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Study on the thermal behavior of different date palm residues: Characterization and devolatilization kinetics under inert and oxidative atmospheres

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  • El may, Yassine
  • Jeguirim, Mejdi
  • Dorge, Sophie
  • Trouvé, Gwenaelle
  • Said, Rachid

Abstract

Date palm residues are an attractive source of biomass energy since they are renewable, abundantly available and do not compete with food crops. Pyrolysis and combustion may be efficient methods of exploiting energy from these biomass resources. The purpose of this research was to investigate the thermal behavior of date palm biomass in order to evaluate their usefulness for energy production. In fact, ultimate and proximate analyses as well as thermal behavior of different date palm residues (date palm leaflets (DPL), date palm rachis (DPR), date palm trunk (DPT), date stones (DS) and fruitstalk prunings (FP)) were investigated. Non-isothermal thermogravimetric analyses (TGA) were performed to assess fuel reactivities under inert and oxidative atmospheres. Thermal degradation of all samples has exhibited quite similar behavior except DS. In contrast, different properties (e.g., reactivity, HHV or activation energy) were obtained, which may be attributed to a difference between tree parts composition (branches, trunk, fruit…). Thus, DPT and FP were found to be the most reactive materials in inert conditions; while in oxidative conditions, DPR is the highest one. In addition, activation energies corresponding to devolatilization regions under inert and oxidative conditions were 49.8, 45.2, 52.7, 50.9, 89.1 kJ mol−1 and 58.9, 49.6, 67.6, 57.7, 110.7 kJ mol−1 for DPL, DPR, DPT, DS and FP respectively. The obtained data, sample properties along with thermal behavior under inert and oxidative atmospheres as well as kinetic parameters, allowed the comparison of the obtained results with other biofuels and can be useful for the design of processing system for energy productions.

Suggested Citation

  • El may, Yassine & Jeguirim, Mejdi & Dorge, Sophie & Trouvé, Gwenaelle & Said, Rachid, 2012. "Study on the thermal behavior of different date palm residues: Characterization and devolatilization kinetics under inert and oxidative atmospheres," Energy, Elsevier, vol. 44(1), pages 702-709.
    • Handle: RePEc:eee:energy:v:44:y:2012:i:1:p:702-709
    DOI: 10.1016/j.energy.2012.05.022
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    5. Remston Martis & Amani Al-Othman & Muhammad Tawalbeh & Malek Alkasrawi, 2020. "Energy and Economic Analysis of Date Palm Biomass Feedstock for Biofuel Production in UAE: Pyrolysis, Gasification and Fermentation," Energies, MDPI, vol. 13(22), pages 1-34, November.
    6. Kraiem, Nesrine & Jeguirim, Mejdi & Limousy, Lionel & Lajili, Marzouk & Dorge, Sophie & Michelin, Laure & Said, Rachid, 2014. "Impregnation of olive mill wastewater on dry biomasses: Impact on chemical properties and combustion performances," Energy, Elsevier, vol. 78(C), pages 479-489.
    7. Lahijani, Pooya & Mohammadi, Maedeh & Mohamed, Abdul Rahman, 2019. "Investigation of synergism and kinetic analysis during CO2 co-gasification of scrap tire char and agro-wastes," Renewable Energy, Elsevier, vol. 142(C), pages 147-157.
    8. de Oliveira, Jofran Luiz & da Silva, Jadir Nogueira & Graciosa Pereira, Emanuele & Oliveira Filho, Delly & Rizzo Carvalho, Daniel, 2013. "Characterization and mapping of waste from coffee and eucalyptus production in Brazil for thermochemical conversion of energy via gasification," Renewable and Sustainable Energy Reviews, Elsevier, vol. 21(C), pages 52-58.
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    10. Besma Khiari & Mejdi Jeguirim, 2018. "Pyrolysis of Grape Marc from Tunisian Wine Industry: Feedstock Characterization, Thermal Degradation and Kinetic Analysis," Energies, MDPI, vol. 11(4), pages 1-14, March.

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