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13X Ex-Cu zeolite performance characterization towards H2S removal for biogas use in molten carbonate fuel cells

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  • Barelli, Linda
  • Bidini, Gianni
  • Micoli, Luca
  • Sisani, Elena
  • Turco, Maria

Abstract

A 13X zeolite modified with Cu ions (13X Ex-Cu) by means of an innovative technique was employed as adsorbent for H2S removal from biogas, to obtain a desulfurized fuel suitable for molten carbonate fuel cell systems. Sorbent performance was characterized over a wide range of operating conditions typical of biogas mixtures (high H2S content - 200 and 1000 ppmv; CH4 (60%)/CO2 (40%) matrices) and compared to several conventional sorbents. A sensitivity performance analysis was conducted, varying parameters as space velocity, reactor temperature, gas matrix composition and particles size, finalized to identify the optimal conditions for the studied application.

Suggested Citation

  • Barelli, Linda & Bidini, Gianni & Micoli, Luca & Sisani, Elena & Turco, Maria, 2018. "13X Ex-Cu zeolite performance characterization towards H2S removal for biogas use in molten carbonate fuel cells," Energy, Elsevier, vol. 160(C), pages 44-53.
    • Handle: RePEc:eee:energy:v:160:y:2018:i:c:p:44-53
    DOI: 10.1016/j.energy.2018.05.057
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    References listed on IDEAS

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    1. Sharaf, Omar Z. & Orhan, Mehmet F., 2014. "An overview of fuel cell technology: Fundamentals and applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 32(C), pages 810-853.
    2. Cozzolino, Raffaello & Lombardi, Lidia & Tribioli, Laura, 2017. "Use of biogas from biowaste in a solid oxide fuel cell stack: Application to an off-grid power plant," Renewable Energy, Elsevier, vol. 111(C), pages 781-791.
    3. Divya, D. & Gopinath, L.R. & Merlin Christy, P., 2015. "A review on current aspects and diverse prospects for enhancing biogas production in sustainable means," Renewable and Sustainable Energy Reviews, Elsevier, vol. 42(C), pages 690-699.
    4. Papadias, Dionissios D. & Ahmed, Shabbir & Kumar, Romesh, 2012. "Fuel quality issues with biogas energy – An economic analysis for a stationary fuel cell system," Energy, Elsevier, vol. 44(1), pages 257-277.
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    Cited by:

    1. Becker, C.M. & Marder, M. & Junges, E. & Konrad, O., 2022. "Technologies for biogas desulfurization - An overview of recent studies," Renewable and Sustainable Energy Reviews, Elsevier, vol. 159(C).
    2. Mirzokhid Abdirakhimov & Mohsen H. Al-Rashed & Janusz Wójcik, 2022. "Recent Attempts on the Removal of H 2 S from Various Gas Mixtures Using Zeolites and Waste-Based Adsorbents," Energies, MDPI, vol. 15(15), pages 1-20, July.

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    Keywords

    13X zeolite; Biogas; MCFC; H2S adsorption; XRD analysis;
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