & Korzeniowski, Łukasz & Plata, Marek & Janus, Rafał & Lewandowski, Marek & Michalik, Marek & Magdziarz, Aneta, 2023. "Pyrolysis of hydrochars obtained from blackcurrant pomace in single and binary solvent systems," Renewable Energy, Elsevier, vol. 214(C), pages 383-394.

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