IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v32y2007i7p1124-1133.html
   My bibliography  Save this article

Two-step water splitting thermochemical cycle based on iron oxide redox pair for solar hydrogen production

Author

Listed:
  • Charvin, Patrice
  • Abanades, Stéphane
  • Flamant, Gilles
  • Lemort, Florent

Abstract

This study deals with solar hydrogen production from the two-step iron oxide thermochemical cycle (Fe3O4/FeO). This cycle involves the endothermic solar-driven reduction of the metal oxide (magnetite) at high temperature followed by the exothermic steam hydrolysis of the reduced metal oxide (wustite) for hydrogen generation. Thermodynamic and experimental investigations have been performed to quantify the performances of this cycle for hydrogen production. High-temperature decomposition reaction (metal oxide reduction) was performed in a solar reactor set at the focus of a laboratory-scale solar furnace. The operating conditions for obtaining the complete reduction of magnetite into wustite were defined. An inert atmosphere is required to prevent re-oxidation of Fe(II) oxide during quenching. The water-splitting reaction with iron(II) oxide producing hydrogen was studied to determine the chemical kinetics, and the influence of temperature and particles size on the chemical conversion. A conversion of 83% was obtained for the hydrolysis reaction of non-stoichiometric solar wustite Fe(1−y)O at 575°C.

Suggested Citation

  • Charvin, Patrice & Abanades, Stéphane & Flamant, Gilles & Lemort, Florent, 2007. "Two-step water splitting thermochemical cycle based on iron oxide redox pair for solar hydrogen production," Energy, Elsevier, vol. 32(7), pages 1124-1133.
    • Handle: RePEc:eee:energy:v:32:y:2007:i:7:p:1124-1133
    DOI: 10.1016/j.energy.2006.07.023
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544206001897
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2006.07.023?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Farrell, Alexander E. & Keith, David W. & Corbett, James J., 2003. "A strategy for introducing hydrogen into transportation," Energy Policy, Elsevier, vol. 31(13), pages 1357-1367, October.
    2. Hennicke, Peter & Fischedick, Manfred, 2006. "Towards sustainable energy systems: The related role of hydrogen," Energy Policy, Elsevier, vol. 34(11), pages 1260-1270, July.
    3. Abanades, Stéphane & Charvin, Patrice & Flamant, Gilles & Neveu, Pierre, 2006. "Screening of water-splitting thermochemical cycles potentially attractive for hydrogen production by concentrated solar energy," Energy, Elsevier, vol. 31(14), pages 2805-2822.
    4. Kaneko, Hiroshi & Gokon, Nobuyuki & Hasegawa, Noriko & Tamaura, Yutaka, 2005. "Solar thermochemical process for hydrogen production using ferrites," Energy, Elsevier, vol. 30(11), pages 2171-2178.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Mohsen Fallah Vostakola & Babak Salamatinia & Bahman Amini Horri, 2022. "A Review on Recent Progress in the Integrated Green Hydrogen Production Processes," Energies, MDPI, vol. 15(3), pages 1-41, February.
    2. Kong, Hui & Hao, Yong & Jin, Hongguang, 2018. "Isothermal versus two-temperature solar thermochemical fuel synthesis: A comparative study," Applied Energy, Elsevier, vol. 228(C), pages 301-308.
    3. Yadav, Deepak & Banerjee, Rangan, 2016. "A review of solar thermochemical processes," Renewable and Sustainable Energy Reviews, Elsevier, vol. 54(C), pages 497-532.
    4. Mao, Yanpeng & Gao, Yibo & Dong, Wei & Wu, Han & Song, Zhanlong & Zhao, Xiqiang & Sun, Jing & Wang, Wenlong, 2020. "Hydrogen production via a two-step water splitting thermochemical cycle based on metal oxide – A review," Applied Energy, Elsevier, vol. 267(C).
    5. Ashokkumar, Veeramuthu & Chen, Wei-Hsin & Kamyab, Hesam & Kumar, Gopalakrishnan & Al-Muhtaseb, Ala'a H. & Ngamcharussrivichai, Chawalit, 2019. "Cultivation of microalgae Chlorella sp. in municipal sewage for biofuel production and utilization of biochar derived from residue for the conversion of hematite iron ore (Fe2O3) to iron (Fe) – Integr," Energy, Elsevier, vol. 189(C).
    6. Agrafiotis, Christos & Roeb, Martin & Sattler, Christian, 2015. "A review on solar thermal syngas production via redox pair-based water/carbon dioxide splitting thermochemical cycles," Renewable and Sustainable Energy Reviews, Elsevier, vol. 42(C), pages 254-285.
    7. Vidal, Alfonso & Gonzalez, Aurelio & Denk, Thorsten, 2020. "A 100 kW cavity-receiver reactor with an integrated two-step thermochemical cycle: Thermal performance under solar transients," Renewable Energy, Elsevier, vol. 153(C), pages 270-279.
    8. Milanese, Marco & Colangelo, Gianpiero & Laforgia, Domenico & de Risi, Arturo, 2017. "Multi-parameter optimization of double-loop fluidized bed solar reactor for thermochemical fuel production," Energy, Elsevier, vol. 134(C), pages 919-932.
    9. Rhodes, Nathan R. & Bobek, Michael M. & Allen, Kyle M. & Hahn, David W., 2015. "Investigation of long term reactive stability of ceria for use in solar thermochemical cycles," Energy, Elsevier, vol. 89(C), pages 924-931.
    10. Abdin, Zainul & Zafaranloo, Ali & Rafiee, Ahmad & Mérida, Walter & Lipiński, Wojciech & Khalilpour, Kaveh R., 2020. "Hydrogen as an energy vector," Renewable and Sustainable Energy Reviews, Elsevier, vol. 120(C).
    11. Hua, Xiuning & Fan, Yiran & Wang, Yidi & Fu, Tiantian & Fowler, G.D. & Zhao, Dongmei & Wang, Wei, 2017. "The behaviour of multiple reaction fronts during iron (III) oxide reduction in a non-steady state packed bed for chemical looping water splitting," Applied Energy, Elsevier, vol. 193(C), pages 96-111.
    12. Daphne Oudejans & Michele Offidani & Achilleas Constantinou & Stefania Albonetti & Nikolaos Dimitratos & Atul Bansode, 2022. "A Comprehensive Review on Two-Step Thermochemical Water Splitting for Hydrogen Production in a Redox Cycle," Energies, MDPI, vol. 15(9), pages 1-24, April.
    13. Carlos E. Arreola-Ramos & Omar Álvarez-Brito & Juan Daniel Macías & Aldo Javier Guadarrama-Mendoza & Manuel A. Ramírez-Cabrera & Armando Rojas-Morin & Patricio J. Valadés-Pelayo & Heidi Isabel Villafá, 2021. "Experimental Evaluation and Modeling of Air Heating in a Ceramic Foam Volumetric Absorber by Effective Parameters," Energies, MDPI, vol. 14(9), pages 1-15, April.
    14. Chaubey, Rashmi & Sahu, Satanand & James, Olusola O. & Maity, Sudip, 2013. "A review on development of industrial processes and emerging techniques for production of hydrogen from renewable and sustainable sources," Renewable and Sustainable Energy Reviews, Elsevier, vol. 23(C), pages 443-462.
    15. Orhan, Mehmet F. & Babu, Binish S., 2015. "Investigation of an integrated hydrogen production system based on nuclear and renewable energy sources: Comparative evaluation of hydrogen production options with a regenerative fuel cell system," Energy, Elsevier, vol. 88(C), pages 801-820.
    16. Stéphane Abanades, 2022. "Redox Cycles, Active Materials, and Reactors Applied to Water and Carbon Dioxide Splitting for Solar Thermochemical Fuel Production: A Review," Energies, MDPI, vol. 15(19), pages 1-28, September.
    17. Imponenti, Luca & Albrecht, Kevin J. & Kharait, Rounak & Sanders, Michael D. & Jackson, Gregory S., 2018. "Redox cycles with doped calcium manganites for thermochemical energy storage to 1000 °C," Applied Energy, Elsevier, vol. 230(C), pages 1-18.
    18. Christopher L. Muhich & Brian D. Ehrhart & Ibraheam Al-Shankiti & Barbara J. Ward & Charles B. Musgrave & Alan W. Weimer, 2016. "A review and perspective of efficient hydrogen generation via solar thermal water splitting," Wiley Interdisciplinary Reviews: Energy and Environment, Wiley Blackwell, vol. 5(3), pages 261-287, May.
    19. Song, Lee-hwa & Kang, Hyun Woo & Park, Seung Bin, 2012. "Thermally stable iron based redox catalysts for the thermo-chemical hydrogen generation from water," Energy, Elsevier, vol. 42(1), pages 313-320.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Song, Lee-hwa & Kang, Hyun Woo & Park, Seung Bin, 2012. "Thermally stable iron based redox catalysts for the thermo-chemical hydrogen generation from water," Energy, Elsevier, vol. 42(1), pages 313-320.
    2. Mao, Yanpeng & Gao, Yibo & Dong, Wei & Wu, Han & Song, Zhanlong & Zhao, Xiqiang & Sun, Jing & Wang, Wenlong, 2020. "Hydrogen production via a two-step water splitting thermochemical cycle based on metal oxide – A review," Applied Energy, Elsevier, vol. 267(C).
    3. Thomson, Heather & Corbett, James J. & Winebrake, James J., 2015. "Natural gas as a marine fuel," Energy Policy, Elsevier, vol. 87(C), pages 153-167.
    4. Arnob Das & Susmita Datta Peu, 2022. "A Comprehensive Review on Recent Advancements in Thermochemical Processes for Clean Hydrogen Production to Decarbonize the Energy Sector," Sustainability, MDPI, vol. 14(18), pages 1-42, September.
    5. Nzihou, Ange & Flamant, Gilles & Stanmore, Brian, 2012. "Synthetic fuels from biomass using concentrated solar energy – A review," Energy, Elsevier, vol. 42(1), pages 121-131.
    6. Marc A. Rosen, 2012. "Engineering Sustainability: A Technical Approach to Sustainability," Sustainability, MDPI, vol. 4(9), pages 1-23, September.
    7. Imran Khan, Muhammad, 2017. "Policy options for the sustainable development of natural gas as transportation fuel," Energy Policy, Elsevier, vol. 110(C), pages 126-136.
    8. Turhan, Tugce & Güvenilir, Yuksel Avcıbası & Sahiner, Nurettin, 2013. "Micro poly(3-sulfopropyl methacrylate) hydrogel synthesis for in situ metal nanoparticle preparation and hydrogen generation from hydrolysis of NaBH4," Energy, Elsevier, vol. 55(C), pages 511-518.
    9. Liu, Xiangyu & Zhang, Hao & Hong, Hui & Jin, Hongguang, 2020. "Experimental study on honeycomb reactor using methane via chemical looping cycle for solar syngas," Applied Energy, Elsevier, vol. 268(C).
    10. Gabriel Zsembinszki & Aran Solé & Camila Barreneche & Cristina Prieto & A. Inés Fernández & Luisa F. Cabeza, 2018. "Review of Reactors with Potential Use in Thermochemical Energy Storage in Concentrated Solar Power Plants," Energies, MDPI, vol. 11(9), pages 1-23, September.
    11. Demeulenaere, Xavier, 2019. "The use of automotive fleets to support the diffusion of Alternative Fuel Vehicles: A Rapid Evidence Assessment of barriers and decision mechanisms," Research in Transportation Economics, Elsevier, vol. 76(C).
    12. Cabeza, Luisa F. & Solé, Aran & Fontanet, Xavier & Barreneche, Camila & Jové, Aleix & Gallas, Manuel & Prieto, Cristina & Fernández, A. Inés, 2017. "Thermochemical energy storage by consecutive reactions for higher efficient concentrated solar power plants (CSP): Proof of concept," Applied Energy, Elsevier, vol. 185(P1), pages 836-845.
    13. Malte Schwoon, 2006. "Simulating the adoption of fuel cell vehicles," Journal of Evolutionary Economics, Springer, vol. 16(4), pages 435-472, October.
    14. Rosen, Marc A., 2010. "Advances in hydrogen production by thermochemical water decomposition: A review," Energy, Elsevier, vol. 35(2), pages 1068-1076.
    15. Xiao, Lan & Wu, Shuang-Ying & Li, You-Rong, 2012. "Advances in solar hydrogen production via two-step water-splitting thermochemical cycles based on metal redox reactions," Renewable Energy, Elsevier, vol. 41(C), pages 1-12.
    16. Alonso, Elisa & Pérez-Rábago, Carlos & Licurgo, Javier & Gallo, Alessandro & Fuentealba, Edward & Estrada, Claudio A., 2017. "Experimental aspects of CuO reduction in solar-driven reactors: Comparative performance of a rotary kiln and a packed-bed," Renewable Energy, Elsevier, vol. 105(C), pages 665-673.
    17. Wang, Wanrong & Ma, Yingjie & Maroufmashat, Azadeh & Zhang, Nan & Li, Jie & Xiao, Xin, 2022. "Optimal design of large-scale solar-aided hydrogen production process via machine learning based optimisation framework," Applied Energy, Elsevier, vol. 305(C).
    18. Liu, Yongan & Wang, Xinhua & Dong, Zhaohui & Liu, Haizhen & Li, Shouquan & Ge, Hongwei & Yan, Mi, 2013. "Hydrogen generation from the hydrolysis of Mg powder ball-milled with AlCl3," Energy, Elsevier, vol. 53(C), pages 147-152.
    19. Haeussler, Anita & Abanades, Stéphane & Julbe, Anne & Jouannaux, Julien & Cartoixa, Bruno, 2020. "Solar thermochemical fuel production from H2O and CO2 splitting via two-step redox cycling of reticulated porous ceria structures integrated in a monolithic cavity-type reactor," Energy, Elsevier, vol. 201(C).
    20. Guijie Zhang & Guang Yu & Yuqiang Feng & Luning Liu & Zhenhua Yang, 2017. "Improving the publication delay model to characterize the patent granting process," Scientometrics, Springer;Akadémiai Kiadó, vol. 111(2), pages 621-637, May.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:32:y:2007:i:7:p:1124-1133. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.