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Three-dimensional, transient, nonisothermal model of all-vanadium redox flow batteries

Author

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  • Oh, Kyeongmin
  • Yoo, Haneul
  • Ko, Johan
  • Won, Seongyeon
  • Ju, Hyunchul

Abstract

A three-dimensional (3-D), transient, nonisothermal model of all-vanadium redox flow batteries (VRFBs) is developed by rigorously accounting for the electrochemical reactions of four types of vanadium ions (V2+, V3+, VO2+, and VO2+) and the resulting mass and heat transport processes. Particular emphasis is placed on analyzing various heat generation mechanisms, including irreversible and reversible heat generation due to vanadium redox reactions and joule heating arising from the solid electrode and electrolyte ionic resistances. The 3-D model is validated against voltage evolution curves measured under charging and discharging processes. The model predictions compare well with the experimental data over a wide range of state of charge (SOCs), and further reveal key electrochemical and transport phenomena inside VRFBs through multidimensional contours of solid electrode/electrolyte potentials, species concentrations, and temperatures. This full 3-D comprehensive VRFB model can be applied to realistic multicell stacks to determine the optimal design and operating conditions.

Suggested Citation

  • Oh, Kyeongmin & Yoo, Haneul & Ko, Johan & Won, Seongyeon & Ju, Hyunchul, 2015. "Three-dimensional, transient, nonisothermal model of all-vanadium redox flow batteries," Energy, Elsevier, vol. 81(C), pages 3-14.
    • Handle: RePEc:eee:energy:v:81:y:2015:i:c:p:3-14
    DOI: 10.1016/j.energy.2014.05.020
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    References listed on IDEAS

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    1. Ko, Johan & Ju, Hyunchul, 2012. "Comparison of numerical simulation results and experimental data during cold-start of polymer electrolyte fuel cells," Applied Energy, Elsevier, vol. 94(C), pages 364-374.
    2. Huang, Ke-Long & Li, Xiao-gang & Liu, Su-qin & Tan, Ning & Chen, Li-quan, 2008. "Research progress of vanadium redox flow battery for energy storage in China," Renewable Energy, Elsevier, vol. 33(2), pages 186-192.
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    Cited by:

    1. Messaggi, M. & Canzi, P. & Mereu, R. & Baricci, A. & Inzoli, F. & Casalegno, A. & Zago, M., 2018. "Analysis of flow field design on vanadium redox flow battery performance: Development of 3D computational fluid dynamic model and experimental validation," Applied Energy, Elsevier, vol. 228(C), pages 1057-1070.
    2. Yuan, Chenguang & Xing, Feng & Zheng, Qiong & Zhang, Huamin & Li, Xianfeng & Ma, Xiangkun, 2020. "Factor analysis of the uniformity of the transfer current density in vanadium flow battery by an improved three-dimensional transient model," Energy, Elsevier, vol. 194(C).
    3. Longchun Zhong & Fengming Chu, 2023. "A Novel Biomimetic Lung-Shaped Flow Field for All-Vanadium Redox Flow Battery," Sustainability, MDPI, vol. 15(18), pages 1-14, September.
    4. Trovò, Andrea & Alotto, Piergiorgio & Giomo, Monica & Moro, Federico & Guarnieri, Massimo, 2021. "A validated dynamical model of a kW-class Vanadium Redox Flow Battery," Mathematics and Computers in Simulation (MATCOM), Elsevier, vol. 183(C), pages 66-77.
    5. Jienkulsawad, Prathak & Jirabovornwisut, Tossaporn & Chen, Yong-Song & Arpornwichanop, Amornchai, 2023. "Effect of battery material and operation on dynamic performance of a vanadium redox flow battery under electrolyte imbalance conditions," Energy, Elsevier, vol. 268(C).
    6. Chen, Wei & Kang, Jialun & Shu, Qing & Zhang, Yunsong, 2019. "Analysis of storage capacity and energy conversion on the performance of gradient and double-layered porous electrode in all-vanadium redox flow batteries," Energy, Elsevier, vol. 180(C), pages 341-355.
    7. Zhang, Kaiyue & Xiong, Jing & Yan, Chuanwei & Tang, Ao, 2020. "In-situ measurement of electrode kinetics in porous electrode for vanadium flow batteries using symmetrical cell design," Applied Energy, Elsevier, vol. 272(C).
    8. Yoon, Sang Jun & Kim, Sangwon & Kim, Dong Kyu, 2019. "Optimization of local porosity in the electrode as an advanced channel for all-vanadium redox flow battery," Energy, Elsevier, vol. 172(C), pages 26-35.
    9. Pan, Jianxin & Huang, Mianyan & Li, Xue & Wang, Shubo & Li, Weihua & Ma, Tao & Xie, Xiaofeng & Ramani, Vijay, 2016. "The performance of all vanadium redox flow batteries at below-ambient temperatures," Energy, Elsevier, vol. 107(C), pages 784-790.
    10. He, Qijiao & Li, Zheng & Zhao, Dongqi & Yu, Jie & Tan, Peng & Guo, Meiting & Liao, Tianjun & Zhao, Tianshou & Ni, Meng, 2023. "A 3D modelling study on all vanadium redox flow battery at various operating temperatures," Energy, Elsevier, vol. 282(C).
    11. Iñigo Aramendia & Unai Fernandez-Gamiz & Adrian Martinez-San-Vicente & Ekaitz Zulueta & Jose Manuel Lopez-Guede, 2020. "Vanadium Redox Flow Batteries: A Review Oriented to Fluid-Dynamic Optimization," Energies, MDPI, vol. 14(1), pages 1-20, December.
    12. Cheng, Ziqiang & Tenny, Kevin M. & Pizzolato, Alberto & Forner-Cuenca, Antoni & Verda, Vittorio & Chiang, Yet-Ming & Brushett, Fikile R. & Behrou, Reza, 2020. "Data-driven electrode parameter identification for vanadium redox flow batteries through experimental and numerical methods," Applied Energy, Elsevier, vol. 279(C).
    13. Pugach, M. & Kondratenko, M. & Briola, S. & Bischi, A., 2018. "Zero dimensional dynamic model of vanadium redox flow battery cell incorporating all modes of vanadium ions crossover," Applied Energy, Elsevier, vol. 226(C), pages 560-569.
    14. Pugach, M. & Vyshinsky, V. & Bischi, A., 2019. "Energy efficiency analysis for a kilo-watt class vanadium redox flow battery system," Applied Energy, Elsevier, vol. 253(C), pages 1-1.

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