IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v41y2012i1p184-191.html
   My bibliography  Save this article

CO2 fixation using magnesium silicate minerals part 1: Process description and performance

Author

Listed:
  • Fagerlund, Johan
  • Nduagu, Experience
  • Romão, Inês
  • Zevenhoven, Ron

Abstract

This paper describes a staged carbonation process for magnesium silicate mineral carbonation. This carbon dioxide capture and storage (CCS) alternative involves the production of magnesium hydroxide, followed by its carbonation in a pressurised fluidised bed (PFB) reactor. The goal is to utilise the heat of the carbonation reaction to drive the Mg(OH)2 production step. The results show that Mg(OH)2 can be produced successfully (up to 78% Mg extraction extent achieved so far) and efficiently from different serpentinite minerals from locations worldwide (Finland, Lithuania, Australia, Portugal…). From the extraction step, ammonium sulphate is recovered while iron oxides (from the mineral) are obtained as by-products. The carbonation step, while still being developed, resulted in >50%-wt conversion in 10 min (500°C, 20 bar) for > 300 μm serpentinite-derived Mg(OH)2 particles. Thus the reaction rate achieved so far is much faster than what is currently being considered fast in the field of mineral carbonation.

Suggested Citation

  • Fagerlund, Johan & Nduagu, Experience & Romão, Inês & Zevenhoven, Ron, 2012. "CO2 fixation using magnesium silicate minerals part 1: Process description and performance," Energy, Elsevier, vol. 41(1), pages 184-191.
    • Handle: RePEc:eee:energy:v:41:y:2012:i:1:p:184-191
    DOI: 10.1016/j.energy.2011.08.032
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S036054421100572X
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2011.08.032?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Zevenhoven, Ron & Teir, Sebastian & Eloneva, Sanni, 2008. "Heat optimisation of a staged gas–solid mineral carbonation process for long-term CO2 storage," Energy, Elsevier, vol. 33(2), pages 362-370.
    2. Lackner, Klaus S. & Wendt, Christopher H. & Butt, Darryl P. & Joyce, Edward L. & Sharp, David H., 1995. "Carbon dioxide disposal in carbonate minerals," Energy, Elsevier, vol. 20(11), pages 1153-1170.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Lombardi, L. & Carnevale, E.A., 2016. "Analysis of an innovative process for landfill gas quality improvement," Energy, Elsevier, vol. 109(C), pages 1107-1117.
    2. Park, Sangwon & Song, Kyungsun & Jo, Hwanju, 2017. "Laboratory-scale experiment on a novel mineralization-based method of CO2 capture using alkaline solution," Energy, Elsevier, vol. 124(C), pages 589-598.
    3. Hyun Sic Park & Ju Sung Lee & JunYoung Han & Sangwon Park & Jinwon Park & Byoung Ryul Min, 2015. "CO2 Fixation by Membrane Separated NaCl Electrolysis," Energies, MDPI, vol. 8(8), pages 1-12, August.
    4. Park, Sangwon, 2018. "CO2 reduction-conversion to precipitates and morphological control through the application of the mineral carbonation mechanism," Energy, Elsevier, vol. 153(C), pages 413-421.
    5. Said, Arshe & Laukkanen, Timo & Järvinen, Mika, 2016. "Pilot-scale experimental work on carbon dioxide sequestration using steelmaking slag," Applied Energy, Elsevier, vol. 177(C), pages 602-611.
    6. Zhang, Huining & Gao, Chong & Chen, Ben & Tang, Jiang & He, Dongfeng & Xu, Anjun, 2018. "Stainless steel tailings accelerated direct carbonation process at low pressure: Carbonation efficiency evaluation and chromium leaching inhibition correlation analysis," Energy, Elsevier, vol. 155(C), pages 772-781.
    7. Nduagu, Experience & Romão, Inês & Fagerlund, Johan & Zevenhoven, Ron, 2013. "Performance assessment of producing Mg(OH)2 for CO2 mineral sequestration," Applied Energy, Elsevier, vol. 106(C), pages 116-126.
    8. Slotte, Martin & Romão, Inês & Zevenhoven, Ron, 2013. "Integration of a pilot-scale serpentinite carbonation process with an industrial lime kiln," Energy, Elsevier, vol. 62(C), pages 142-149.
    9. Zevenhoven, Ron & Slotte, Martin & Åbacka, Jacob & Highfield, James, 2016. "A comparison of CO2 mineral sequestration processes involving a dry or wet carbonation step," Energy, Elsevier, vol. 117(P2), pages 604-611.
    10. Hyun Sic Park & JunYoung Han & Ju Sung Lee & Kwang-Mo Kim & Hyung Jun Jo & Byoung Ryul Min, 2016. "Comparison of Two Processes Forming CaCO 3 Precipitates by Electrolysis," Energies, MDPI, vol. 9(12), pages 1-8, December.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Baral, Saroj S. & Singh, Kaustub & Sharma, Prabudh, 2015. "The potential of sustainable algal biofuel production using CO2 from thermal power plant in India," Renewable and Sustainable Energy Reviews, Elsevier, vol. 49(C), pages 1061-1074.
    2. Kakizawa, M. & Yamasaki, A. & Yanagisawa, Y., 2001. "A new CO2 disposal process via artificial weathering of calcium silicate accelerated by acetic acid," Energy, Elsevier, vol. 26(4), pages 341-354.
    3. Jun-Hwan Bang & Seung-Woo Lee & Chiwan Jeon & Sangwon Park & Kyungsun Song & Whan Joo Jo & Soochun Chae, 2016. "Leaching of Metal Ions from Blast Furnace Slag by Using Aqua Regia for CO 2 Mineralization," Energies, MDPI, vol. 9(12), pages 1-13, November.
    4. Wang, Xiaolong & Maroto-Valer, M. Mercedes, 2013. "Optimization of carbon dioxide capture and storage with mineralisation using recyclable ammonium salts," Energy, Elsevier, vol. 51(C), pages 431-438.
    5. Ioannis Rigopoulos & Michalis A. Vasiliades & Klito C. Petallidou & Ioannis Ioannou & Angelos M. Efstathiou & Theodora Kyratsi, 2015. "A method to enhance the CO 2 storage capacity of pyroxenitic rocks," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 5(5), pages 577-591, October.
    6. Klaus Keller & Zili Yang & Matt Hall & David F. Bradford, 2003. "Carbon Dioxide Sequestrian: When And How Much?," Working Papers 108, Princeton University, Department of Economics, Center for Economic Policy Studies..
    7. Giulia Costa & Alessandra Polettini & Raffaella Pomi & Alessio Stramazzo & Daniela Zingaretti, 2017. "Energetic assessment of CO 2 sequestration through slurry carbonation of steel slag: a factorial study," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 7(3), pages 530-541, June.
    8. Ukwattage, N.L. & Ranjith, P.G. & Wang, S.H., 2013. "Investigation of the potential of coal combustion fly ash for mineral sequestration of CO2 by accelerated carbonation," Energy, Elsevier, vol. 52(C), pages 230-236.
    9. Lombardi, Lidia & Carnevale, Ennio, 2013. "Economic evaluations of an innovative biogas upgrading method with CO2 storage," Energy, Elsevier, vol. 62(C), pages 88-94.
    10. Puthiya Veetil, Sanoop Kumar & Rebane, Kaarel & Yörük, Can Rüstü & Lopp, Margus & Trikkel, Andres & Hitch, Michael, 2021. "Aqueous mineral carbonation of oil shale mine waste (limestone): A feasibility study to develop a CO2 capture sorbent," Energy, Elsevier, vol. 221(C).
    11. Lombardi, L. & Carnevale, E.A., 2016. "Analysis of an innovative process for landfill gas quality improvement," Energy, Elsevier, vol. 109(C), pages 1107-1117.
    12. Wang, Honglin & Liu, Yanrong & Laaksonen, Aatto & Krook-Riekkola, Anna & Yang, Zhuhong & Lu, Xiaohua & Ji, Xiaoyan, 2020. "Carbon recycling – An immense resource and key to a smart climate engineering: A survey of technologies, cost and impurity impact," Renewable and Sustainable Energy Reviews, Elsevier, vol. 131(C).
    13. Klaus Keller & Zili Yang & Matt Hall & David F. Bradford, 2003. "Carbon Dioxide Sequestrian: When And How Much?," Working Papers 108, Princeton University, Department of Economics, Center for Economic Policy Studies..
    14. Raza, Waseem & Raza, Nadeem & Agbe, Henry & Kumar, R.V. & Kim, Ki-Hyun & Yang, Jianhua, 2018. "Multistep sequestration and storage of CO2 to form valuable products using forsterite," Energy, Elsevier, vol. 155(C), pages 865-873.
    15. Sina Hoseinpoori & David Pallarès & Filip Johnsson & Henrik Thunman, 2023. "A comparative exergy-based assessment of direct air capture technologies," Mitigation and Adaptation Strategies for Global Change, Springer, vol. 28(7), pages 1-20, October.
    16. Romão, Inês & Nduagu, Experience & Fagerlund, Johan & Gando-Ferreira, Licínio M. & Zevenhoven, Ron, 2012. "CO2 fixation using magnesium silicate minerals. Part 2: Energy efficiency and integration with iron-and steelmaking," Energy, Elsevier, vol. 41(1), pages 203-211.
    17. Dea Hyun Moon & Jun Eu & Wonhee Lee & Young Eun Kim & Ki Tae Park & You Na Ko & Soon Kwan Jeong & Min Hye Youn, 2020. "Comparison of reactions with different calcium sources for CaCO3 production using carbonic anhydrase," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 10(5), pages 898-906, October.
    18. Robin Koch & Gregor Sailer & Sebastian Paczkowski & Stefan Pelz & Jens Poetsch & Joachim Müller, 2021. "Lab-Scale Carbonation of Wood Ash for CO 2 -Sequestration," Energies, MDPI, vol. 14(21), pages 1-11, November.
    19. Arcusa, Stephanie & Sprenkle-Hyppolite, Starry, 2022. "Snapshot of the Carbon Sequestration Certification Market Ecosystem," OSF Preprints fu59w, Center for Open Science.
    20. Lee, Myung gyu & Jang, Young Nam & Ryu, Kyung won & Kim, Wonbeak & Bang, Jun-Hwan, 2012. "Mineral carbonation of flue gas desulfurization gypsum for CO2 sequestration," Energy, Elsevier, vol. 47(1), pages 370-377.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:41:y:2012:i:1:p:184-191. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.