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Biomass-derived self-supported porous carbon membrane embedded with Co nanoparticles as an advanced electrocatalyst for efficient and robust hydrogen evolution reaction

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  • Min, Shixiong
  • Duan, Yan
  • Li, Yanan
  • Wang, Fang

Abstract

Powderous transition metal-based electrocatalysts have been widely studied for hydrogen evolution reaction (HER), but their practical application still remains challenging due to the tedious slurry-based electrode assembly process and unavoidable stability decay at high current density. Herein, a self-supported H2 evolution cathode based on pomelo peel (PP)-derived porous carbon (PPDC) membrane with embedded Co nanoparticles (Co@PPDC) is developed by direct carbonization of Co-adsorbed PP (Co2+-PP). Benefiting from the large surface areas, the abundant open and interconnected pores, the highly graphitic PPDC membrane, and the highly dispersed Co nanoparticles, the self-supported Co@PPDC electrode demonstrates superior electrocatalytic performance for HER in 1.0 M KOH solution, with overpotentials of 154 and 264 mV at current densities of 10 and 100 mA cm−2, respectively. In addition, owing to the good structural integrity, the Co@PPDC electrode exhibits an excellent cycling stability for 2000 cycles and a stable current density of ∼100 mA cm−2 at a constant overpotential of 265 mV over 12 h with a nearly 100% Faradaic efficiency (FE) and H2 production rate of 1.56 mmol h−1. Therefore, this work provides a versatile and effective strategy for development of high-performance self-supported electrodes at low cost for large-scale H2 production from electrochemical water splitting.

Suggested Citation

  • Min, Shixiong & Duan, Yan & Li, Yanan & Wang, Fang, 2020. "Biomass-derived self-supported porous carbon membrane embedded with Co nanoparticles as an advanced electrocatalyst for efficient and robust hydrogen evolution reaction," Renewable Energy, Elsevier, vol. 155(C), pages 447-455.
    • Handle: RePEc:eee:renene:v:155:y:2020:i:c:p:447-455
    DOI: 10.1016/j.renene.2020.03.164
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    References listed on IDEAS

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    1. Hong Wang & Shixiong Min & Chun Ma & Zhixiong Liu & Weiyi Zhang & Qiang Wang & Debao Li & Yangyang Li & Stuart Turner & Yu Han & Haibo Zhu & Edy Abou-hamad & Mohamed Nejib Hedhili & Jun Pan & Weili Yu, 2017. "Synthesis of single-crystal-like nanoporous carbon membranes and their application in overall water splitting," Nature Communications, Nature, vol. 8(1), pages 1-9, April.
    2. Steven Chu & Arun Majumdar, 2012. "Opportunities and challenges for a sustainable energy future," Nature, Nature, vol. 488(7411), pages 294-303, August.
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    1. Zhao, Meng-Jie & Li, Er-Mei & Deng, Ning & Hu, Yingjie & Li, Chao-Xiong & Li, Bing & Li, Fang & Guo, Zhen-Guo & He, Jian-Bo, 2022. "Indirect electrodeposition of a NiMo@Ni(OH)2MoOx composite catalyst for superior hydrogen production in acidic and alkaline electrolytes," Renewable Energy, Elsevier, vol. 191(C), pages 370-379.

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    More about this item

    Keywords

    Biomass; Porous carbon membrane; Co nanoparticles; Self-supported electrode; H2 evolution reaction;
    All these keywords.

    JEL classification:

    • H2 - Public Economics - - Taxation, Subsidies, and Revenue

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