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Treatment of two different water resources in desalination and microbial fuel cell processes by poly sulfone/Sulfonated poly ether ether ketone hybrid membrane

Author

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  • Ghasemi, Mostafa
  • Wan Daud, Wan Ramli
  • Alam, Javed
  • Ilbeygi, Hamid
  • Sedighi, Mehdi
  • Ismail, Ahmad Fauzi
  • Yazdi, Mohammad H.
  • Aljlil, Saad A.

Abstract

The PS (Polysulfone)/SPEEK (sulfonated poly ether ether ketone) hybrid membranes were fabricated and modified with low and high DS (degrees of sulfonation) for the desalination of brackish water and proton exchange membrane in microbial fuel cell. The results illustrated that SPEEK has changed the morphology of membranes and increase their hydrophilicity. PS/SPEEK with lower DS (29%) had the rejection percentage of 62% for NaCl and 68% for MgSO4; while it was 67% and 81% for PS/SPEEK (76%) at 4 bars. Furthermore, the water flux for PS at 10 bar was 12.41 L m−2 h−1. It was four times higher for PS/SPEEK (29%) which means 49.5 L m−2 h−1 and 13 times higher for PS/SPEEK (76%) with means 157.76 L m−2 h−1. However, in MFC (microbial fuel cell), the highest power production was 97.47 mW/m2 by PS/SPEEK (29%) followed by 41.42 mW/m2 for PS/SPEEK (76%), and 9.4 mW/m2 for PS. This revealed that the sulfonation of PEEK (poly ether ether ketone) made it a better additive for PS for desalination, because it created a membrane with higher hydrophilicity, better pore size and better for salt rejection. Although for the separator, the degree of sulfonation was limited; otherwise it made a membrane to transfer some of the unwanted ions.

Suggested Citation

  • Ghasemi, Mostafa & Wan Daud, Wan Ramli & Alam, Javed & Ilbeygi, Hamid & Sedighi, Mehdi & Ismail, Ahmad Fauzi & Yazdi, Mohammad H. & Aljlil, Saad A., 2016. "Treatment of two different water resources in desalination and microbial fuel cell processes by poly sulfone/Sulfonated poly ether ether ketone hybrid membrane," Energy, Elsevier, vol. 96(C), pages 303-313.
    • Handle: RePEc:eee:energy:v:96:y:2016:i:c:p:303-313
    DOI: 10.1016/j.energy.2015.12.053
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    1. Parnian, Mohammad Javad & Rowshanzamir, Soosan & Gashoul, Fatemeh, 2017. "Comprehensive investigation of physicochemical and electrochemical properties of sulfonated poly (ether ether ketone) membranes with different degrees of sulfonation for proton exchange membrane fuel ," Energy, Elsevier, vol. 125(C), pages 614-628.
    2. Tawalbeh, Muhammad & Al-Othman, Amani & Singh, Karnail & Douba, Ikram & Kabakebji, Dania & Alkasrawi, Malek, 2020. "Microbial desalination cells for water purification and power generation: A critical review," Energy, Elsevier, vol. 209(C).
    3. Mostafa Ghasemi & Mehdi Sedighi & Yie Hua Tan, 2021. "Carbon Nanotube/Pt Cathode Nanocomposite Electrode in Microbial Fuel Cells for Wastewater Treatment and Bioenergy Production," Sustainability, MDPI, vol. 13(14), pages 1-13, July.
    4. Chen, Wenwen & Liu, Zhongliang & Li, Yanxia & Liao, Qiang & Zhu, Xun, 2021. "High electricity generation achieved by depositing rGO@MnO2 composite catalysts on three-dimensional stainless steel fiber felt for preparing the energy-efficient air cathode in microbial fuel cells," Energy, Elsevier, vol. 222(C).
    5. Zinadini, S. & Zinatizadeh, A.A. & Rahimi, M. & Vatanpour, V. & Bahrami, K., 2017. "Energy recovery and hygienic water production from wastewater using an innovative integrated microbial fuel cell–membrane separation process," Energy, Elsevier, vol. 141(C), pages 1350-1362.

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    Keywords

    SPEEK; Industrial; Brackish; Membrane; MFC;
    All these keywords.

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