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High volume hydrogen evolution from KBH4 hydrolysis with palladium complex catalyst

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  • Kilinc, Dilek
  • Sahin, Omer

Abstract

In this work, we aimed to present an efficient catalyst in potassium borohydride hydrolysis for hydrogen production. Therefore 5-Amino-2,4-dichlorophenol-3,5-ditertbutylsalisylaldimine-Pd complex was synthesized. FT-IR, SEM, TEM, BET, XRD, Elemental Analysis techniques was employed for characterization of Pd-complex catalyst. When the catalyst tested in KBH4 hydrolysis reaction, some affecting factors were studied such as temperatures (20°C-50 °C), catalyst amounts (5–50 mg), KOH concentrations (0–10%) and KBH4 concentration (2–10%) The results displayed that the synthesized Palladium Schiff Base complex catalyst facilitates potassium borohydride hydrolysis with 25.194 kJ/mol activation energy (Ea). Additionally, Pd Schiff Base complex demonstrated remarkable reusability performance and conserved 95% of its inherent catalytic activity even at sixth recycle.

Suggested Citation

  • Kilinc, Dilek & Sahin, Omer, 2020. "High volume hydrogen evolution from KBH4 hydrolysis with palladium complex catalyst," Renewable Energy, Elsevier, vol. 161(C), pages 257-264.
    • Handle: RePEc:eee:renene:v:161:y:2020:i:c:p:257-264
    DOI: 10.1016/j.renene.2020.06.035
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    References listed on IDEAS

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