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Stability mechanism investigation of emulsion fuels from biomass pyrolysis oil and diesel

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  • Guo, Zuogang
  • Wang, Shurong
  • Wang, Xiangyu

Abstract

In this paper, emulsion fuels from crude bio-oil and its molecular distillation fractions were prepared by single ultrasonic and ultrasonic-mechanical emulsification. The results showed that the emulsions from crude bio-oil and 0# diesel had the best stability, with a stability time of 31 days. The stability time of the bio-oil middle fraction emulsion was 216 min, while that of the bio-oil heavy fraction emulsion was as low as 14 min. The particle size distributions of the emulsions were analyzed by a Malvern particle size analyzer. Emulsion fuels made from crude bio-oil and the bio-oil middle fraction had a smaller droplet size of 8–60 nm. In contrast, the emulsion fuel from the alcohol-diluted bio-oil heavy fraction had much larger droplet size, reaching up to 6000 nm. Compared with single ultrasonic emulsification, ultrasonic-mechanical emulsification had positive effects on increasing the stability time of the crude bio-oil emulsion, but negative effects on the stability time of the bio-oil middle and heavy fraction emulsions. To explain the above differences, spherical shell mechanism models were proposed according to the composition properties of the crude bio-oil and its fractions.

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  • Guo, Zuogang & Wang, Shurong & Wang, Xiangyu, 2014. "Stability mechanism investigation of emulsion fuels from biomass pyrolysis oil and diesel," Energy, Elsevier, vol. 66(C), pages 250-255.
    • Handle: RePEc:eee:energy:v:66:y:2014:i:c:p:250-255
    DOI: 10.1016/j.energy.2014.01.010
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    7. de Luna, Mark Daniel G. & Cruz, Louie Angelo D. & Chen, Wei-Hsin & Lin, Bo-Jhih & Hsieh, Tzu-Hsien, 2017. "Improving the stability of diesel emulsions with high pyrolysis bio-oil content by alcohol co-surfactants and high shear mixing strategies," Energy, Elsevier, vol. 141(C), pages 1416-1428.
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    10. Pachapur, Vinayak Laxman & Sarma, Saurabh Jyoti & Brar, Satinder Kaur & Le Bihan, Yann & Buelna, Gerardo & Verma, Mausam, 2016. "Surfactant mediated enhanced glycerol uptake and hydrogen production from biodiesel waste using co-culture of Enterobacter aerogenes and Clostridium butyricum," Renewable Energy, Elsevier, vol. 95(C), pages 542-551.
    11. Leng, Lijian & Yuan, Xingzhong & Chen, Xiaohong & Huang, Huajun & Wang, Hou & Li, Hui & Zhu, Ren & Li, Shanxing & Zeng, Guangming, 2015. "Characterization of liquefaction bio-oil from sewage sludge and its solubilization in diesel microemulsion," Energy, Elsevier, vol. 82(C), pages 218-228.
    12. David Längauer & Yu-Ying Lin & Wei-Hsin Chen & Chao-Wen Wang & Michal Šafář & Vladimír Čablík, 2018. "Simultaneous Extraction and Emulsification of Food Waste Liquefaction Bio-Oil," Energies, MDPI, vol. 11(11), pages 1-13, November.
    13. Elsanusi, Osama Ahmed & Roy, Murari Mohon & Sidhu, Manpreet Singh, 2017. "Experimental Investigation on a Diesel Engine Fueled by Diesel-Biodiesel Blends and their Emulsions at Various Engine Operating Conditions," Applied Energy, Elsevier, vol. 203(C), pages 582-593.
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