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Development of copper-doped TiO2 photocatalyst for hydrogen production under visible light

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  • Yoong, L.S.
  • Chong, F.K.
  • Dutta, Binay K.

Abstract

The advantage of copper doping onto TiO2 semiconductor photocatalyst for enhanced hydrogen generation under irradiation at the visible range of the electromagnetic spectrum has been investigated. Two methods of preparation for the copper-doped catalyst were selected – complex precipitation and wet impregnation methods – using copper nitrate trihydrate as the starting material. The dopant loading varied from 2 to 15%. Characterization of the photocatalysts was done by thermogravimetric analysis (TGA), temperature programmed reduction (TPR), diffuse reflectance UV-Vis (DR-UV-Vis), scanning electron microscopy (SEM), Fourier transform infrared (FTIR) spectroscopy and X-ray diffraction (XRD). Photocatalytic activity towards hydrogen generation from water was investigated using a multiport photocatalytic reactor under visible light illumination with methanol added as a hole scavenger. Three calcination temperatures were selected – 300, 400 and 500°C. It was found that 10wt.% Cu/TiO2 calcined at 300°C for 30min yielded the maximum quantity of hydrogen. The reduction of band gap as a result of doping was estimated and the influence of the process parameters on catalytic activity is explained.

Suggested Citation

  • Yoong, L.S. & Chong, F.K. & Dutta, Binay K., 2009. "Development of copper-doped TiO2 photocatalyst for hydrogen production under visible light," Energy, Elsevier, vol. 34(10), pages 1652-1661.
    • Handle: RePEc:eee:energy:v:34:y:2009:i:10:p:1652-1661
    DOI: 10.1016/j.energy.2009.07.024
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    References listed on IDEAS

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    2. Nair, Ranjith G. & Tripathi, A.M. & Samdarshi, S.K., 2011. "Photocatalytic activity of predominantly rutile mixed phase Ag/TiV oxide nanoparticles under visible light irradiation," Energy, Elsevier, vol. 36(5), pages 3342-3347.
    3. Alami, Abdul Hai & Rajab, Bilal & Abed, Jehad & Faraj, Mohammed & Hawili, Abdullah Abu & Alawadhi, Hussain, 2019. "Investigating various copper oxides-based counter electrodes for dye sensitized solar cell applications," Energy, Elsevier, vol. 174(C), pages 526-533.
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    5. Samanta, Ritika & Chakraborty, Rajat, 2023. "Methyl levulinate synthesis from rice husk employing e-waste derived silica supported nano CuO–CdSO4 photocatalyst: Assessment of production environmental impacts, engine performance and emissions," Renewable Energy, Elsevier, vol. 210(C), pages 842-858.
    6. Bashiri, Robabeh & Mohamed, Norani Muti & Kait, Chong Fai & Sufian, Suriati & Kakooei, Saied & Khatani, Mehboob & Gholami, Zahra, 2016. "Optimization hydrogen production over visible light-driven titania-supported bimetallic photocatalyst from water photosplitting in tandem photoelectrochemical cell," Renewable Energy, Elsevier, vol. 99(C), pages 960-970.
    7. El Naggar, Ahmed M.A. & Gobara, Heba M. & Nassar, Ibrahim M., 2015. "Novel nano-structured for the improvement of photo-catalyzed hydrogen production via water splitting with in-situ nano-carbon formation," Renewable and Sustainable Energy Reviews, Elsevier, vol. 41(C), pages 1205-1216.
    8. Ruban, Priya & Sellappa, Kanmani, 2014. "Development and performance of bench-scale reactor for the photocatalytic generation of hydrogen," Energy, Elsevier, vol. 73(C), pages 926-932.
    9. Diker, Halide & Varlikli, Canan & Mizrak, Koray & Dana, Aykutlu, 2011. "Characterizations and photocatalytic activity comparisons of N-doped nc-TiO2 depending on synthetic conditions and structural differences of amine sources," Energy, Elsevier, vol. 36(2), pages 1243-1254.

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